carboxylic acids Flashcards

1
Q

What are carboxylic acids?

A

Carboxylic acids are weak acids with the –COOH functional group.

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2
Q

How are carboxylic acids named?

A

They are named by adding the suffix ‘oic acid’.

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3
Q

Where is the functional group of carboxylic acids located?

A

The functional group is always found at the end of the molecule.

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4
Q

How do carboxylic acids dissociate in solution?

A

They partially dissociate into hydrogen ions and carboxylate ions.

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5
Q

What makes the –COOH group polar?

A

The presence of electronegative oxygen atoms pulls electrons towards them, making them slightly negative.

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6
Q

How do carboxylic acids interact with water?

A

They can form hydrogen bonds with water, allowing smaller carboxylic acids to dissolve easily.

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7
Q

What happens to the solubility of carboxylic acids as chain length increases?

A

As chain length increases, solubility decreases.

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8
Q

What do carboxylic acids form when they react with metal hydroxides?

A

They form a salt and water.

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9
Q

What do carboxylic acids produce when they react with metal carbonates?

A

They form a salt, water, and carbon dioxide.

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10
Q

What is produced when carboxylic acids react with reactive metals?

A

They produce a salt and hydrogen.

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11
Q

What are acyl chlorides?

A

Acyl chlorides are compounds that contain the –COCl functional group.

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12
Q

How are acyl chlorides named?

A

They are named using the suffix –oyl chloride, e.g., ethanoyl chloride.

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13
Q

How are acyl chlorides formed?

A

They are formed when carboxylic acids react with thionyl chloride (SOCl2).

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14
Q

What do acyl chlorides react with?

A

They react with water, alcohols, ammonia, and amines.

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15
Q

What type of reactions do acyl chlorides undergo?

A

They undergo nucleophilic addition-elimination reactions.

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16
Q

What is produced when acyl chlorides react with water?

A

They produce a carboxylic acid and hydrogen chloride.

17
Q

What do acyl chlorides form when they react with alcohols?

A

They form an ester and hydrogen chloride.

18
Q

What is produced when acyl chlorides react with ammonia?

A

They produce a primary amide and hydrogen chloride.

19
Q

What do acyl chlorides produce when they react with amines?

A

They form a secondary amide and hydrogen chloride.

20
Q

How are esters usually made?

A

Esters are usually made by reacting an alcohol with a carboxylic acid.

21
Q

Can esters be made from acyl chlorides?

A

Yes, they can also be made by reacting an acyl chloride with phenol.