carboxylic acid derivatives Flashcards
anhydrides reacting with nucleophile
create carboxylic acid + either ester or amide
PCC
can only oxidize primary alcohols to aldehydes and secondary alcohols to ketones
K2Cr2O7
oxidizing agent that turns primary alcohol into carboxylic acid; aldehyde into carboxylic acid; and secondary alcohol into a ketone
KMnO4
oxidizing agent that turns primary alcohol into carboxylic acid; aldehyde into carboxylic acid; and secondary alcohol into a ketone
H2CrO4
oxidizing agent that turns primary alcohol into carboxylic acid; aldehyde into carboxylic acid; and secondary alcohol into a ketone
CrO3
aka Jones oxidation
oxidizing agent that turns primary alcohol into carboxylic acid; aldehyde into carboxylic acid; and secondary alcohol into a ketone
H2O2
oxidizing agent that turns primary alcohol into carboxylic acid; aldehyde into carboxylic acid; and secondary alcohol into a ketone
O2
oxidizing agent that turns primary alcohol into carboxylic acid; aldehyde into carboxylic acid; and secondary alcohol into a ketone
Ag2O
Tollens Test
turns aldehyde into carboxylic acid
can turn hydroxy ketone into a carboxylic acid as well if it undergoes tautomerization