Carboxylic acid 26.3 Flashcards
Are carboxylic acids soluble in water?
Carboxylic acids with up to 4 carbons are soluble in water
Why are long chain carboxylic acids insoluble?
As number of C atoms increases, the solubility decreases as the non-polar carbon chain has a greater effect on overall polarity of the molecule
Which bonds are polar in carboxylic acids?
C=O and O—H
How strong are carboxylic acids?
They are classified as weak acids
When dissolved in water they partly dissociate
What type of reactions to carboxylic acids undergo?
Redox reactions with metals
Neutralisation reaction with bases
What is the carboxylic acid ion called?
The carboxylate ion
E.g.
(Sodium carboxylate)
What is produced from carboxylic acid + metal ?
And what would be observed
- Hydrogen gas and salt
2. Effervescence of H2 gas and the metal disappearing
Carboxylic acid + metal oxide =
Salt + water
Carboxylic acid + alkali =
Salt + water
Carboxylic acid + carbonate =
Water + carbon dioxide gas
How to test for the carboxyl group?
As CB acids react with carbonates to produce CO2 chemists can use this to distinguish carboxylic acids from any other compound.
As carboxylic acids only common organic compound sufficiently acidic to react with carbonates.