Carbon & Its Compound Flashcards

1
Q

How many bonds can Carbon make

A

4

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2
Q

In terms of bonding, what makes carbon unique compared to other element 1`

A

C can bond with itself

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3
Q

Most abundant element on earth

A

Oxygen

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4
Q

What element is organic chem based on

A

carbon q

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5
Q

1 reason why carbon is special structurally

A

can form long chains + rings + complex molecules.

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6
Q

how many types of bonds are there

A

2

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7
Q

what are the 2 types of bonds

A

Ionic and covalent

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8
Q

what is ionic bonding

A

electrons transferred from one to another

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9
Q

When does an ionic bond occur

A

when the electronegativity difference between 2 atoms is high

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10
Q

in ionic bonds, what are the resulting compounds called

A

salts

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11
Q

what are covalent bonds

A

share electrons

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12
Q

what is the most common bond in organic molecules

A

covalent bond

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13
Q

in covalent bonds, what holds the atoms together

A

charges

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14
Q

What elements follow octet rule strictly

A

B, C, N. O. F

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15
Q

what elements can exceed the octet rule

A

from the 3rd row and below of PT elements can exceed octet rule

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16
Q

in lewis structures, how are bonded and non-bonded electrons shown

A

bonded electrons shown as line. non bonded electrons shown as dots

17
Q

what are formal charges

A

they help track charged atoms

18
Q

what does formal charges show

A

the shared and non shared electrons to the number of valence atoms

19
Q

what is the formula to find formal charges

A

(Groups #) - (# of bonds) - (# of non-bonded e) = FC

20
Q

Steps of finding formal charges (7)

A
  1. Count tot valence e-
  2. If charged molecules, then add 1 electron for -ve charge and subtract 1 for electron for +ve charge
  3. Draw out atoms w/ single bonds only
  4. count total # of bonds drawn. # valence e - # bonded e = # non bonded e
  5. add non bonded e to the structure. Start with most electronegative atoms
  6. calculate FC using formula. note, carbons with 4 bonds have no FC
  7. rearrange so that atoms have fewest charges possible. Take e from -ve atom and bond with +ve atom that doesnt have full octet
21
Q

what is an incomplete octet

A

structures with less than 8 electrons

22
Q

what expanded octet

A

structures with more than 8 electrons

23
Q

what is electronegativity

A

Ability of an atom to pull an electron towards itself from the surrounding atoms to which it is bonded.

24
Q

What is the PT trend for electronegativity

A

EN increases from left to right and bottom to top

25
Q

What is EN for Hydrogen

A

2.2

26
Q

what is the EN for Sulfur

A

2.6

27
Q

what is the EN for Phosphorous

A

2.2

28
Q

Whats the EN for oxygen

A

3.4

29
Q

what does the difference of EN b/w atoms indicate

A

bond polarity

30
Q

what creates a bond dipole

A

If there is one atom that is more EN than the other, this creates bond dipole.

31
Q

What are polar covalent bonds

A

Bonds with significant dipole because of unequal electron sharing (Significant difference between the EN of two atoms)

32
Q

covalently bonded carbon atoms have 3 structures, they are?

A
  1. linear
  2. trigonal planar
  3. tetrahedral
33
Q

bond angle for linear

A

180

34
Q

how are the atoms positioned in linear geometry

A

straight line

35
Q

bond angle for trigonal planar

A

120

36
Q

position of atoms in trigonal planar

A

3 atoms around central carbon.

37
Q

bond angle in tetrahedral

A

109

38
Q

atom arrangement in tetrahedral

A

pyramid