Carbon & Its Compound Flashcards

1
Q

How many bonds can Carbon make

A

4

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2
Q

In terms of bonding, what makes carbon unique compared to other element 1`

A

C can bond with itself

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3
Q

Most abundant element on earth

A

Oxygen

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4
Q

What element is organic chem based on

A

carbon q

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5
Q

1 reason why carbon is special structurally

A

can form long chains + rings + complex molecules.

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6
Q

how many types of bonds are there

A

2

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7
Q

what are the 2 types of bonds

A

Ionic and covalent

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8
Q

what is ionic bonding

A

electrons transferred from one to another

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9
Q

When does an ionic bond occur

A

when the electronegativity difference between 2 atoms is high

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10
Q

in ionic bonds, what are the resulting compounds called

A

salts

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11
Q

what are covalent bonds

A

share electrons

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12
Q

what is the most common bond in organic molecules

A

covalent bond

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13
Q

in covalent bonds, what holds the atoms together

A

charges

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14
Q

What elements follow octet rule strictly

A

B, C, N. O. F

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15
Q

what elements can exceed the octet rule

A

from the 3rd row and below of PT elements can exceed octet rule

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16
Q

in lewis structures, how are bonded and non-bonded electrons shown

A

bonded electrons shown as line. non bonded electrons shown as dots

17
Q

what are formal charges

A

they help track charged atoms

18
Q

what does formal charges show

A

the shared and non shared electrons to the number of valence atoms

19
Q

what is the formula to find formal charges

A

(Groups #) - (# of bonds) - (# of non-bonded e) = FC

20
Q

Steps of finding formal charges (7)

A
  1. Count tot valence e-
  2. If charged molecules, then add 1 electron for -ve charge and subtract 1 for electron for +ve charge
  3. Draw out atoms w/ single bonds only
  4. count total # of bonds drawn. # valence e - # bonded e = # non bonded e
  5. add non bonded e to the structure. Start with most electronegative atoms
  6. calculate FC using formula. note, carbons with 4 bonds have no FC
  7. rearrange so that atoms have fewest charges possible. Take e from -ve atom and bond with +ve atom that doesnt have full octet
21
Q

what is an incomplete octet

A

structures with less than 8 electrons

22
Q

what expanded octet

A

structures with more than 8 electrons

23
Q

what is electronegativity

A

Ability of an atom to pull an electron towards itself from the surrounding atoms to which it is bonded.

24
Q

What is the PT trend for electronegativity

A

EN increases from left to right and bottom to top

25
What is EN for Hydrogen
2.2
26
what is the EN for Sulfur
2.6
27
what is the EN for Phosphorous
2.2
28
Whats the EN for oxygen
3.4
29
what does the difference of EN b/w atoms indicate
bond polarity
30
what creates a bond dipole
If there is one atom that is more EN than the other, this creates bond dipole.
31
What are polar covalent bonds
Bonds with significant dipole because of unequal electron sharing (Significant difference between the EN of two atoms)
32
covalently bonded carbon atoms have 3 structures, they are?
1. linear 2. trigonal planar 3. tetrahedral
33
bond angle for linear
180
34
how are the atoms positioned in linear geometry
straight line
35
bond angle for trigonal planar
120
36
position of atoms in trigonal planar
3 atoms around central carbon.
37
bond angle in tetrahedral
109
38
atom arrangement in tetrahedral
pyramid