Carbohydrates Part 1 Flashcards
What is a carbohydrate? What is it composed of?
Biomolecules consisting of C, H, and O atoms
Primary energy source for metabolic processes
What are saccharides? What are the 4 types and examples of each?
A group that includes sugars, starch and cellulose
Monosaccharides- sugars, glucose
Disaccharides- lactose, sucrose
Oligosaccharides
Polysaccharides- starch, glycogen
Describe Monossacharides. How many carbons? What are they defined by?
Simple sugars
3-9 C atoms
Defined by location of carbonyl group
Describe Aldose. Where is the location of the carbonyl group? What kind of group is it?
Monosaccharide
Carbonyl group is on endmost C atom
Aldehyde group
Describe Ketose. Where is the location of the carbonyl group? What kind of group is it?
Monosaccharide
Carbonyl group within sugar backbone
Ketone group
What is a functional group?
Characteristic groups in organic molecules that give them their reactivity
What is a chiral carbon on a monosaccharide?
4 different atoms or groups of atoms attached
C atom farthest from the carbonyl group
What is the orientation of the OH group within D-sugar? What sugar exists naturally in this form?
On the chiral center on the right
Glucose
What is the orientation of the OH group within L-sugar?
On the chiral center on the left
Which glucose (D or L) is the natural form? What is their relationship to each other?
D glucose is the natural form
Enantiomers
Are monosaccharides soluble in water? By what process do they form rings? What is the significance of this phenomenon?
Soluble in water
Form rings via internal cyclization
Thermodynamically more stable form
What is a pyranose ring?
Ring with 5C and 1O atom forms
The hydroxyl group on carbon 5 reacts with aldehyde at carbon 1
What is a furanose ring?
Ring with 4 C and 1 O atom forms
The hydroxyl on carbon 4 reacts with the aldehyde at carbon 1
How is a hemiacetal formed? What do they contain?
Formed when an alcohol reacts with an aldehyde
Contain alcohol (OH) and an ether (OR) group attached to the same carbon
What are anomers?
Geometric variation of cyclic sugars
What is the most common form of glucose at equilibrium in aqueous?
Pyranose
Define glycosides/glycosidic bonds/linkage. What portions of the carbohydrate are involved?
Covalent bond that joins carbohydrate (sugar) to another carbohydrate (sugar) to form disaccharide
Hydroxyl group of carbohydrate and hydrogen of another sugar or organic molecule
Ex: glucose and galactose can form Lactose structure
What is a glycosidic bond? What is a glycoside? What atoms may be involved with this bond?
Sugar (OH group) may form a glycosidic bond with another biomolecule that is not a carbohydrate (can be between sugar and sugar or sugar and non carbohydrate
Substance containing a glycosidic bond
O, N, S, or C
What is a nucleotide? What is a nucleoside, what bond is involved? What are the 5 nitrogenous bases?
Phosphate, ribose sugar and nitrogenous base
Ribose sugar and nitrogenous base (linked by glycosidic bond)
Adenine, guanine, cytosine, thymine, uracil
Is the dominating form of D-glucose the open chain form or the furanose form?
Furanose ring
What is formed when monosaccharides (alcohols) react with acids?
Esters
What are the three components of a nucleoside triphosphate? (ATP) What does it function as?
Nitrogenous base adenosine
Sugar ribose
Triphosphate
Energy source
What are the contents of the enzyme Nicotinamide Adenine Dinucleotide? (NAD)
Adenine (nitrogenous base)
2x the sugar ribose
2x phosphate
Nicotinamide (form of vitamin B3)