Carbohydrates I Flashcards
Monosaccharides
Simple carbs, (sugars) include glucose, galactose and mannose.
Aldoses
Monosaccharides with an aldehyde group
Glyceraldehyde
A simple triose.
Sterioisomers
Mirror images of each other ( ex D-glyceraldehyde and L-glyceraldehyde.
Diastereomers
When sugars differ in stereoisomeric configuration.
Enantiomers
Stereoisomers are mirror images of each other
Epimers
When two sugars differ in configuration of only one carbon
Anomers
When sugars differ only in the configuration of the anomeric carbon.
Cyclization of monosaccarides
Typically leads to five or six membered rings.
Furanoses
5 member rings
Pyranoses
6 member rings
Glycosides
created by altering the hydroxyl group on the anomeric carbon. commonly created during the formation of disaccharides and longer carbohydrates.
Higher order saccharides
created by linking together more than one sugar residues includes, disaccharides (2), trisaccharides (3), oligosaccharides (several) and polysaccharides (many).
Glycosidic bonds
Bonds formed when the anomeric hydroxyl group is altered. After it has been altered the sugar can no longer flip back to its linear form.
Reduced sugar
its aldehyde is reduced to an alcohol, Ex Sorbitol- sometimes used as an artificial sweetener.