carbohydrates Flashcards

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1
Q

state the elements present in carbohydrates

A

carbon, hydrogen, oxygen

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2
Q

state the general formula of carbohydrates

A

Cx(H2O)y

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3
Q

define the term monosaccharide

A

a monomer, or single unit, that makes a simple sugar

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4
Q

define the term disaccharide

A

two monosaccharides joined together by a condensation reaction

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5
Q

define the term polysaccharide

A

many monosaccharides joined together by a polymerisation reaction

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6
Q

define the term pentose sugar

A

a monosaccharide containing 5 carbons

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7
Q

define the term hexose sugar

A

a monosaccharide containing 6 carbons

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8
Q

what is meant by a furanose ring?

A

a monosaccharide that forms a cyclic ring with 5 members

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9
Q

what is meant by a pyranose ring?

A

a monosaccharide that forms a cyclic ring with 6 members

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10
Q

define the term isomer

A

an isomer has the same chemical formula but a different structural formula and arrangement

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11
Q

describe the difference between alpha and beta glucose

A

the same other than the arrangement of the OH and H group on carbon 1. alpha glucose has the OH group below the carbon whereas beta glucose has the OH above the carbon.
when alpha glucose forms a polysaccharide the chain is helix shaped, whereas beta glucose forms a straight chain.

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12
Q

list the properties of ribose

A
carbons : 5
oxygens: 10
hydrogens: 5 
positioning of OH on carbon 1: above c 
solubility: soluble
polar: yes
hydroxyl groups: yes
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13
Q

list the properties of alpha-glucose

A

carbons: 6
oxygens: 12
hydrogens: 6
positioning of OH on carbon 1: below c
solubility: soluble
polar: yes
hydroxyl groups: yes

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14
Q

list three examples of disaccharides and the monomers they are composed of.

A

sucrose - alpha glucose and fructose
lactose - alpha glucose and galactose
maltose - 2 x alpha glucose

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15
Q

state the properties and function of glucose

A
  • small, soluble, a good source of energy, polar

- found in plant sap, human blood and most animal cells

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16
Q

state the properties and function of fructose

A
  • soluble, energy source, one of the smallest units

- found in fruits

17
Q

state the properties and function of galactose

A
  • very stable in solution, very similar to glucose

- not normally found in large quantities but forms a part of milk

18
Q

state the properties and function of maltose

A
  • formed by the breakdown of starch, made of two alpha glucose molecules
  • found in intestines and germinating seeds
19
Q

state the properties and function of sucrose

A
  • made from glucose and sucrose, good preservative

- found in sugar cane or beat

20
Q

state the properties and function of lactose

A
  • made from glucose and galactase, the beta glycosidic bonds can cause lactose intolerance. difficult to hydrolyse - slow release of energy.
  • found in milk
21
Q

describe how the hydrolysis of maltose occurs and why water is needed.

A

two alpha glucose units are broken at the glycosidic 1-4 bond. water is needed to complete the units of alpha glucose produced.

22
Q

explain why alpha glucose linking forms starch whereas beta glucose forms cellulose.

A

alpha glucose chains form helix shapes called amylose, alpha glucose also forms branches called amylopectin. these two elements form starch. However when beta glucose forms a chain it forms only straight lines, these are held together by hydrogen bonds to form cellulose microfibrils.

23
Q

name the two different polysaccharides that link together to form starch.

A

amylose and amylopectin

24
Q

explain why glycosidic bonds are called 1,4 or 1,6

A

they’re called 1,4 if they occur between carbon 1 of one monosaccharide and carbon 4 of another, and 1,6 when it’s between carbon 1 and carbon 6. you start counting the carbons from the very right carbon in the sugar.

25
Q

explain how to calculate the number of glycosidic bonds in a polysaccharide given the number of monosaccharides within it.

A

each monosaccharide forms 1 bond except the last one so the formula would be n-1

26
Q

what is the function of starch?

A

an energy storage product

27
Q

what is the function of cellulose?

A

structural support for plant cells in the form of the cell wall.

28
Q

what is the function of glycogen?

A

an energy storage product

29
Q

describe the structure of a cellulose fibre.

A
  • made from straight chains of beta glucose
  • the many chains are held together by hydrogen bonds
  • chains clump to make microfibrils which in turn from macrofibrils which create cellulose fibres
30
Q

relate the structural properties of starch to its function.

A
  • insoluble: stops the energy source from dissolving and affecting the water potential of the cell.
  • small and compact size: lots of energy can be stored in a small area
  • bonding: glucose molecules can be broken off from either end to get more energy.
  • side chains: amylopectin forms many branches so more glucose molecules can be broken off at once from each chain.
31
Q

relate the structural properties of cellulose to its function.

A
  • insoluble: it holds its shape and remains even in plants living under water.
  • size: large with many chains forming a strong mesh
  • bonding: resistant to hydrolysis
  • no side chains
32
Q

relate the structural properties of glycogen to its function.

A
  • insoluble: doesn’t dissolve/affect water potential. readily available as an energy source
  • size: long chains but consists mostly of branches
  • bonding: hydrolysed very rapidly due to the large number of side chains caused by many 1,6 glycosidic bonds.
  • side chains: lots of side chains increase the number of ends for glucose to be taken off of during respiration.