Carbohydrates Flashcards

1
Q

Carbohydrates are chemically classified as:
A) Polyhydroxy aldehydes and ketones
B) Amino acids
C) Lipids
D) Nucleic acids

A

A

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2
Q

The process by which plants synthesize carbohydrates is called:
A) Fermentation
B) Photosynthesis
C) Respiration
D) Hydrolysis

A

B

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3
Q

The molecular formula of glucose is:
A) C5H10O5
B) C6H12O6
C) C7H14O7
D) C8H16O8

A

B

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4
Q

The main product of photosynthesis is:
A) Starch
B) Glucose
C) Fructose
D) Protein

A

B

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5
Q

Which of the following is NOT a property of carbohydrates?
A) Soluble in water
B) Have a sweet taste
C) Contain nitrogen
D) Can be used as an energy source

A

C

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6
Q

The main source of carbon in the formation of carbohydrates in plants is:
A) Carbon dioxide
B) Water
C) Oxygen
D) Sunlight

A

A

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7
Q

Which functional group is present in glucose?
A) Amine
B) Hydroxyl and Carbonyl
C) Carboxyl
D) Ester

A

B

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8
Q

The process of carbohydrate metabolism in animals is known as:
A) Glycolysis
B) Photosynthesis
C) Fermentation
D) Hydrolysis

A

A

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9
Q

Which element is NOT a major component of carbohydrates?
A) Carbon
B) Hydrogen
C) Oxygen
D) Nitrogen

A

D

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10
Q

The breakdown of glucose to release energy occurs in:
A) Photosynthesis
B) Cellular respiration
C) Polymerization
D) None of the above

A

B

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11
Q

What are carbohydrates?

A

Carbohydrates are polyhydroxy aldehydes or ketones that serve as a primary energy source in living organisms.

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12
Q

What is the molecular formula of glucose?

A

The molecular formula of glucose is C₆H₁₂O₆.

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13
Q

What is the main product of photosynthesis?

A

The main product of photosynthesis is glucose.

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14
Q

What are the reactants of photosynthesis?

A

Carbon dioxide (CO₂) and water (H₂O) are the reactants of photosynthesis.

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15
Q

What functional groups are present in glucose?

A

Glucose contains hydroxyl (-OH) and carbonyl (C=O) functional groups.

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16
Q

What role do carbohydrates play in metabolism?

A

Carbohydrates serve as an energy source, being broken down in cellular respiration to produce ATP.

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17
Q

Why are carbohydrates soluble in water?

A

Carbohydrates have multiple hydroxyl (-OH) groups that form hydrogen bonds with water molecules, making them soluble.

18
Q

What is the difference between an aldose and a ketose?

A

Aldoses have an aldehyde (-CHO) group, while ketoses have a ketone (C=O) group.

19
Q

How do plants produce carbohydrates?

A

Plants synthesize carbohydrates through photosynthesis, using CO₂, H₂O, and sunlight.

20
Q

What is the chemical equation for photosynthesis?

A

6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂ (in the presence of sunlight).

21
Q

Define carbohydrates and explain their general chemical composition.

A

Carbohydrates are organic compounds composed of carbon (C), hydrogen (H), and oxygen (O), usually in a ratio of 1:2:1. They are classified as polyhydroxy aldehydes or ketones because they contain multiple hydroxyl (-OH) groups and either an aldehyde (-CHO) or a ketone (C=O) functional group. The general formula for carbohydrates is (CH₂O)n, where n ≥ 3.

22
Q

Differentiate between aldose and ketose carbohydrates with suitable examples.

A

Aldoses are carbohydrates that contain an aldehyde (-CHO) functional group at the terminal carbon.
Example: Glucose (C₆H₁₂O₆), an aldohexose.
Ketoses are carbohydrates that contain a ketone (C=O) functional group usually at the second carbon.
Example: Fructose (C₆H₁₂O₆), a ketohexose.
Both glucose and fructose have the same molecular formula but differ in functional groups, making them structural isomers.

23
Q

Describe the process of photosynthesis and explain how it contributes to carbohydrate formation.

A

Photosynthesis is the biological process by which green plants, algae, and some bacteria convert light energy into chemical energy in the form of carbohydrates. The process occurs in the chloroplasts of plant cells and involves two stages:

Light-dependent reactions – Occur in the thylakoid membrane, where sunlight is absorbed to produce ATP and NADPH.
Light-independent reactions (Calvin Cycle) – Occur in the stroma, where CO₂ is fixed using ATP and NADPH to form glucose.

24
Q

Write the balanced chemical equation for the synthesis of glucose via photosynthesis and explain each reactant and product.

A

The balanced equation for photosynthesis is:

6
C
O
2
+
6
H
2
O

sunlight
C
6
H
12
O
6
+
6
O
2
6CO
2

+6H
2

O
sunlight

C
6

H
12

O
6

+6O
2

Reactants:
CO₂ (Carbon dioxide): Absorbed from the atmosphere.
H₂O (Water): Absorbed from the soil.
Sunlight: Provides the energy required for the reaction.
Products:
C₆H₁₂O₆ (Glucose): A simple sugar stored as energy.
O₂ (Oxygen): Released into the atmosphere as a byproduct.
This process is crucial for producing organic compounds that serve as food for plants and other organisms.

25
Discuss the significance of hydroxyl (-OH) and carbonyl (C=O) functional groups in carbohydrates.
The hydroxyl (-OH) groups make carbohydrates highly polar and soluble in water, allowing easy transport in biological systems. They also participate in hydrogen bonding, stabilizing carbohydrate structures. The carbonyl (C=O) group determines whether the carbohydrate is an aldose (aldehyde) or ketose (ketone). It is highly reactive and plays a key role in the formation of ring structures in sugars. These functional groups make carbohydrates versatile biomolecules involved in energy storage, signaling, and structural functions.
26
Explain why carbohydrates are considered the primary source of energy in most living organisms.
Answer: Carbohydrates serve as a primary energy source because: They can be easily broken down into simpler sugars (e.g., glucose) that undergo cellular respiration to produce ATP, the energy currency of the cell. Glycogen (animals) and starch (plants) act as storage forms of carbohydrates, ensuring a readily available energy supply. Unlike proteins and fats, carbohydrates provide quick and efficient energy metabolism, making them the preferred energy source for the brain and muscles.
27
Describe the structural difference between glucose and fructose.
Answer: Glucose is an aldohexose with an aldehyde (-CHO) functional group at carbon 1. Fructose is a ketohexose with a ketone (C=O) functional group at carbon 2. Both sugars have the same molecular formula (C₆H₁₂O₆) but differ in their functional groups and structural arrangement.
28
How does the polyhydroxy nature of carbohydrates contribute to their solubility in water?
Answer: Carbohydrates contain multiple hydroxyl (-OH) groups, which form hydrogen bonds with water molecules. These interactions make them highly hydrophilic (water-soluble), allowing carbohydrates like glucose to dissolve easily in biological fluids for transport and metabolism.
29
Discuss the role of carbohydrates in plant metabolism and storage.
Answer: Carbohydrates play several essential roles in plants: Energy storage: Glucose is converted into starch for long-term storage. Structural support: Cellulose, a carbohydrate polymer, forms the cell wall, providing rigidity. Metabolism: Carbohydrates act as fuel in cellular respiration to generate ATP for plant growth and development. Transport: Sucrose (a disaccharide) transports energy from leaves to other parts of the plant via the phloem.
30
Explain the importance of glucose in biological systems and how it is utilized in cellular respiration.
Glucose is the primary metabolic fuel in living organisms. In cellular respiration, it is broken down through three key steps: Glycolysis: Occurs in the cytoplasm, breaking glucose into pyruvate, producing ATP and NADH. Krebs Cycle (Citric Acid Cycle): Takes place in mitochondria, generating electron carriers NADH and FADH₂. Electron Transport Chain (ETC): Produces ATP through oxidative phosphorylation. The overall equation for cellular respiration is: C 6 H 12 O 6 + 6 O 2 → 6 C O 2 + 6 H 2 O + A T P C 6 ​ H 12 ​ O 6 ​ +6O 2 ​ →6CO 2 ​ +6H 2 ​ O+ATP Glucose is vital for ATP production, fueling cellular processes such as muscle contraction, nerve function, and biosynthesis.
31
can a carbohydrate contain both aldehyde and ketone groups
No, a carbohydrate cannot naturally contain both an aldehyde (-CHO) and a ketone (C=O) functional group at the same time. Explanation: Carbohydrates are classified based on their functional groups: Aldoses: Contain an aldehyde (-CHO) group at carbon-1. Ketoses: Contain a ketone (C=O) group, usually at carbon-2. Mutual Exclusion: In a monosaccharide, only one carbonyl functional group can be present—either an aldehyde or a ketone, but not both. If a molecule had both, it would not be classified as a simple carbohydrate (monosaccharide) but rather a derivative or a chemically modified carbohydrate. Exceptions in Special Cases: Some derivatives of carbohydrates may be chemically modified to contain both an aldehyde and a ketone group, but this does not occur in naturally occurring simple sugars.
32
can a carbohydrate contain two carbon atoms
No, a naturally occurring carbohydrate cannot contain only two carbon atoms because the smallest possible carbohydrate must have at least three carbon atoms (a triose). Explanation: General Carbohydrate Formula: Carbohydrates follow the empirical formula (CH₂O)n, where n ≥ 3. The smallest naturally occurring monosaccharides are trioses (C₃H₆O₃), such as: Glyceraldehyde (an aldose) Dihydroxyacetone (a ketose) Why Not C₂H₄O₂? A two-carbon (C₂) compound following the (CH₂O)n rule would be C₂H₄O₂, which does not fit the structure of a carbohydrate. It would lack the necessary polyhydroxy (multiple -OH) and carbonyl (-CHO or C=O) features that define carbohydrates. Are There Any C₂ Sugar-Like Compounds? There exist two-carbon sugar derivatives, such as glycolaldehyde (C₂H₄O₂), but they are not classified as true carbohydrates. Glycolaldehyde is a simple aldehyde with hydroxyl groups, but it does not fit the polyhydroxy definition of carbohydrates. Conclusion: Carbohydrates must have at least three carbon atoms, making C₂ carbohydrates impossible under the standard biochemical definition.
33
Stereoisomers in Carbohydrates
Stereoisomers are compounds with the same molecular formula and sequence of bonded atoms but different 3D orientations. Example: D-Glucose and L-Glucose D-Glucose and L-Glucose are stereoisomers because they have the same molecular formula (C₆H₁₂O₆) but differ in their spatial arrangement.
34
Enantiomers (Mirror Images) Definition: Enantiomers are non-superimposable mirror images of each other.
Example: D-Glucose and L-Glucose are enantiomers. They are mirror images but cannot be rotated to look exactly the same. Most naturally occurring sugars in living organisms are D-sugars.
35
Diastereomers (Non-Mirror Stereoisomers)
Definition: Diastereomers are stereoisomers that are not mirror images of each other. Example: D-Glucose and D-Mannose are diastereomers because they differ at C-2 but are not mirror images. D-Glucose and D-Galactose are also diastereomers (differ at C-4).
36
Epimers (A Type of Diastereomer)
Definition: Epimers are diastereomers that differ at only one chiral carbon. Examples: D-Glucose and D-Mannose (C-2 epimers) D-Glucose and D-Galactose (C-4 epimers)
37
Anomers (A Type of Epimer)
Definition: Anomers are epimers that differ specifically at the anomeric carbon (C-1 in aldoses, C-2 in ketoses) when the sugar is in its cyclic form. Examples: α-D-Glucose and β-D-Glucose are anomers because they differ at C-1: α-anomer: -OH group on C-1 is down in Haworth projection. β-anomer: -OH group on C-1 is up in Haworth projection. Anomers exist in equilibrium due to mutarotation in aqueous solutions.
38
isomerism in carbohydrates
39
Define monosaccharides and explain their significance in biological systems.
Monosaccharides are the simplest form of carbohydrates, consisting of a single sugar unit. They are polyhydroxy aldehydes or ketones that cannot be hydrolyzed into simpler sugars. Significance: They are the building blocks of larger carbohydrates like disaccharides and polysaccharides. They serve as quick energy sources in metabolic processes like glycolysis. Some, like ribose, are essential for nucleic acids (DNA & RNA).
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