Carbohydrates Flashcards

1
Q

Four major kinds of macromolecules found in living organisms?

A

Carbohydrates, lipids, proteins and nucleic acids

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2
Q

What do these macromolecules have in common?

A
  • They are large. Made up of smaller units called monomers to make up polymers exclusive of lipids.
    -They contain carbon based core (organic material) special groups attached to it that confer specific
    chemical properties
    -held together by covalent bonds- distinct form that influences function.
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3
Q

What are functional groups?

A

Functional groups are groups of atoms that occur within organic molecules in conferral with specific chemical properties.

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4
Q

What are functional groups classified as

A

hydrophobic and hydrophilic

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5
Q

hydrogen bonds and functional groups

A

hydrogen bonds between functional groups are important to the function of many macromolecules and help them to fold properly and maintain shape needed for functioning correctly.

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6
Q

Hydrogen bonds are also involved in various recognition processes such as

A
  • DNA complementary Base Pairing
    -Binding an enzyme to its substrate
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7
Q

Functional groups of Carbohydrates

A

in general monosaccharides only have one carbonyl group (aldehyde, ketone or acid), and the remaining carbons each bear one hydroxyl group

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8
Q

Polymers from monomer monosaccharide

A
  • Polysaccharide
    -Carbohydrates (starch)
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9
Q

Monosaccharides

A

Monosaccharides are the simplest carbohydrates. Building blocks of more complex carbs.

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10
Q

Aldoses

A

monosaccharides containing aldehyde group (-CHO) are known as aldoses and regarded as reducing sugars.

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11
Q

Ketoses

A

monosaccharides containing ketone groups -C=0 known as ketoses and regarded as non reducing sugars.

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12
Q

Disaccharides

A

Most monosaccharides are rare in nature. Most sugars found in nature are disaccharides. These form when two monosaccharides come together.

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13
Q

How to the two monosaccharides react to form the disaccharide

A

A process called condensation/dehydration which requires a lot of energy releases water and a glycosidic bond forms which holds the two monosaccharide units together.

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14
Q

What are the three most important disaccharides?

A

Sucrose (non reducing sugar)
maltose (reducing)
lactose (reducing)

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15
Q

disaccharides and their forming monosaccharides

A

sucrose = @ glucose + @ fructose
maltose = @ glucose + @ glucose
@ Lactose = @glucose + B galactose
B Lactose = B glucose + B galactose

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16
Q

Dehydration

A

In this process a covalent bond is formed, one hydroxyl (-OH) is removed from one sub unit and a H+ bond is removed from the other sub unit. (enzymes facilitate this process)

17
Q

hydrolysis

A

In instances where the covalent bond needs to be broken, hydrolysis occurs where a hydrogen group is attached to one sub unit and a hydroxyl group is attached to another sub unit.

18
Q

Condensation polymerization

A

Monosaccharides undergo a series of condensation reactions adding one unit after another to the chain forming very large molecules (polysaccharides).

19
Q

Starch is usually produced in plants as a way of storing energy. It exists in two forms

A

Amylose and amylopectin
(both made from @ glucose

20
Q

Amylose

A

An unbranched polymer of @ glucose, the molecules coil into a helical structure. It forms a colloidal suspension in hot water.

21
Q

Amylopectin

A

A branched polymer of @ glucose completely insoluble in water

22
Q

Glycogen

A

Glycogen is amylopectin with very short distances between branching side chains. Starch from plants is hydrolysed in the body to form glucose, which is then passed into the cell and used in metabolic reactions. There in the cell the glucose can be polymerized to form glycogen which acts as a carbohydrate energy store.

23
Q

Cellulose

A

Another polymer made from glucose however it is made from B glucose molecules and the polymer molecules are straight

24
Q

Cellulose makes up the cell walls in plant cells. Which are tougher than cell membranes because

A

because of the arrangement of glucose polymer chains and hydrogen bonding to neighboring chains. Cellulose is not easily hydrolysed so therefore cannot be digested by humans for a source of energy

25
Q
A