carbohydrates Flashcards
these substances include carbohydrates. lipids, proteins, and nucleic acid (the 4 biomolecules)
bioorganic substances
this is the element of life
carbon
structural element of photosynthesis
cellulose
energy reservoir for plants
starch
energy reservoir for humans
glycogen
serves as energy currency of the human body
Adenosine Triphosphate (ATP)
source of carbohydrates
plant products
carbohydrates, specifically ____, form the structural framework of DNA and RNA
Ribose
carbohydrates is present in lipids. true or false?
true
carbohydrates link to proteins and act as signals for cell recognition. true or false?
true
the common chemical formula of photosynthesis?
Cn(H20)n
what are carbohydrates? this means a substance with multiple OH
polyhydroxy aldehydes or ketones
this refers to reactions involving H20. how chemical reaction happens thru __
hydrolysis
is fructose a ketone or a aldehyde?
ketone
which monosaccharides are aldoses?
glucose, galactose
the common number of C atoms in a monosaccharide?
5 and 6
these sugars contain 2-10 monosaccharides
oligosaccharides
these sugars contain 2 monosaccharide units
disaccharides
also called as the table sugar
sucrose
also called the milk sugar
lactose
also called the malt sugar
maltose
these sugars are associated with proteins and lipids in human body for structural and regulatory functions
disaccharides
these sugars contain many monosaccharides bonded and branched
polysaccharides
these are images that coincide at all points when the images are laid upon each other. these are achiral.
superimposable
these are images that are chiral or has handedness
non-superimposable
this refers to an atom attached to a 4 different groups
chiral center
almost all _____ are right handed (D)
monosaccharides
almost all ____ are left handed (L)
amino acids
isomers that have the same molecular and structural formulas but differ in the orientation of atoms in space
stereoisomers
stereoisomers whose molecules are nonsuperimposable mirror images of each other (chiral)
enantiomers
is carbohydrate a enantiomer or diastereoisomers?
enantiomers
basis for structure of carbohydrates
D and L system
four groups attached to the atom at the chiral center assume this geometry
tetrahedral arrangement
these isomers have lower boiling point as compared to straight chain because its active site is exposed
constitutional isomers
light move only in one direction
plane polarized light
our body reacts differently to different enantiomers. true or false?
true
which of the carbohydrates are aldohexose?
D-glucose
what is the meaning of aldohexose
an aldose group with 6 carbon atoms
which of the carbohydrates are ketohexose?
D-fructose
the sweet tasting sugar
fructose
this sugar is an aldopentose and is part of RNA, DNA, ATP
ribose
cyclic form of molcules that bears a shape
hemiacetal
OH is below the ring
alpha
OH is above the ring
Beta
cyclic monosaccharide containing 6 atom rings
pyranose
cyclic monosaccharide containing 5 atom rings
furanose
two-dimensional structural notation that specifies the three dimensional structure of a cyclic form of monosaccharide
Haworth projection formula
a ____ sugar gives a positive test with Tollen’s and Benedict’s solutions
reducing sugar
this is a reaction when the carbonyl group is reduced to a hydroxyl group. it produces sugar alcohol like sorbitol.
reduction to sugar alcohol
monosaccharide acetals formed by replacement of hemiacetal carbon -oh with -or group
glycoside
monosaccharide responsible for blood groups
D-galactose
these play an important role in metabolism of carbohydrates
phosphate ester
important building block of polysaccharide
amino sugar
this attaches 2 monosaccharides
glycosidic linkage
cellobiose is linked through a ___ glycosidic linkage
beta(1-4) glycosidic linkage
maltose is linked through a ___ glycosidic linkage
alpha (1-4) glycosidic linkage
maltose and cellobiose are combination of two monosaccharide called____?
glucose
lactose is joined by a _____ glycosidic linkage
beta (1-4) glycosidic linkage
lactose is a combination of monosaccharide ____ and ____
galactose and glucose
a condition in which people lack the enzyme lactase
lactose intolerance
this is a disaccharide produced by bonding of fructose and glucose
sucrose
this disaccharide is joined together by a head to head linkage and is the most abundant disaccharide
sucrose
sucrose is joined together by a ___glycosidic linkage
beta (1-2) glycosidic linkage
2 types of polysaccharides
linear & branched, homo- & hetero-
storage polysaccharide in plants and used as an energy source in cells
starch
this is a straight chain polymer
amylose
amylose is bonded through ____ linkage
alpha (1-4) linkage
branched chain polymer
amylopectin
amylopectin is bonded by _____ linkages
alpha (1-4) for straight chains, alpha (1-6) for branches
glycogen is bonded by ____ linkages
alpha (1-4) glycosidic linkage for straight chain, alpha (1-6) for branches
glycogen is broken down into glucose by a process of?
Glycogenolysis
glycogen is produced from glucose by a process of?
Glycogenesis
cellulose is linked by a _____ bond
beta (1-4) glycosidic bond, cannot be digested by humans
chitin is linked by a _____
beta (1-4) glycosidic bond
a structural polysaccharide that serves as lubrication for the joints
acidic polysaccharides
a lipid molecule with a carbohydrate molecule; important in cell recognition
glycolipid
a protein molecule with a carbohydrate molecule; important in cell recognition
glycoproteins
these are dietary monosaccharides or disaccharides, sweet
simple carbohydrate
dietary polysaccharides; not sweet
complex carbohydrates
also called the blood sugar as it can access the organs and the CNS
glucose
in beans, there are necessary _____ that help production of carbohydrates
amino acids
the coating of beans is made up of ____ that contains cellulose
insoluble fibers
what is the original name of fructose?
levulose
the condition of lack of enzyme needed to metabolize galactose
galactosemia
fermentation product of lactose
lactic acid
inability to digest lactose due to low levels of enzyme
maldigestion
a metabolic process that consumes sugar in the absence of oxygen; the primary means of producing ATP for microorganisms
fermentation
a nondigestible polysaccharide that provides no energy
fiber
fiber that is easily fermented by intestinal bactera
soluble fiber
fiber that not easily fermented
insoluble fiber
soluble fiber that helps in lowering high blood cholesterol
dietary fiber
suggested amount of dietary fiber for adults
25g/day for women; 38g/day for men
suggested amount of dietary fiber for 5oyrs and above
21g for women; 30g for men
dietary fiber amount for preganant and lactating women
28g/day
these carbohydrates cannot be digested by the human body; similar in length as simple carb and similar in make up of polysaccharides
oligosaccharides
the goal for blood glucose
70-100 mg/dl
this lowers blood glucose levels; stimulates glycogen formation
insulin
this increases blood glucose levels; stimulated glycogen breakdown
glucagon
measure of how quickly a food can make blood sugar rise
Glycemic Index (GI)
type of diabetes that means no insulin produced; usually begins in childhood
type 1 diabetes mellitus
this type is associated with insulin resistance
type 2 diabetes mellitus
a blood glucose level that is too low (below 70 mg/dl)
hypoglycemia
sugar present in zero-sugar drinks
sugar alcohol