Carbohydrates Flashcards
Define carbohydrates
“polyhydroxy aldehydes or
polyhydroxy ketones, or substances that
yield such compounds on hydrolysis”
Formula for starch
(C6H10O5)n
Glucose converted to starch for storage
C6H12O6 => (C6H10O5)n + nH20
What does colonic fermentation of fibre produce
Colonic fermentation of fibre produces butyrate which is beneficial for gut health
Two types of simple sugars:
Monosaccharides and disaccharides
Types of monosaccharides
Glucose, fructose, galactose
Types of disaccharides
Lactose, maltose, sucrose
Two types of complex carbs
polysaccharides (starch)
non-starch polysaccharides (dietary fibre)
Monosaccharides
(2-6 carbon units)
– Biose, triose, tetrose, pentose, hexose (# of C)
– Glucose, fructose, galactose
Disaccharides
(2 monosaccharides)
– Sucrose (glucose + fructose)
– Maltose (glucose + glucose)
– Lactose (glucose + galactose)
Oligosaccharides
(3-10 monosaccharides)
– Not as common in food; pulses
– Inulin (fructan - chain of fructose; extracted from chicory)
Polysaccharides
(10+ monosaccharides)
– Complex carbohydrates
– Dextrin, starch, cellulose, pectin, gums
Hydrolysis of sucrose produces
Glucose, Fructose
Beet & cane (table) sugars, molasses/treacle, maple syrup
Hydrolysis of lactose produces
Glucose, Galactose
Milk & milk products
Hydrolysis of starch produces
Glucose
Branched/linear, contributes to
viscosity & gel formation
Hydrolyis of dextrin produces
Glucose
Hydrolysis product of starch
Hydrolysis of glycogen produces
Glucose
Meat products and seafood
Hydrolysis of cellulose produces
glucose
skeletal structure of plant cell (indigestible)
Simple sugars functions
Sweetness
* Other taste/aroma
* Colour
* Volume (e.g. fermentation in bread)
* Texture (e.g. crystallisation vs gelling in jams)
* ↓ freezing point
* Binds water (shelf-life)
Starch
- Complex carbohydrate (polysaccharide)
- Long chains of glucose (C6H10O5)n
n=400-4000
– Amylose (linear) (gel) 25% of starch
– Amylopectin (branched) (waxy) 75% of starch - Found in granules (small packets)
Derived from various plants:
– Roots (e.g. potato, tapioca)
– Cereal (e.g. corn, wheat, rice)
Caramelisation
- Browning of sugar (>100°C)
- Dry & moist heat
- e.g. crème caramel
Dextrinisation
Browning of starchy food
* Dry heat
* Breaks down starch > dextrins
* e.g. toasting bread
Gelatinisation
Thickening
* Starch heated with water
* Forms a suspension
* 60°C = swell
* 80°C = burst
Maillard reaction
sugar + protein
Enzymatic browning reaction
polyphenol oxidase > melanin
Unmodified starch uses in foods
Refined wheat flour - Thickening sauces/soups (roux)
Potato starch - Thicken soups (++ viscosity)
High amylose starch -Edible film for wrapping candies
Uses for modified starch in foods
Pre-gelatinised starch - instant puddings and soup mixes
uses for other polysaccharides in foods
Cellulose - Powered form- bulk in weight-reducing foods
Dextrins - In coffee extracts
Gums - Thickening & gelling agent
Uses for sugars in foods
Glucose - Humectant in confectionery
Caramel - Colouring & flavouring
How much total dietary energy should come from carbs?
50%