Carbohydrates Flashcards

1
Q

____________ are the most abundant biomolecule on earth.

A

Carbohydrates

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2
Q

Which biomolecule is often abbreviated to ‘CHO’?

A

Carbohydrate

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3
Q

Name two carbohydrates that are staples of the human diet.

A

Sugar and starch

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4
Q

___________ of carbohydrates is the central energy-yielding pathway in most non-photosynthetic cells.

A

Oxidation

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5
Q

Which type of carbohydrates are found in the cell coats of animals?

A

Insoluble

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6
Q

Name two classes of simple sugars.

A

Aldehyde sugars (aldoses) and ketone sugars (ketoses)

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7
Q

How many R-groups does an aldose have?

A

One

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8
Q

How many R-groups does a ketose have?

A

Two

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9
Q

Define ‘stereoisomers’.

A

Molecules that are non-superimposable, mirror images of each other

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10
Q

Glyceraldehyde has a single _______ carbon atom.

A

Asymmetric

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11
Q

Name the stereoisomers of glyceraldehyde.

A

D- and L-glyceraldehyde

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12
Q

What do ‘D and L’ refer to, in the context of stereoisomers?

A

D and L refer to the configuration of the asymmetric carbon atom, furthest from the aldehyde or ketone group

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13
Q

L-sugars rotate polarised light to the _____.

A

Left

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14
Q

D-sugars rotate polarised light to the _____.

A

Right

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15
Q

True or false: most hexose sugars are found naturally in the D-sugar form.

A

True

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16
Q

Name a sugar that naturally occurs in the L-sugar form.

A

L-arabinose

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17
Q

What is an epimer?

A

A D-sugar that differs in configuration at only a single asymmetric carbon atom

18
Q

What are the two crystalline forms of D-glucose?

A

Downward-pointing alpha-D-glucose and upward-pointing beta-D-glucose

19
Q

Glucose undergoes a reversible reaction between -OH group of C5, and the anomeric carbon (C1) forms a _______ _______ structure

A

Pyranose ring

20
Q

Fructose undergoes a common reaction between the -OH group of ___ and the anomeric carbon (C2), forming a furanose ring structure.

21
Q

Six-membered sugar rings are called ________.

22
Q

Five-membered sugar rings are called ________.

23
Q

What type of sugar will the following reaction for maltose yield?
A condensation reaction takes place. A bond is formed that is termed ‘glycosidic linkage’. Maltose involves the linking of two glucose molecules, 1-4 glycosidic linkage between the C1 and C4 positions of two D-glucose molecules.
The D-glucose containing C1 atom is in its alpha form, therefore the bond is termed an alpha (1-4) glycosidic bond.

A

Disaccharide

24
Q

A ______ glycosidic bond is seen in the glycosidic linkage of sucrose

25
True or false: Multiple reactions in a sugar create smaller polysaccharides.
False
26
Carbohydrates may be _________ or branched.
Linear
27
Name two functions of carbohydrates.
Storage and structure
28
Excess glucose is stored as ________.
Glycogen
29
Plants store excess glucose as _______.
Starch
30
What is the exoskeleton of some animals called?
Chitin
31
Cellulose is a plant storage __________.
Polysaccharide
32
Bacteria and yeasts store excess glucose as _______.
Dextran
33
What is amylose?
Unbranched polymers of glucose units, joined by α1-4 glycosidic bonds
34
What is amylopectin?
Similar to amylose, but additional α1-6 bonds occur every 25-30 units, creating branchpoints
35
_________ consists entirely of glucose units, mostly linked by α1-4 bonds
Glycogen
36
Every ___ sugar units, glycogen's chains are branched by the formation of an α1-6 bond
10
37
Where is glycogen primarily made and stored?
The liver and the muscles
38
Cellulose strands are held together by which type of bond?
Hydrogen
39
Name two animals that are capable of degrading cellulose in their gut.
Cow and horse
40
Cellulose is made up of unbranched ___________ of glucose units, linked by β1-4 glycosidic bonds
Polysaccharides
41
α and β forms exist for all cyclic _______________.
Monosaccharides