Carbohydrates Flashcards
What is the general formula of a monosachharide
(CH2O)n - where n can be any number between three and seven (3,4,5,6,7)
What type of substance is a monosaccharide
A sweet tasting, soluble sugar that cannot be broken down further by hydrolysis as it is already in its simplest sugar form.
Which two monosaccharides combine to make maltose
Glucose + Glucose
What disaccharide is made of two glucose monosaccharides
Maltose
Which two monosaccharides combine to form sucrose
Glucose + fructose
What disaccharide is formed when glucose and fructose combine
Sucrose
Which two monosaccharides combine to form lactose
Glucose + galactose
What disaccharide is formed when glucose and galactose combine
Lactose
What reaction breaks down a disaccharide into its constituent monosachharides
Hydrolysis
What type of reaction is it when two monosaccharides combine to form a disaccharide
Condensation reaction
Define monosachharide
A single saccharide/sugar monomer. They are not decomposable to simpler sugars by hydrolysis as they are already in their simplest form
Define polysaccharide
Polymers consisting of many monosacharide monomers/subunits that are joined by glycosidic bonds formed in a condensation reaction
What are three key properties of polysaccharides
1) they are insoluble
2) they are large,compact molecules
3) when hydrolysed, they break down into disaccharides or monosaccharides.
Which organisms store glucose as starch
Plants
Why can glucose not be stored as a monosaccharide
Glucose is extremely soluble in water. This means it affects the cells water potential. If a cell contains a high amount of dissolved glucose, this would cause water to move into the cell via osmosis and this could cause the cell to burst.
Describe why glucose is soluble in water
Glucose contains a large amount of hydroxyl groups which are polar due to the small negative charge on the oxygen atom and the small positive charge on the hydrogen atom. This means that the hydroxyl groups form hydrogen bonds with water and this makes glucose extremely soluble in water.
Describe the structure of starch
Starch is made up of chains of a-glucose monosaccharides.
The chains are branched and unbranched and the unbranched chains allow starch to be wound into a tight coil that’s makes the molecule very compact.
The OH groups point inwards and form the hydrogen bonds that hold the helix in place.
Describe how the structure of starch is suited to its function
- It is insoluble and therefore does not affect the cells water potential.
- It is large and insoluble so it doesn’t diffuse out of cells.
- It is compact, so a lot of it can be stored in a small space.
- When hydrolysed it forms a-glucose, which is both easily transported and readily used in respiration.
- The branched chains have many ends, each of which can be acted on simultaneously by enzymes which means glucose monomers are easily released.
Describe the structure of glycogen
- Glycogen is made of a-glucose monomers and is highly branched (more so than starch).
- It also forms an a-helix shape (like starch) which is held together by hydrogen bonds and this makes it compact.
Describe how the structure of glycogen is suited to its function
- It is insoluble and therefore does not affect a cells water potential.
- It is large and insoluble so it does not diffuse out of cells.
- It is compact- a lot of it can be stored in a small space.
- It is highly branched so has more ends that can be acted on simultaneously by enzymes which means it is very rapidly broken down to form glucose monomers,which are used in respiration.
Which organisms store glucose as glycogen
Animals
Why is glycogen more highly branched than starch
Glycogen is found in animals whereas starch is found in plants. Animals have a higher metabolic rate than plants and this includes respiratory rate so more rapidly need glucose. Glucose can be released more rapidly from glycogen due to it being more highly branched meaning enzymes can work on more ends simultaneously.
What is the main difference in structure between cellulose and starch/glycogen
Cellulose consists of b-glucose monomers whereas glycogen and starch are made of a-glucose monomers.
Describe the structure of cellulose
Cellulose has straight, unbranched chains of b-glucose.
The chains run parallel to each other which allows hydrogen bonds to form cross-linkages between adjacent chains.
The hydrogen bonds add collective strength to the molecule.
The cellulose molecules are grouped together to form microfibrils which in turn are arranged into groups called fibres. This structure gives cellulose a high tensile strength.