Calorimetry and Enthalpy Flashcards
Calorimetry
- Science of measuring heat
- Based on observing the temperature change when a body absorbs or releases energy as heat
Calorimeter
A device that can be used to measure thermal energy changes in a chemical reaction
Specific Heat Capacity
- Quantity of thermal energy required to raise the temp of 1 gram of a substance by 1℃
What’s the SI unit for specific heat capacity?
J/g℃
What does high specific heat capacity mean?
The substance requires a larger amount of thermal energy to raise the temp and take a longer time to cool
What does low specific heat capacity mean?
The substances takes less thermal energy to raise the temp and is quicker to cool down
2 Parts of value “q”
- Magnitude
- Sign
Magnitude
Calculated value
Sign
Indicates the type of thermochemical reaction
Enthalpy Definition
- Sum of internal energy
- Product of pressure and volume
What happens when a process occurs at a constant pressure?
The heat involved is equal to the change in enthalpy
Molar Enthalpy Definition
- Enthalpy change associated with a physical, chemical or nuclear change
- Involving one mole of a substance
Note about enthalpy of neutralization
It can be written per mole of the base or acid
4 ways to represent enthalpy changes:
- Thermochemical equation with energy terms
- Thermochemical equation with delta H values
- Molar enthalpies
- Potential energy diagrams