Calculations Flashcards
Relative isotopic mass
The mass of an atom of a particular isotope on the scale where one atom of C-12 has a mass of exactly 12
AKA mass number
Relative atomic mass (Ar)
The weighted average mass of all the atoms in a normal isotopic sample of the element on the scale where 1 atom of C-12 has a mass of exactly 12
AKA mass number
(% isotope 1 x mass isotope 1) + (% isotope 2 x mass isotope 2) / 100
Relative molecular mass (Mr)
Mr of a covalent substance. It is the mass of 1 molecule relative to 1/12 the mass of one atom of C-12
E.g. Cl2 = 71
Relative formula mass (Mr)
Mass of an ionic substance formula unit relative to 1/12 the mass of one atom of C-12
E.g. Na2CO3=106
Mole
The amount of a substance that contains the same number of particles as there are atoms of carbon in 12g of C-12
Represents 6.022x10^23 (Avogardro’s constant); the number of atoms per mole
Molar mass = Mr
Molar mass of a compound is the mass of 1 mole of that compound
One mole of a substance (g/mol) has a mass = to the Mr of the substance
E.g. molar mass MgCl2 = 95.3 g/mol
Empirical formula
Simplest formula of a substance which shows the ratio of the numbers of atoms or ions in each element present
(1) Molecular –> empirical formula
(2) n = (molecular mass/empirical formula mass) x empirical formula
Percentage yield
Theoretical yield = mass of product/reactant
Theoretical yield = (Mr product / Mr reactant) x amount of yield
% yield = (mass of product/max theoretical yield) x 100
Atom economy
Determines efficiency of a reaction in terms of how many atoms of starting material are converted into useful product
Atom economy = mass of required product / total mass of reactants
Atom economy = molar mass of required products / total molar mass of reactants
Stoichiometry
The study and calculation of quantitative relationships between reactants and products in chemical reactions
Molarity
The concentration of a substance in solution, expressed as the number moles of solute per L of solution
Molality
The concentration of a substance in solution, expressed as the number of moles of solute per kg of solvent