C9 Crude Oils and Fuels Flashcards
how is crude oil formed?
over millions of years
as remains of ancient sea animals and plants are pressured under rocks
at a high temperature
without oxygen.
what compounds is crude oil made of?
mostly made of hydrocarbon compounds
as well as mixtures of other carbon compounds
formula of an alkane
CnH(2n+2)
describe bonding in an alkane
saturated hydrocarbon
- SINGLE covalent bond between all carbon atoms: saturated,
- each molecule contains as many hydrogen atoms as possible.
alkane/alkene prefixes
meth (1 carbon atom)
eth (2 carbo atoms)
prop (3 carbon atoms)
but (4 carbon atoms)
which types of hydrocarbon are most useful?
why?
short-chain
ignite more easily, burn well, with non-smoky flame
compare the properties of short and long-chain hydrocarbons
short-chain
- very flammable: less smoky flame,
- low viscosity (thin, runny),
- highly volatile,
- low boiling point.
long-chain
- less flammable: smoky flame,
- high viscosity (thick),
- lower volatility,
- higher boiling point.
what does it mean for something to be highly volatile?
it has a strong tendency to become a gas.
what are products collected from the fractional distillation of crude oil used for?
petrol, kerosene, diesel oil, petroleum gas
what are the lighter fractions from fractional distillation of crude oil used for?
fuel
word equation for complete combustion of hydrocarbons
hydrocarbon + oxygen -> carbon dioxide + water
product of incomplete combustion
carbon monoxide
what is cracking?
breaking long-chain hydrocarbons into short-chained, more useful ones
describe the process of cracking hydrocarbons
- heat them so that they vapourise,
- either pass the vapour over a hot catalyst, or mix with steam and heat to a hotter temp.
what type of chemical reaction happens during cracking?
thermal decomposition reactions
when large molecules split into smaller, more useful ones
formula of alkene
CnH2n
bonding in an alkene
unsaturated
- at least one DOUBLE bond between carbon atoms
compare the properties of alkenes and alkanes
- alkenes generally more reactive,
- both burn in air but alkanes burn better,
(alkenes tend to combust incompletely, producing a yellow, smoky flame) - alkenes react with orange bromine water and turn it colourless, whereas alkanes do not,
which hydrocarbons can and cannot participate in addition reactions?
alkenes can endure addition reactions,
alkanes cannot because all of their carbon atoms are already covalently bonded to a hydrogen atoms
what does cracking produce?
produces alkanes and alkenes
test for alkene
turns orange bromine water colourless