C9 Crude Oil Flashcards
Crude oil
A mixture of comparatively volatile liquid hydrocarbons
Why fractional distillation is used to separate crude oil into fractions
Each fraction has different properties due to the length of the carbon
We can use each fraction for different purposes
How to classify a hydrocarbon as an alkane
A hydrocarbon that contains no double bonds is called an alkane
How to apply a general formula to generate a molecular formula and a displayed formula for a straight-chain alkane
C n H2n+2
Alkane
Any of the series of saturated hydrocarbons
Methane, ethane, propane…
Alkali
Any base substance that dissolves in water to produce OH (hydroxide) ions and neutralise acids
First 10 alkanes
Methane, ethane, propane, butane, pentane, hexane, heptane, octane, nonane, decane
Formula for first 4 alkanes
Methane CH4
Ethane C2H6
Propane C3H8
Butane C4H10
How to classify an alkane
Organic compounds that consist entirely of single-bonded carbon and hydrogen atoms
Name the different fractions of crude oil
Refinary gases
Gasoline
Kerosene
Diesel
Fuel oil
Bitumen
How the trend in colour, viscosity, flammability, and boiling point changes as the length of the hydrocarbon chain changes
As hydrocarbon length increases
boiling point increases
Viscosity increases
Flammability decreases
Colour becomes darker
Process of fractional distallation
Crude oil is heated
Vapour enters fractionating column
The fractions have different boiling points so the vapour will condense at different levels
Use of kerosene
Cooking, lighting, heating
Use of refinary gases
Fuel gas in furnaces or for power generation
Use of gasoline
Mainly used in vehicle engines
Use of diesel
Trains, buses, boats
Use of fuel oil
Heating homes and buildings
Use of bitumen
Primarily used for industrial purposes
How the properties of a fraction of crude oil make it appropriate for its use
Each fraction has different properties due to the length of the carbon chain
How chain length affects the properties of crude oil fractions
As chain length increases viscosity increases
Complete combustion
Complete combustion of a hydrocarbon produces water vapour and carbon dioxide
Incomplete combustion
Happens when supply of air or oxygen is poor
Differences between complete and incomplete combustion
Complete combustion happens when there is a sufficient amount of oxygen supply
Incomplete combustion happens when there is an insufficient amount of oxygen supply
Word equation to describe the complete combustion of a hydrocarbon
Ethane + oxygen ———> carbon dioxide + carbon + water
Word equation to describe the incomplete combustion of a hydrocarbon
ethane + oxygen → carbon monoxide + carbon + water
Why is complete reaction better than incomplete reaction
Less soot produced
More heat produced
Carbon monoxide not produced
Symbol equation for incomplete combustion
CH4 + O2 ⟶ C + 2H2O
Symbol equation for complete combustion
Fuel + O2 → CO2 + H2O
How the production of carbon monoxide in incomplete combustion can be lethal
The CO gas can poison people when exposes to carbon monoxide
How to test for the products of complete combustion
Can test carbon dioxide by passing it through limewater as it turns milky when carbon dioxide is passed through it
If supply of air is limited carbon monoxide is formed
Cracking
The process of breaking down larger heavy hydrocarbon molecules into smaller lighter ones by heating them in the presence of a catalyst
Examples to explain process of cracking and why it’s important to the petrochemical industry
Cracking is the most important process for the commercial production of gasoline and diesel fuel
A word equation to describe cracking
C16H34 → C10H22 + C6H12
Alkene
A type of organic molecule that contain a carbon-carbon (C=C) double bond
Similarities between alkane and alkene
Both are hydrocarbons
Both only made up of hydrogen and carbon only
Differences between alkane and alkene
Alkanes are saturated hydrocarbons consisting of single bonds
Alkenes are unsaturated hydrocarbons which include a carbon-carbon double bond
Examples of alkene
Ethene
Propene
Hexene
Cyclobutene
Chemical test to show alkene is present
A simple test with bromine water
An alkene turns brown bromine water to colourless
Equation for reaction of alkene and bromine water
R - CH2=CH2 - R + Br2 ——-> R - CH2 r - CH2Br - R
Why is CH3COOC3H7 not an alkane
Contains oxygen
Homologuous series
Group of organic compounds that react in a similar way
Saturated compound
Chemical compound that resists addition reactions
Waste products in complete combustion
Carbon dioxide and water vapour
What is oxidised in complete combustion
Carbon and hydrogen
Where does crude oil come from
Formed from remains of plants and animals mainly plankton that died millions of years ago and buried in mud
Organic compound
Anything containing carbon
Why are short-chain hydrocarbons make good fuels
They’re flammable
What type of reaction is cracking
Thermal decomposition reaction
Catalytic cracking
Long chain molecules split apart on surface of specks of catalyst
Steam cracking
Cracking hydrocarbons by vapourising them
Mix with steam
Heat with high temperature
Why do alkenes have double carbon bond
They have double bond between two of the carbon atoms in their chain
Functional group
Group of atoms in a molecule that determine how that molecule typically reacts