c8 rates of reaction Flashcards

1
Q

mean rate of reaction
(reactant)

A

quantity of reactant used/time taken

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2
Q

mean rate of reaction (product)

A

quantity of product formed/time taken

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3
Q

unit of rate of reaction

A

g/s or cm3/s

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4
Q

when plotting a graph for rate of reaction what goes in the x-axis?

A

time

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5
Q

when do you draw a tangent on a specific point and calculate the gradient of the tangent?

A

to measure the rate of reaction at a specific time

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6
Q

factors which affect the rates of chemical reactions include:

A

-the concentration of reactants in the solution
-the pressure of reacting gasses
-the surface area of solid reactants
-the temperature
-presence of a catalyst

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7
Q

as you increase the temperature

A

the rate of reaction increases but same amount of products produced at the end

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8
Q

what is concentration?
-increasing concentration increases rate

A

the number of particles dissolved in a given volume of solvent

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9
Q

what is pressure
increased pressure=increased number of particles

A

a measurement of the number of particles in a given volume of gas

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10
Q

is the surface area of a block or powder of that block greater?

A

powder surface area greater

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11
Q

highest rate of reaction means

A

steepest gradient

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12
Q

what does collision explain?

A

how various factors affect the rates of reactions

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13
Q

chemical reactions can only occur when

A

reacting particles collide with each other and with sufficient energy

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14
Q

what is the activation energy?

A

the minimum amount of energy that particles must have to react is called the activation energy

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15
Q

what does increasing the concentration of reactants in solution, the pressure of reacting gases and the surface area of solid reactants increase?

A

the frequency of collisions so increases the rate of reaction

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16
Q

increasing the temperature increases the frequence of collisions. What does this do?

A

this makes the collisions more energetic,and so increases the rate of reaction

17
Q

increasing temperature

A

particles have more kinetic energy
move faster
more collisions per second
collide with more energy

18
Q

larger surface area (lump cut up into smaller parts)

A

more particles exposed to other reactants more frequent collisions

19
Q

catalysts

A

reduce the amount of energy needed for particles to have a successful collision

20
Q

enzymes act as catalysts in?

A

biological systems

21
Q

what are reversible reactions?
example: A + B ⇌C + D

A

reactions where the products of the reaction can react to produce the original reactions

22
Q

the direction of reversible reactions can be changed by?

A

changing the conditions
For example: heat
ammonium chloride ⇌ ammonia + hydrogen chloride cool

23
Q

if a reversible reaction is exothermic in one direction, what is it in the opposite direction?

A

endothermic

24
Q

in reversible reactions, one reaction is exothermic and the other is endothermic so the same amount of energy is transferred in each case.
give an example

A

endothermic
ammonium chloride ⇌ ammonia + hydrogen chloride exothermic

25
Q

when a reversible reaction occurs in apparatus which prevents the escape of reactants and products, when is equilibrium reached?

A

when the forward and reverse reactions occur exactly at the same rate

26
Q

dynamic equilibrium

A

in a reversible reaction,rate of the forward reaction is equal o the rate of the backward reaction ina closed system

27
Q

three conditions affect the rate of reaction:

A

-temperature
-pressure
-concentration

28
Q

what is le chatlier’s principle?

A

When a reaction has reached dynamic equilibrium and a change occurs the position of equilibrium will move to counteract the change. This concept is known as Le Chatelier’s principle.

29
Q

required practical:the disappearing cross reaction
sodium thiosulfate solution + hcl–>sulfur (solid). what does sulfur do to the solution?

A

sulfur makes the solution go cloudy (turbidity)

30
Q

steps for disappearing cross reaction:

A

-use a measuring cylinder put 10cm3 of sodium thiosulfate in conical flask
-place the conical flask onto a printed black cross
-add 10cm3 of hydrochloric acid into the conical flask
-swirl solution , start a stopwatch

31
Q

after some time, what happens to the solution?

A

it turns cloudy, stop clock when cross no longer visible

32
Q

repeat again using?

A

lower concentrations of sodium thiosulfate

33
Q

repeat the whole experiment and ?

A

calculate the mean with no anomalies included

34
Q

reproducibility

A

can be repeated with different people or equipment but still same result

35
Q

what is the problem with this experiment?

A

different eyesights , people might see cross for longer however same size printed cross helps solve this