C8 - Rates And Equilibrium Flashcards

1
Q

E. Mean rate of reaction?

A

Quantity of reactant used / time
OR
Quantity of product formed / time

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2
Q

How to calculate the rate of reaction at a specific time? (On a graph)

A

Draw a tangent!!!

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3
Q

Gradient of the line shows…

A

Rate at that time.

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4
Q

D. Activation energy.

A

The minimum amount of energy that particles must have before they can react.

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5
Q

What increases the rate of reaction?

A
  • Surface area
  • Pressure
  • Temperature
  • Catalyst
  • Concentration
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6
Q

Why does increasing the surface area of a reactant increase the rate of reaction?

A

Because it means more particles are exposed and so the number of collisions increases, and so the number of successful collisions increases.

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7
Q

Why does increasing the temperature increase the rate of reaction?

A

Because particles collide more often, meaning there is more successful collisions. Also the particles collide with more energy so an increases proportion of particles exceeding the activation energy has a greater effect on rate then increased frequency of collisions.

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8
Q

Why does increasing the concentration of reactants increase the rate of reaction?

A

Increases the frequency because there is more particles, and so increases the number of successful collisions, which increases the rate.

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9
Q

Why does increasing the pressure increase the rate of reaction?

A

Because the particles are colder together, so the number of collisions increases, and so does the number of successful collisions.

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10
Q

What do catalysts do?

A

Speed up the rate of the reaction, but not used up in the reaction - remains chemically unchanged. So can be used more then once.

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11
Q

Catalysts are used to….?

A

Increase rates and reduce energy cost.

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12
Q

Increasing pressure favours…

A

reaction that forms fewer gas molecules

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13
Q

Decreasing pressure favours…

A

reaction that forms more gas molecules

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14
Q

Increasing temperature favours….

A

endothermic reaction

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15
Q

Decreasing temperature favours…

A

exothermic reaction

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16
Q

Le Chatetier’s principle?

A

whenever a change in conditions is introduced to a system at equilibrium, the position of equilibrium shifts to cancel out the change

17
Q

Concentration increase = …

A

equilibrium shifts so that more products are formed, until equilibrium is reached

18
Q

Concentration decrease = …

A

equilibrium shifts so that more reactants are formed, until equilibrium is reached

19
Q

For Exothermic reactions:

  • temp increase = …
  • temp decrease = …
A
  • yield decrease

- yield increase

20
Q

For Endothermic reactions:

  • temp increase = …
  • temp decrease = …
A
  • yield increase

- yield decrease