C8 Flashcards
What are hydrocarbons
compounds that contain hydrogen and carbon only.
What is crude oil
-a complex mixture of hydrocarbons
-containing molecules in which carbon atoms are in chains or rings
-an important source of useful substances(fuels and feedstock for the petrochemical industry)
-a finite resource.
Process of separation of crude oil
-by fractional distillation
-heated crude oil enters near the bottom of a tall fractionating column which is hot at the bottom and gets cooler towards the top
-vapours from the oil rise through the column
-vapours condense when the temp of the column is cool enough
-liquids are led out of the column at different heights.
-some hydrocarbons with low bps leave the column as gas as do not condense
-ones with high bps leave the column as hot liquid bitumen.
names and uses of different fractions
gases-fuel for domestic heating and cooking
petrol-fuel for cars
kerosene-fuel for aircrafts
diesel oil-fuel for some cars and trains
fuel oil-fuel for large ships and in some poweer stations
bitumen-used to surface roads and rooves
How hydrocarbons in different fractions differ from each other
at top of column:
-smaller molecules
-low bp
-very volatile
-flows easily
-ignites easily
large molecules:
-high bp
-not very volatile
-not very viscous/dont flow easily
-does not ignite easily
-at bottom of column because column hotter at bottom.
-all mostly members of the alkane homologous series.
What is a homologous series
-series of compounds which:
-have same general formula
-differe by CH(small 2) in molecular formulae from neighbouring compounds
-show a gradual variation in physical properties as exemplified by their bps
-have similar chemical properties.
complete combustion of hydrocarbon fuels
CO2 and water are produced
energy is given out(exothermic)
why can the incomplete combustion of hydrocarbons produce carbon and carbon monoxide
-happens when supply of oxygen is poor
-produces those because part of the carbon is not completely oxidised/ doesnt all react so produces carbon monoxide/soot.
why is carbon monoxide a toxic gas
-absorbed by the lungs and binds with haemoglobin in red blood cells
-reduces capacity of blood to carry O2
-can cause drowsiness or death/ fall unconscious.
soot
carbon released as fine black particles
-smoky flames and deposited as soot
-can cause breathing problems and blackens buildings
-blocks boilers/other appliances or cause fire.
how impurities in hydrocarbon fuels result in sulfur dioxide
-many hydrocarbon fuels naturally contain sulfur impurities
-When fuels burnt, sulfur oxidises to form sulfur dioxide
formation of acid rain and problems
-sulfur dioxide dissolves in water in clouds to form sulfourus acid
-O2 in air reacts with this to form sulfuric acid
-mixture from these two acids fall from clouds as acid rain
-damages natural and built environments
-reacts with metal and rocks(limestone) weakening and damaging buildings and statues
-damages plants and trees making them lose leaves and die
-makes rivers and lakes too acidic for some aquatic wildlife to survive
oxides on N2
-when fuels are burnt at high temps, N2 and O2 from air react to produce oxides of N2
-atmospheric pollutants
-can react in sunlight to produce smog
-N2 dioxide is toxic
-can cause bronchitis and other lung conditions
-dissolves inj water in clouds creating acidic sol adding to acid rain
advantages and dis of using hydrogen over petrol as fuel in cars
petrol is non-renewable and takes lots of energy to produce
hydrogen produced from natural gas or crude oil is also finite but nit with elevtrolysis of water
incomplete combustion happens with petrol as fuel producing carbon and carbon monoxide
water only product of combustion with H2
fewer H2 filling stations so ncould make it more hard to runn a car fuelled with H2
both very flammable
H2 releases more enrgy per kg than petrol
petrol liquid at room temo and H2 gas.
kerosene, petrol, diesel oil and methane
k,p,do-non-renewable fossil fuel from crude oil
m-non-renew fossil from natural gas