C7 Flashcards
General formula for carbon atoms and hydrogen atoms
CnH (2n+2) E.g. Méthane = CH4 Éthane = C2H6 Propane = C3H8 Butane = C4H10
Hydrocarbons
Make up majority of the compounds of crude oils.
Most of these are called alkanes.
Crude oil
A finite resource.
Consisting mainly of plankton that was buried in the mud, crude oil is the remains of ancient biomass.
Alkanes to alkenes
Long chain alkanes are cracked into short chain alkenes.
Alkenes
Hydrocarbons with a double bond (some are formed during the cracking process)
Properties of alkenes
More reactive than alkanes and react with bromine water.
Bromine water changes from orange to colourless in the presence of alkenes.
Unsaturated - some carbon - carbon bonds are double bonds.
Cracking
Breaking down of long chain hydrocarbons into smaller chains.
Smaller chains more useful.
Done in various methods.
Catalytic cracking
Heavy fraction is heated until vaporised.
After vaporisation, vapour is passed over a hot catalyst forming smaller, more useful hydrocarbons.
Steam cracking
Heavy fraction heated until vaporised
After vaporisation, the vapour is mixed with steam, heated to high temp forming smaller more useful hydrocarbons.
Fractions
Hydrocarbons in crude oil can be split into fractions.
Each fraction has molecules with a similar no. of carbon atoms in them.
The process to do this is called fractional distillation.
Alkanes
Saturated - all carbon - carbon bonds are single
A homologous series (same properties and general formula)
Separating crude oil
Fractional distillation: the oil is heated to 400 degrees, it becomes a vapour. There is a temp. gradient of cold at the top and hot at the bottom of the fractionating column.
The gases then rise, when they reach their boiling point they condensé and become a liquid.
Using fractions
Processed to produce field and feed stick for petrochemical industry:
Gas - LPG, bottled gas.
Gasoline - petrol
Kerosene - aviation fuel
Diesel oil - diesel cars and lorries
Fuel oil - ships
Naptha-solvents, polymers, detergents, prep of rubber compounds
Combustion
To burn in oxygen/air to produce carbon dioxide and water.
Complete combustion
Burnt with enough/excess oxygen.
Methane + oxygen - water and carbon dioxide
CH4 + 2O2 - 2H2O + CO2
Incomplete combustion
Burnt with not enough oxygen.
Methane + oxygen - water + carbon monoxide
CH4 + 1&halfO2 - 2H2O + CO
Methane and oxygen - water + carbon
CH4 + O2 - 2H2O + C
Tests: hydrogen, carbon dioxide, water
Hydrogen: lit spill squeaky pop.
Carbon dioxide: bubbles through lime water, lime water turns cloudy.
Water:CuSO4 + 5H2O - CuSO4 . 5H2O
Tests: chlorine and oxygen
Chlorine: bleached damp litmus paper
Oxygen: RELIGHTS a LIT spill
Decane -
Decane - pentane and propene + ethane
C10H22 - C5H12 + C3H6 + C2 + H4