C6.1 Improving processes and products Flashcards
What elements do plants need?
Nitrogen , Phosphorus , Potassium
If a plant receives a limited supply of these elements…
Plants will not grow well and show symptoms of mineral deficiency
Lack of nitrogen causes?
Poor growth , yellow leaves
Lack of phosphorus causes?
Poor root growth , discoloured leaves
Lack of Potassium causes?
Poor fruit growth , discoloured leaves
Fertilisers
Substance that replenish and replace elements used by plants as they grow
In what form can plant roots absorb these elements
When they are in a water soluble form :
- nitrate ions ( NO3-)
-phosphate ions ( PO34-)
-potassium ions ( K+)
-ammonium ions ( NH4+)
NPK fertilisers
Provide nitrogen phosphorus and potassium in water soluble compounds
What is the Haber Process ?
Manufactures Ammonia from nitrogen and hydrogen
-reversible reaction
Word Equation for the Haber Process:
N2 ( g ) + 3H2 ( g ) <——> 2NH3 ( g )
Which raw materials are required for the Haber Process?
-air
-natural gas
-steam
What percent of ammonia is used to make fertilisers?
80%
The atmosphere consists of ___% nitrogen
78%
How is nitrogen manufactured for the Haber Process?
Fractional distillation of liquified air
How is hydrogen manufactured for the Haber Process?
Reacting natural gas ( methane ) with steam
What are the conditions required for the Haber Process?
-presence of iron catalyst
-high temperature
-high pressure
Ammonium nitrate
NH4NO3
Ammonium sulfate
(NH4)2SO4
Ammonium Phosphate
(NH4)3PO4
Potassium Nitrate
KNO3
Which compounds of fertilisers can we make in the lab ?
-potassium sulfate
-ammonium sulfate
Describe the method of making potassium sulfate in the lab (6)
Made from potassium hydroxide ( KOH) and sulphuric acid ( H2S04 )
-add KOH to a conical flask alongside a few drops of phenolphthalein indicator
-add dilute sulphuric acid from a burette , stopping when the indicator changes from pink to colourless
-add ‘activated charcoal’ , this binds/attracts to the phenolphthalein which can then be easily filtered out of the mixture to avoid including any impurities
-warm the filtrate to gently evaporate the water , leaving potassium sulfate behind
Why is single indicator ( phenolphthalein or methyl orange ) used instead of universal indicator ?
This provides a distinct colour changes , so adding this enables you to determine the exact point when the alkali has been neutralised
How can the experiment be made more accurate ?
- use a white tile which makes the colour change more distinct and easier to see
How is ammonium sulfate made in the lab?
-place dilute ammonia solution in a conical flask with methyl orange indicator
-add dilute sulphuric acid from a burette / dropping pipette , stopping when the indicator changes from yellow to red
-when reaching the end point ( distinct colour change ) , add a little extra ammonia solution to ensure the reaction is complete
What are some hazards when making ammonium sulfate and how can these be prevented ?
-ammonia and potassium hydroxide are highly alkaline and irritant : wear gloves , eye protection and lab coat
-ammonia gives off an irritating sharp smell : carry out the experiment in a fume cupboard or be cautious when inhaling near the experiment
Batch process
Small amount at one time eg in a school lab
Continuous process
Large amounts and continue all the time eg large industrial processes
Features of batch process are?
-low rate of production
-low cost
-large no of people / workers needed
-frequent shut down periods
-low ease of automating the process
Features of continuous processes are?
-high rate of production - ADV
-high cost of equipment - DISADV
-small no of workers needed - ADV
-rare shut down periods - ADV
-high ease of automating
What is the difference between making substances in a lab vs industrially in a factory ?
Lab starts off with pure substances bought from chemical manufacturers , whereas fertiliser factors start with raw materials ( which must be purified either before or the whole substance after )
What type of reaction is the Haber Process?
Exothermic
Conditions for the Haber Process ?
-pressure of 200 ATM ( 20MPa )
-a temperature of 450 degrees Celsius
-an iron catalyst
Under these usual conditions , what is the equilibrium yield of ammonia ?
30%
Despite the low equilibrium yield , why is ammonia still made ( The Haber Process ) conducted under such conditions?
- if pressure is increased , equilibrium position moves to the right and equilibrium yield of ammonia increase
-however this is extremely hazardous and also expensive
-the higher equilibrium yield does not justify the additional costs , so manufacturers must comprise with a lower pressure
What factors determine the temperature chosen for the Haber Process?
-if temp is increased, equilibrium position moves to the left , decreasing yield of ammonia therefore a high equilibrium yield is favoured by a low temperature
-therefore manufacturers have to compromise with temp and pick a temperature ( 450 C ) low enough to produce a reasonable yield but high enough to achieve a good rate of reaction
-additionally , the iron catalyst works more efficiently about 400 C
What other conditions are chosen to increase yield of ammonia during the Haber Process?
-mixture of gases leaving the reaction vessel is cooled so that ammonia is liquefied
-this allows ammonia to be removed and products ( unreacted nitrogen and hydrogen ) to be recycled
-this improves the overall yield to 95%
Uses of sulfuric acid?
Fertilisers , oil refining , metal extraction , making paints and polymers
How many steps are needed to synthesise sulfuric acid?
3 steps , including the Contact process
Which raw materials are required to make sulfuric acid?
-sulfur
-air ( any source of oxygen )
-water
Stage 1
sulfur burns in air to produce sulfur dioxide
-exothermic reaction
Word equation for stage 1 of synthesising sulfuric acid?
S + O2 ——> SO2
Stage 2 of producing sulfuric acid?
The Contact Process:
-sulfur dioxide and oxygen react together to produce sulfur trioxide
-exothermic reaction
Word equation for the Contact Process ( Stage 2 ) ?
2SO + O2 <——> 2SO3
What are the conditions chosen for the (reversible) Contact process?
-pressure of 2ATM
-temperature of 450 degrees Celsius
-a vanadium oxide catalyst , V2O5
Produces an equilibrium yield of 96%
Stage 3 of producing sulfuric acid?
Sulfur trioxide is converted tosulfuric acid
Word equation for stage 3?
H20 + SO3 ——> H2SO4
Renewable raw materials can be…
Replaced as they are used , and technically should not run out
How is ethanol made?
Via the process of fermentation , relies on yeast
What is the role of yeast during fermentation?
-it contains enzymes which catalyse the conversion of glucose solution to carbon dioxide and ethanol
Word equation for fermentation ?
Glucose ——> Carbon Dioxide + Ethanol
Chemical equation for fermentation including state symbols?
C6H12O6 (aq) ——> 2CO2 (g) + 2C2H5OH (aq)
How can fermentation be carried out in a school laboratory?
-place glucose solution and yeast in a conical flask
-use a rubber bung to seal the conical flask , collecting the gas and bubbling it through limewater
Non renewable materials are…
Materials that are used faster than they can be replaced
How is ethanol produced from non renewable materials
Ethene is obtained from crude oil , and is then hydrated to form ethanol
What type of reaction is the hydration of ethene ?
Exothermic and reversible
Chemical equation for the hydration of ethene?
C2H4 (g) + H2O (g) <——> C2H5OH ( g )
What is the state of steam?
Gas
- H2O with the state symbol (g)
Why can’t the hydration of ethene be carried out in a school laboratory?
-requires temp of 300 degrees Celsius
-pressure of 60ATM
-presence of a phosphoric acid catalyst
What are the ways in which ethanol is produced?
Fermentation of sugars and Hydration of ethene
Positive features of fermentation of sugars?
-low costs of raw materials
-can be carried out in school lab ; as it is carried out in moderate conditions
-low energy requirements
Negative features of fermentation of sugars?
-low rate of reaction
-low percentage yield
-low purity of product ( requires fractional distillation and filtering )
Positives of hydration of ethene?
-high rate of reaction
-high percentage yield
-high purity of product ( no by products )
Negatives of hydration of ethene?
-high cost of raw materials
-high temp and pressure
-high energy requirements
What is an ore?
A rock or mineral which contains enough metal to make it economical to extract it - the value of the metal is more than the cost of extracting it
What metal compound is found in malachite?
Copper carbonate
What metal compound is found in bauxite?
Aluminium oxide
What metal compound is found in haematite?
Iron ( III ) oxide
Where does carbon lie in the reaction series?
In between aluminium and zinc
What possible methods could be used to extract metal from its ores?
-electrolysis
-if the metal is less reactive than carbon , cheaper methods are used instead by heating the metal with carbon or carbon monoxide
Why is electrolysis not used to extract metal from its ores?
Electricity is expensive
Describe the first stage of extracting copper from copper (II) sulfide : word equation , chemical equation
Stage 1 : the copper (II) sulfide is “roasted” in air
Copper (II) sulfide + oxygen ——> copper (II) oxide + sulfur dioxide
2CuS(s) + 3O2(g) ——> 2Cu(s) + CO2(g)
Describe the second stage of extracting copper from copper (II) sulfide: word equation , chemical equation
Stage 2:Copper oxide is heated with carbon
Copper(II) oxide + carbon ——> copper + carbon dioxide
2CuO(s) + C(s) ——> 2Cu(s) + CO2(g)
Is the extraction of copper a redox reaction?
Yes