C6.1 Flashcards
what are the three essential elements needed by plants?
nitrogen, phosphorus and potassium
what happens is plants have limited supply of their essential elements in the soil?
they will show signs of mineral deficiency and the quality and yield of food will be reduced
what are the symptoms of plants if they are nitrogen deficient?
poor growth and yellow leaves
what are the symptoms of plants if they are phosphorous deficient?
poor root growth and discoloured leaves
what are the symptoms of plants if they are potassium deficient?
poor fruit growth and discoloured leaves
what are fertilisers?
substances added to soil that replace elements and nutrients used by plants as they grow
in what conditions can plant roots only absorb elements ?
if they are in a water soluble form
what does: nitrogen ammonium phosphorus potassium have to be in order for plants to be able to absorb them?
nitrate ions - NO3 -
ammonium ions - NH4 +
phosphate ions - PO4 3-
potassium ions - K +
what is the name for fertilisers that provide nitrogen, phosphorus and potassium in water soluble compounds known as?
NPK fertilisers
what is the Haber process?
an industrial process to make ammonia from nitrogen an hydrogen
what is the chemical equation for the Haber process?
N2(g) + 3H2(g) <=> 2NH3 (g)
how many tonnes of ammonia are manufactured in the world per year?
150 million
what are the raw materials required for the Haber process?
air, natural gas and steam
how is nitrogen manufactured?
by fractional distillation of liquefied air (air is 98% nitrogen)
how is hydrogen manufactured?
by reacting natural gas (mostly methane) with steam
what happens in a fertiliser factory?
several different processes are integrated so a range of compounds for fertilisers can be made
name 4 compounds for fertilisers that can be created in a fertiliser factory
1) ammonium nitrate - NH4NO3
2) ammonium sulfate - (NH4)3SO4
3) ammonium phosphate - (NH4)3PO4
4) potassium nitrate- KNO3
what are the 4 steps to making potassium sulfate in a lab?
1) put dilute potassium hydroxide into a conical flask and add a few drops of phenolphthalein indicator to enable you to determine when the alkali has been neutralised
2) add dilute sulfuric acid from a burette or dropping pipette stopping when the indicator changes from pink to colourless
3) add activated charcoal which attracts the phenolphthalien and then filter the mixture to remove the charcoal and phenolphthalein attached to it
4) heat filtrate to make water evaporate leaving potassium sulfate behind but it shouldn’t be heated to dryness
what can potassium sulfate be made from?
potassium hydroxide and sulfuric acid
what are the 3 steps of making ammonium sulfate in a lab?
1) place dilute ammonia solution in a conical flak with methyl orange indicator
2) add dilute sulfuric acid from a burette or dropping pipette stopping when the indicator changes from yellow to red
3) when you reach the end point add a little extra ammonia solution to ensure the reaction is complete and any remaining ammonia will be lost in evaporation
what are the hazards with making ammonium sulfate in the lab?
1) ammonia solution releases small amounts of ammonia in gas state which has an irritating sharp smell so you have to try not breath it in
2) excess ammonia is given off in the gas state when the solution is warmed
what is the batch process? when is it used?
a chemical process that makes products in limited amounts at different times and is used in the lab
what is the continuous process? when is it used?
chemical process that makes products in large amounts at a time and is used in industrial processes and are rarely shut down
what is the difference between the materials used in a laboratory and the materials used in fertiliser factories?
laboratories use pure substances bought from a chemical manufacturer but fertiliser factories use raw materials that are either purified before or after the reaction
what is the difference between the rate of production in the batch process vs the continuous process?
batch has low rate continuous has high
what is the difference between the relative cost of equipment in the batch process vs the continuous process?
batch is low continuous is high
what is the difference between the number of workers needed in the batch process vs the continuous process?
batch has a large number but continuous has low
what is the difference between the shut down periods in the batch process vs the continuous process?
batch have frequent shut down periods while continuous are rare
what is the difference between the ease of automating the process in the batch process vs the continuous process?
batch is low and continuous is high
what are the conditions used for the Haber process? (temperature and pressure)
pressure of 200 atmospheres (20 MPa)
temerature of 450C
what type of catalyst is used in the Haber process?
iron catalyst
what yield do the conditions usually chosen for the Haber process create?
a 30% equilibrium yield of ammonia
what would happen if the pressure increased in the chosen conditions fro the Haber process?
the equilibrium yield of ammonia would increase but it would be hazardous and expensive and the higher yield wouldn’t justify the additional costs of the high pressure
what type of reaction is the forward reaction of the Haber process?
exothermic
what type of reaction is the backward reaction of the Haber process?
endothermic
what would happen if you increased the temperature of the chosen conditions of the Haber process?
the equilibrium yield would decrease
why is 450C chosen as the temperature for the Haber process?
because it is a compromise. low enough to achieve a reasonable equilibrium yield but high enough to achieve reasonable rate of reaction
what temperature does the catalyst in the Haber process work at best?
400C
why are the mixture of gases in the Haber process cooled?
so that the ammonia is liquefied allowing it to be removed and the un-reacted nitrogen and hydrogen to be recycled improving the overall yield to 97%
what are the 3 raw materials required to make sulfuric acid?
sulfur, air and water
what happens in the first stage of creating sulfuric acid?
sulfur burns in air to produce sulfur dioxide
what is the equation for the first stage of creating sulfuric acid?
sulfur + oxygen -> sulfur dioxide
S (s) + O2(g) -> SO2(g)
what is the name of the second stage of creating sulfuric acid?
the contact process
what is the contact process
the industrial process that makes products in large amounts over time
what happens in the contact process?
sulfur dioxide and oxygen react together to produce sulfur trioxide
what is the equation for the contact process?
2SO2(g) + O2(g) <=> 2SO3(g)
what are the conditions usually chosen for the contact process when making sulfur trioxide? (pressure/temp/catalyst)
pressure of 2 atmospheres (200 kPa)
temperature of 450C
vanadium oxide catalyst
what is the yield in the chosen conditions for creating sulfur trioxide when making sulfuric acid?
98%
what happens in the third stage of making sulfuric acid?
sulfur trioxide is converted into sulfuric acid
what is the equation for he third stage f making sulfuric acid?
water + sulfur trioxide -> sulfuric acid
H2O(l) + SO3(g) -> H2SO4 (aq)
what would happen if you increased the chosen pressure for the reaction creating sulfur trioxide?
it would be unnecessary because 2 atmospheres is enough to push the gases through the converter and 3 is not necessary
what would happen if you increased the temperature of the reaction to create sulfur trioxide?
the equilibrium yield of sodium trioxide would decrease as a high equilibrium yield is favoured by a low temperature
why is the temperature of 450C chosen when creating sodium trioxide?
it is a compromise that is low enough to achieve a reasonable equilibrium yield but a high enough rate of reaction and the catalyst only works above 380 C
why is stage three of creating sulfuric acid carried out in two pahses?
because it is an extremely exothermic reaction that would produce a hazardous acidic mist
what is the first stage of the third phase of creating sulfuric acid?
sulfur trioxide is passed through concentrated sulfuric acid to make a compound called oleum
what is the equation for the first stage of the third phase of creating sulfuric acid?
H2SO4(l) + SO3 (g) => HS2O7 (l)
what is the second stage of the third phase of creating sulfuric acid?
the oleum created in the first phase is then added to water and the reaction makes a larger volume of concentrated sulfuric acid
what is the equation for the second stage of the third phase of creating sulfuric acid ?
H2S2O7 (l) + H2O (l) => 2H2SO4 (aq)
what are renewable raw materials?
materials that can be replaced as they are used and in theory should not run out
what is ethanol made from?
plant sugars using fermentation
how is ethanol made? (renewable)
yeast cells are single celled fungi and catalyse the conversion of glucose solution into carbon dioxide and ethanol
what is the equation for making ethanol? (renewable)
glucose -> carbon dioxide + ethanol
C6H12O6 (aq) -> 2CO2 (g) + 2C2H5OH (aq)
what happens if the temperature is too low or too high when using yeast?
the yeast cells become inactive if it is too low and denature if it is above 50C
what conditions is fermentation carried under?
35C and normal atmospheric pressure (100 kPA)
what are non renewable raw materials?
material that can be used faster than they can be replaced and will run out one day if you continue using them
how is ethanol made? (non renewable)
it is obtained from crude oil which is non renewable and can be produced through the hydration of ethene
what is hydration?
a reaction where water is added
what is the equation fro making ethanol? (non renewable)
ethene + steam -> ethanol
C2H4 (g) + H2O (g) <=> C2H50H (g)
where can renewable ethanol be produced?
in the lab and with industrial fermentation with more complex equipment but the same conditions
where can non renewable ethanol be produced?
only as an industrial process
what are the conditions required for creating non renewable ethanol? temperature/pressure/catalyst
temperature of 300C
pressure of 60 atmospheres
catalyst of phosphoric acid
what is the difference between the cost of raw material for fermentation of sugars vs hydration of ethene?
fermentation is a low cost but hydration is a high cost
what is the difference between the conditions for fermentation of sugars vs hydration of ethene?
fermentation : moderate temperature and normal pressure
hyrdation: high temperature and pressure
what is the difference between the energy requirements for fermentation of sugars vs hydration of ethene?
fermentation requires low energy but hydration requires high
what is the difference between the rate of reaction for fermentation of sugars vs hydration of ethene?
fermentation has a low rate but hydration has a high rate
what is the difference between the percentage yield for fermentation of sugars vs hydration of ethene?
fermentation : low - 15%
hydration: high - 95%
what is the difference between the purity of the product produced for for fermentation of sugars vs hydration of ethene?
fermentation: low - needs filtering and fractional distillation
hydration: high - there are no by-products
what will the choice for production of ethene depend upon?
- availability of materials
- cot of materials
- cost of energy required
what is an ore?
a rock or mineral that contains enough metal/metal compound to make it economical to extract the metal
what metal compound is found in the ore malachite?
copper carbonate
what metal is found in the ore bauxite?
aluminium oxide
what metal is found in the ore haematite?
iron (III) oxide
what must happen to an ore in order to separate a metal from an ore?
the ore must be mined and processed to separate the metal from the other substances in the ore. the metal is extracted from the pure metal compound using a chemical reaction
what does the method of extracting a metal from its ore depend upon?
the position of the metal in the reactivity series
what type of met to extract metal from an ore if the metal is less reactive than carbon?
cheaper methods are used
why isnt electrolysis used to extract all metals?
because it is an expensive process
how are copper and iron extracted from their ores?
they are extracted by heating their compounds with carbon or carbon monoxide because they are less reactive than carbon
how many stages are required to extract copper from copper sulfide?
two
what happens in the first stage of extracting copper from copper sulfide?
coper(ll) sulfide is “roasted” in air