C6 Rate of Chemical Change Flashcards
Calculating the rate of reaction (g/s or cm3/s)
Quantity of reactant/product (g or cm3)
Time (s)
Why do chemical reactions occur?
Reacting particles collide with each other and with sufficient energy
What is the minimum amount of energy required when particles collide called?
Activation energy
Why does an increased concentration cause a faster reaction?
There are more particles in the same volume so there are more frequent collisions
Why does an increased pressure cause a faster reaction?
The particles are closer together so there are more frequent collisions
Why does an increased surface area cause a faster reaction?
There are more particles available to collide so there are more frequent collisions
Why does an increased temperature cause a faster reaction?
The particles move faster so there are more frequent collisions and the collisions are harder so more reach the activation energy
Why does using a catalyst cause a faster reaction?
A catalyst provides an alternative reaction pathway with a lower activation energy. Catalyst is not used up in the reaction
What is equilibrium?
In a closed system equilibrium is reached when the forward and reverse reactions occur at exactly the same rate
What is Chatilier’s principle?
If a system is at equilibrium and a change is made to any of the conditions the reaction will respond to counteract the change.
What is the affect of increasing the concentration of the reactants on the position of equilibrium?
The position of equilibrium shifts to the right and the yield of products is greater
What is the affect of increasing the concentration of the products on the position
of equilibrium
The position of equilibrium shifts to the left and the yield of the reactants is greater
What is the rule for increasing pressure?
If pressure is increased equilibrium will shift to the side with
What is the rule for increasing temperature?
If temperature is increased equilibrium will shift in the endothermic direction to reduce the temperature
What is the rule for decreasing temperature?
If temperature is decrease equilibrium will shift in the exothermic direction to increase the temperature