C6 - Global Challenges Flashcards
what are the 3 essential elements needed by plants
- nitrogen
- phosphorus
- potassium
> plants don’t grow well if these are limited
what are some symptoms of mineral deficiencies in plants
- poor growth
- discoloured leaves
what are fertilisers
- substances that replace the essential elements used by plants as they grow
what conditions must fertilisers be in, so that plant roots can easily absorb them
- ions in water soluble form
what ions are commonly found in fertilisers containing all 3 essential elements
- Nitrogen: nitrate ions (NO 3-) and ammonium ions (NH4+)
- Phosphorous: phosphate ions (PO4 3-)
- Potassium: potassium ions (K+)
what are NPK fertilisers
- fertilisers that provide all 3 essential elements in the form of water soluble compounds
what are some examples of NPK fertilisers
- ammonium nitrate NH4NO3
- ammonium sulfate (NH4)2 SO4
- ammonium phosphate (NH4)3 PO4
- potassium nitrate KNO3
name the raw materials needed to make ammonium sulfate
- sulfur (makes sulfuric acid)
- natural gas
- air (all 3 make ammonia)
- water
> ammonia + sulfuric acid —> ammonium sulfate
name the raw materials needed to make ammonium phosphate
- phosphate rock
- sulfur —–> phosphoric acid
- natural gas
- air —–> ammonia
- water
> ammonia + phosphoric acid —> ammonium phosphate
how can potassium sulfate be made in the lab
- pour dilute potassium hydroxide into conical flask + add phenolphthalein indicator
- add dilute sulfuric acid from a burette until neutralised
- add activated charcoal to remove indicator, then filter out to remove
- warm filtrate to leave crystals behinds (don’t heat to dryness)
how can ammonium sulfate be made in the lab
- pour dilute ammonia solution into conical flask + add methyl orange indicator
- add dilute sulfuric acid from burette until neutralised
- at the end-point add a little extra ammonia solution to ensure the reaction is complete
- add activated charcoal to remove indicator + filter to remove
- warm the filtrate leaving crystals behind (don’t heat to dryness)
what is a batch process
- when you make a small amount of substance at a time and once it’s made you stop the reaction
what is a continuous process
- when large amounts of substances are made and go on continuously without the reaction being stopped
what is the Haber Process
- produces ammonia from nitrogen and hydrogen
what is the equation for the Haber process
Ns(g) + 3H2(g) <—–> 2NH3(g)
what conditions are used to carry out the Haber Process
- temp of 450 degrees Celsius
- pressure of 200 atmospheres (20 MPa)
- iron catalyst
why is the pressure in Haber process considered to be a compromise
- it’s high enough to produce a reasonable equilibrium yield
> as equilibrium shifts to the right side because there’s less moles of gas so more product - however it’s not too high for it to be hazardous and expensive
why is the temperature in Haber process considered to be a compromise
- it’s low enough for a reasonable equilibrium yield
> because forward reaction is exothermic so to counteract equilibrium shifts to the left, decreasing ammonia yield - however it’s high enough for a reasonable rate of reaction + for the catalyst to work efficiently
what are the raw materials for the Haber Process
- natural gas
- air
- steam
how is nitrogen manufactured to be used in the Haber process
- nitrogen is manufactured by the fractional distillation of liquefied air
> air is 78% nitrogen
how is hydrogen manufactured to be used in the Haber Process
- hydrogen is manufactured by reacting natural gas (mostly methane) with steam
what other conditions are chosen for Haber process
- liquefying ammonia (letting gas cool + turn to liquid)
> conc of NH3 decrease so to counteract equilibrium shifts to right to increase NH3 yield - recycling the unreacted hydrogen + nitrogen
- both of these improves the yield to around 97%
what is the contact process
- an important process in the formation of sulfuric acid
what is sulfuric acid used for
- making fertilisers
- oil refining
- metal extraction
- making paints + polymers
what are the 3 raw materials needed for making sulfuric acid
- sulfur
- air (source of oxygen)
- water
what step process is sulfuric acid synthesised in
- 3 step process
> including the contact process
what is stage 2 in the synthesis of sulfuric acid
- the contact process
> sulfur dioxide and oxygen react to produce sulfur trioxide
sulfur dioxide + oxygen —> sulfur trioxide
2SO2 + 2O2 <—> 2SO3
> energy change = -144kj/mol = exothermic
> reversible reaction because double arrow
what is stage 1 in the synthesis of sulfuric acid
- sulfur burns in air to produce sulfur dioxide
sulfur + oxygen —> sulfur dioxide
S(s) + O2(g) —> SO2(g)
> energy change = -297kj/mol = exothermic
> not reversible as single arrow
what conditions are used for the contact process (stage 2)
- pressure of 2 atmospheres (200 kPa)
- temperature of 450 degrees Celsius
- vandium oxide catalyst (V2O5)
> under these conditions equilibrium yield is around 96%
why is the pressure chosen for Contact process a compromise
- increased pressure will push equilibrium to the right with less moles of gas
> however, in this reaction equilibrium is already so far to the right that we don’t need to spend more money on increasing the pressure
> the pressure is enough
why is the temperature a compromise for the contact process
- forward reaction is exothermic so to oppose the change the equilibrium will shift in the endothermic direction
> the temperature chosen is a compromise as it’s low enough for a reasonable equilibrium yield but it’s high enough for a reasonable rate of reaction + for catalyst to work
what are the hazards in stage 3 of the synthesis of sulfuric acid + how can they be controlled
- reaction between sulfur trioxide + water = very exothermic + produces hazardous acidic mist
- so stage 3 is carried out in 2 steps:
> 1. sulfur trioxide reacts with concentrated sulfuric acid to make a compound called oleum
H2SO4 + SO3 –> H2S2O7
> 2. the oleum is added to water to produce sulfuric acid as a final product
H2S2O7 + H20 –> 2H2SO4
what is stage 3 in the synthesis of sulfuric acid
- sulfur trioxide is converted into sulfuric acid
> sulfur trioxide + water —> sulfuric acid
SO3 + H2O —> H2SO4
> not reversible
what is an ore
- a rock or mineral that contains enough metal (or metal compound) to make it economical to extract the metal
give examples of some ores + metal compounds found in the ore
- malachite = copper carbonate
- bauxite = aluminium oxide
- haematite = iron (III) oxide
what extraction methods are there to extract metals from their ores
- essentially all metals could be extracted using electrolysis but electricity is expensive
> instead, metals less reactive than carbon can be extracted by heating their compounds with carbon / carbon monoxide
> as carbon (more reactive) can displace the oxygen
how is copper extracted from an ore
copper can be extracted from copper(II) sulfide in 2 stages:
- stage 1- first the copper(II) sulfide is ‘roasted’ in air
> copper(II) sulfide + oxygen —> copper(II) oxide + sulfur dioxide
2CuS(s) + 3O2(g) —> 2CuO(s) + 2SO2 (g)
- stage 2 - the copper(II) oxide is heated with carbon
> copper(II) oxide + carbon —> copper + carbon dioxide
2CuO(s) + C(s) —> 2Cu(s) + CO2(g)
what is stage 2 in copper extraction from ore, an example of
- redox reaction
> copper(II) oxide loses oxygen (reduced)
> carbon gains oxygen (oxidised)
what other methods can be used to reduce Copper(II) oxide to copper
- by heating it with methane / hydrogen
> copper oxide + hydrogen —> copper + water
> copper oxide + methane (CH4) —> copper + carbon dioxide + water
> methane contains carbon + hydrogen
what are the unreactive metals
- silver
- gold
- platinum
what are native elements
- elements found in pure form in the earth’s crust
what is a blast furnace used for
- to extract iron from it’s core
what raw materials are added to the top of the blast furnace
- iron ore (haematite) - contains iron(III) oxide
- coke - mostly carbon + made by heating coal in absence of air
- limestone - mostly calcium carbonate - removes impurities
> additionally, hot air is forced in at the bottom of the blast furnace
what is a reducing agent
- a substance which causes something to be reduced so they lose oxygen
> reducing agents get oxidised as they gin oxygen
what is the main reducing agent in the blast furnace
- carbon monoxide
> formed when coke reacts with carbon dioxide
what is stage 1 in the extraction of iron in a blast furnace
- coke burns in the hot air making carbon dioxide
C(s) + O2(g) —> CO2(g)
what is stage 2 in the extraction of iron in a blast furnace
- more coke reduces the carbon dioxide, making carbon monoxide
C(s) + CO2(g) —> 2CO(g)
what happens in the blast furnace once iron(III) oxide gets reduced to iron
- the molten iron trickles downwards in the blast furnace
> however it contains sandy impurities from iron ore
> this can be removed using limestone (calcium carbonate)
what is stage 3 in the extraction of iron in the blast furnace
- carbon monoxide reduces iron(III) oxide to iron at around 1500 degrees Celsius
3CO(g) + Fe2O3(s) —> 3CO2(g) + 2FE(l)
what happens in stage 4 in the extraction of iron in the blast furnace
- calcium carbonate decomposes in high temperatures forming calcium oxide and carbon dioxide
CaCO2(s) —> CaO(s) + CO2(g)
what happens in stage 5 in the extraction of iron in the blast furnace
- the calcium oxide formed reacts with silica from the sandy impurities to form calcium silicate (slag)
CaO(s) + SiO2(g) —> CaSiO3(l)
what is the final steps of the extracting iron from a blast furnace after all 5 stages
- molten calcium silicate (called slag) floats on molten iron
- both iron + slag are removed separately at the bottom of the blast furnace
write balanced equations + small explanations for all the reactions taking place in the blast furnace when extracting iron
- C(s) + O2(g) —> CO2(g)
> coke burns in air making carbon dioxide - C(s) + CO2(g) —> 2CO(g)
> more coke reduces carbon dioxide to carbon monoxide - 3CO(g) + Fe2O3(s) —> 3CO2(g) + 2Fe(l)
> carbon monoxide reduces iron(III) oxide to iron at around 1500 degrees Celsius - CaCO3(s) —> CaO(s) + CO2(g)
> calcium carbonate decomposes in high temperatures forming calcium oxide + carbon dioxide - CaO(s) + SiO2(g) —> CaSiO3(l)
> calcium oxide formed, reacts with silica from sandy impurities to form calcium silicate (slag)
what are some uses of aluminium
- can be used in pans, drink cans and cars
- aluminium alloys have low density but are very strong so can be used in bicycles + aeroplanes
what does aluminium naturally exist as
- aluminium oxide
Al2O3
what ore is aluminum found in
- bauxite
what method is used to extract aluminium from it’s ore + why
- electrolysis
- because aluminium is more reactive than carbon so must be extracted through electrolysis
where is the molten mixture of aluminium oxide + cryolite contained
- huge electrolysis cell
> made from steel, lined with graphite
> graphite lining acts as the cathode
> huge graphite blocks act as anode
electrolysis only works if the compound is ____ or ______
- molten
- in solution
what are problems with the electrolysis of just aluminium oxide
- aluminium oxide is insoluble in water + has a very high melting point (2050)
> it would be very expensive to heat it to this temp
how can you reduce the melting point of aluminium oxide in order to carry out electrolysis
- by adding an ionic compound called cryolite
> cryolite has a much lower melting point
> this allows electrolysis to happen at about 950
during electrolysis of aluminium oxide, what is produced at the anode + cathode + give half equations
- aluminium is produced at the cathode where it gains electrons (reduction)
Al3+ + 3e- —> Al - oxygen is produced at the anode where it loses electrons (oxidation)
2O2- —> O2 + 4e-
during the electrolysis of aluminium oxide, what does the oxygen react with
- the oxygen reacts with the hot graphite anodes, making carbon dioxide
what is the difference between high grade ore and low grade ore
- high grade ore = high metal content
- low grade ore = low metal content
how can bacteria produce sulfuric acid
- by oxidising iron(II) ions + sulfide ions
> the sulfuric acid forms in the presence of water + oxygen
what are the 2 biological methods of metal extraction
- bioleaching
- phytoextraction