C6 Flashcards
How do you calculate the rate of reaction?
- quantity of reactants used/ time taken
- quantity of products formed/ time
taken
What four factors affect the rate of reaction?
- temperature
- concentration/pressure
- surface area
- catalyst
Explain collision theory
In order for particles to react, they have to collide with each other with sufficient energy (activation energy)
How does temperature affect the rate of chemical reactions?
- Particles gain more kinetic energy and move faster
- This faster movement allows the particles to collide more frequently
- The additional energy means that there are more frequent SUCCESSFUL collisions
How does concentration/ pressure affect the rate of chemical reaction?
if there are more particles per unit of volume, there are more frequent successful collisions
How does the surface area affect the rate of chemical reaction?
- a higher surface area to volume ratio provides a greater area for the collisions to take place
- higher frequency of successful collisions
How does the presence of a catalyst affect the rate of chemical reaction?
Catalysts lower the activation energy which means there are more frequent successful collisions
What happens when the equilibrium lies to the right?
when the concentration of products is greater than the reactants
What happens when the equilibrium lies to the left?
The concentration of the reactants is greater
What is Le Chatelier’s Princriple?
states that if you change the conditions of a reversible reaction at equilibrium in a closed system, the system will try to counteract the change
How does temperature effect the equilibrium?
- if you decrease the temp, the equilibrium will move in the exothermic direction to produce more heat
• more products for the exothermic reaction - if you raise the temp, the equilibrium will move in the endothermic direction to try and decrease it
• more products for the endothermic reaction (fewer products for the exothermic reaction)
How does pressure effect the equilibrium?
only affects an equilibrium involving gases
- if you increase the pressure, the equilibrium tries to reduce it by moving the equilibrium in the direction where there are fewer molecules
- if you decrease the pressure, equilibrium moves in the direction where there are more molecules of gas
How does concentration effect the equilibrium?
- increasing the concentration of the reactants, makes more product
- decreasing the concentration of the products, reduces the amount of the reactants