C5 - Exothermic and Endothermic Reactions Flashcards
Law of conservation of Energy
Energy cannot be created or destroyed, only transferred
Exothermic
A reaction which transfers energy to the surroundings (can be shown through rise of temperature)
Examples of exothermic reactions
Combustion, neutralisation, oxidation
Endothermic
A reaction which takes in energy from surroundings (shown by fall in temperature)
Examples of endothermic reactions
Thermal decomposition
How can you measure the amount of energy released by a chemical reaction?
By taking the temperature of the regents, mixing them in a polystyrene cup and measuring the temperature pf the solution at the end of the reaction
What is the biggest problem when using temperature to measure the energy released in a reaction?
A lot of heat is lost to the surroundings
How can you reduce the heat loss to the surroundings?
Using a polystyrene cup and placing it in a beaker of cotton wool to five more insulation, and putting a lid on the cup to reduce energy lost by evaporation (this method works for neutralisation)
What other variables could you measure apart from the energy change?
The mass or concentration of the reactants used
Exothermic reaction graph
- Products are at a lower energy than the reactants, the difference in height represents the overall energy change in the reaction per mole
- Activation energy is the initial rise in energy (which represents the energy needed to start the reaction)
- The activation energy is the minimum amount of energy the reactants need to collide with each other and react. The greater the activation energy, the more energy needed to start the reaction
Endothermic reaction graph
- Products are at a higher energy than the reactants
- Difference in height represents the overall energy change during the reaction per mole
What happens to the bonds in a chemical reaction?
- Old bonds are broken and new bonds are formed
- Endothermic reaction to break existing bonds
- Exothermic reaction is released when new bonds are formed
- Energy required to break bonds is greater than the energy released by forming them
Every chemical bond has a particular … … associated with it
Bond energy (which varies slightly depending on the compound the bond occurs in)
How to calculate the overall energy change for a reaction change?
Overall energy change is the sum of the energies needed to break bonds in the reactants minus the energy released when the new bonds are formed in the products