C4 - Predicting And Identifying Reactions And Products Flashcards

1
Q

What are the group 1 metals?

A

Lithium, sodium, potassium, rubidium, caesium, francium

They all have one outer electron - thus have similar chemical properties

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2
Q

What are the common physical properties group 1 metals have?

A

Relative to other metals:

  • Low melting points
  • Low density
  • Very soft
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3
Q

What type of compounds do alkali metals form?

A

Ionic compounds

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4
Q

How can you test for the presence of group 1 metal ions?

A

Using a flame test

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5
Q

Why are alkali metals reactive?

A

The outer electron is more easily lost because it is further from the nucleus, so the nuclear force of attraction is weaker and less energy is required to remove it

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6
Q

What are the Halogens?

A

Group 7 elements are known as the halogens

It is made up of Fluorine, Chlorine, Bromine, Iodine and Astatine

They all have 7 electrons in their outer shell

They also exist as diatomic molecules e.g. Cl2

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7
Q

Describe the trends going down the group 7 elements

A

As you go down group 7, the melting points and boiling points of the halogens increase.

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8
Q

Why does reactivity decrease going down group 7?

A

A halogen atom only needs to gain one electron in order to achieve a stable electronic structure.

As you go down the group, the halogens become less reactive as it gets harder to attract the extra electron due to the weaker nuclear force and the increased electron shielding

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9
Q

How are metal halides formed?

A

The halogens will react vigorously with alkali metals to form salts called metal halides

e.g. 2Na + Cl2 —> 2NaCl

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10
Q

Desribe a halogen displacement reaction?

A

A displacement reaction is where a more reactive element ‘pushes out’ (displaces) a less reactive element from a compound.

For example, chlorine is more reactive than bromine. If you add chlorine water to potassium bromide solution, the chlorine will displace the bromine from the salt solution.

e.g. Cl2 + 2KBr –> Br2 + 2KCl

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11
Q

Describe chlorine at room temperature:

A

Fairly reactive, poisonous, green gas

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12
Q

Describe bromine at room temperature:

A

Poisonous, red-brown liquid, which gives off an orange vapour

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13
Q

Describe iodine at room temperature:

A

Dark great crystalline solid which gives off a purple vapour when heated

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14
Q

What are the group 0 elements?

A

Group 0 elements are called the noble gases.

They include: helium, neon, argon, krypton, xenon, radon

They are all colourless gases at room temp

They have a full outer shell thus are more or less inert (unreactive)

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15
Q

Describe the properties of the transition metals

A

They have all the typical properties of metals - they are hard, strong and shiny materials that conduct heat and electricity

They have high melting points apart from Mercury

They also have high densities

They make very good catalysts e.g. iron is used in the Haber Process

The compounds of transition elements are also very colourful.

Most of the time, transition metals are much less reactive than Group 1 and 2 metals

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16
Q

What is the reactivity series?

A

Potassium

Sodium

Calcium

Magnesium

Aluminium

Zinc

Iron

Copper

Silver

17
Q

What is the reaction between metals and water?

A

Metal + Water —> Metal Hydroxide + Hydrogen

18
Q

How to test for oxygen gas?

A

You test for oxygen by placing a glowing splint near the mouth of the container of gas.

If oxygen is present, the splint should relight.

19
Q

How to test for carbon dioxide?

A

You test for carbon duoxide using limewater, a calcium sulfate solution.

If you bubble CO2 through a limewater solution, it should turn cloudy white.

20
Q

How to test for hydrogen gas?

A

You test for hydrogen by placing a lighted splint near the mouth of the container of gas.

If hydrogen is present, it should ignite with a squeaky pop.

21
Q

How to test for chlorine gas?

A

Use a drop of water to dampen a piece of blue litmus paper.

Hold the paper near to the container that holds the substance

If chlorine is present, the paper turns red then white.

22
Q

How to detect sulfate ions?

A
  1. Add a few drops of dilute hydrochloric acid
  2. Then a few drops of barium chloride solution

If sulfate ions are present, you get a white precipitate

23
Q

How do you detect carbonate ions?

A
  1. Add a few drops of dilute hydrochloric acid

If carbonate ions are present, bubbles of gas will be produced. Dilute nitric acid can also be used

24
Q

How to detect halide ions?

A
  1. Add a few drops of dilute nitric acid
  2. Then a few drops of silver nitrate solution

If chloride ions are present - a white precipitate is formed

If bromide ions are present - a cream precipitate is formed

If iodide ions are present - a yellow precipitate is formed

25
Q

How do you carry out a flame test?

A
  1. Dip a clean Nichrome wire loop into the powder or solution
  2. Use the handle to hold the loop in the edge of a roaring blue flame
  3. Record the flame colour
26
Q

What are the different colours produced by different metals from a flame test?

A

Metal Flame test colour

Lithium Red

Sodium Yellow

Potassium Lilac

Calcium Orange-red

Copper. Green-blue

27
Q

What are the results from a sodium hydroxide test?

A

Ion Precipitate colour

Iron (II) Green

Iron (III) Orange-brown

Copper (II) Blue

Calcium White

Zinc White

28
Q

Why are instrumental methods of analysis better than ‘wet’ tests?

A

They are more sensitive - can analyse small amounts of substances

They are more accurate

They are much quicker - can be be run constantly

29
Q

Why does density increase down group 1 metals?

A

Density increases down group 1 because there are more protons and neutrons which in result increases the atomic mass of the atom

30
Q

Why does melting point decrease down group 1?

A

Melting point decreases as you go down group 1 because the strength of the metallic bonds decreases.

There is also a greater distance between the nucleus and electrons therefore less energy is required to break the bonds.

31
Q

Why does reactivity increase down group 1?

A

Reactivity increases down group 1 because the atoms get larger making the outer electron further away from the nucleus allowing it to be lost more easily.

Electron shielding also occurs; the other electrons get in the way of the nucleus and the outer electron

32
Q

Why does melting point increase as you go down group 7?

A

Melting point increases as you down group 7 because the intermolecular forces get stronger

33
Q

Why does density increase as you go down group 7?

A

Density increases because there are more protons and neutrons

34
Q

Why does reactivity decrease as you go down group 7?

A

Group 7 halogens are trying to gain an electron.

As you go down, it is harder to gain an electron because the nuclear attraction force is weaker

35
Q

How do you interpret a gas chromatogram?

A

Each peak represents a substance present in the mixture

The area under each peak shows the relative amount of each substance in the mixture

The retention time is relatively unique for each substance

36
Q

What is a mass spectrometer?

A

A mass spectrometer measures the mass of atoms and molecules.

You can use it to measure the relative mass of different isotopes and also find out information about the structure of a molecule

37
Q

How do you interpret a mass spectrum?

A

Each peak represent a fragment of the molecule

The peak on the far right represents the molecular ion

38
Q

How does mass spectrometry work?

A
  1. Ionisation - the molecules are bombarded with electrons of which some will collide with enough force to knock an electron off the molecule - these molecules now have a +1 charge
  2. Acceleration - the ions are accelerated so they all have the same kinetic energy
  3. Deflection - the ions are passed through a magnetic field and will deflect in proportion to their mass and charge
  4. Detection - the beam of ions are detected electronically
39
Q

How does infra-red spectroscopy work?

A
  1. A range of infra-red waves are passed through a sample of an organic compound
  2. Some are absorbed in varying amounts by different types of bonds
  3. A detector on the other side can tell which frequencies have been absorbed and by how much