C3-4. Moles And Calculations Flashcards
What is the definition of an acid?
- An acid is a substance which dissociates in solution to release H+ ions.
- Therefore they are also referred to as proton donors.
What is the definition of alkali and base?
- Bases are substances which can accept H+ ions from other molecules.
- Alkalis are soluble bases.
What is a neutralisation reaction?
This is a reaction between H+ and OH- ions to form water.
What determines strong and weak acids?
Strong acids fully dissociate in solution to release H+ ions, whereas weak acids only partially dissociate in a reversible reaction.
What are polyprotic acids?
These are acids such as H2SO4 which contain more than one hydrogen atom. One H+ ion is released, and the resulting 1- ion partially dissociates.
What is percentage yield defined as?
The amount of product we produce during a reaction as a percentage of the amount we expect to form.
What factors affect percentage yield?
- Incomplete reactions
- Some product may remain within the reaction vessel
- Unexpected alternate reactions involving our reactants may have also occurred
- Some product may be lost during purification
Define atom economy.
- Atom economy is a measure of how much of the total product formed during a reaction is considered useful.
- Note that we do consider the coefficients of substances involved here.
What is the difference between empirical and molecular formulae?
- Molecular formulae provide the actual number of atoms present in a substance.
- Empirical formulae represent the simplest ratio of atoms present in a substance.
How can we work out empirical formulae from reaction data?
Generally, you should calculate the number of moles of ‘items’ involved in the formula of the unknown compound:
- C and H for hydrocarbons
- The salt and water of crystallisation for hydrated salts.
This allows you to calculated ratios of atoms in a given compound.
What calculations are generally used to process titration data?
- Generally, we need to work towards determining the number of moles present in the reacting solution, and the using that to determine concentration, mass etc. of the unknown substance.
- Remember that we may need to scale the number of moles, e.g. from 25cm3 in a burette to 250cm3 in a flask.
What is molar gas volume?
The volume a gas occupies at room temperature and pressure (RTP), generally given as 24dm3.
What is the ideal gas equation?
pV=nRT
- i.e. pressure * volume = amount * ideal gas constant * change in temperature
- With units given in Pa, dm3, mol, J mol-1 K-1, and K respectively.
What is the ideal gas constant?
8.314 J mol-1 K-1
What is a standard solution?
A solution of a known concentration, made by dissolving an exact mass of a solute in a solvent before making up the solution to an exact volume.