C2 - Rates of Reaction Flashcards

0
Q

Where are catalysts used?

A

They are used in industrial chemical reactions where there isn’t much time
They are used in catalytic converters

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1
Q

What is a catalyst?

A

A substance that massively increases the rate of a reaction without being used up or changed

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2
Q

What are the 4 factors that can change the speed of a reaction?

A

Temperature, concentration, surface area and pressure

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3
Q

Why is a catalytic converter needed?

A

The harmful gases of carbon monoxide and nitrogen oxides are changed to the much less harmful carbon dioxide and nitrogen

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4
Q

What is the biggest problem with catalysts?

A

They are very specific

Only one type of catalyst will catalyse a specific reaction

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5
Q

What is the Haber process?

A

Iron is used as a catalyst to produce ammonia from nitrogen gas and hydrogen gas

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6
Q

How do catalysts work?

A

The catalyst particles collide with the reactant particles and lower the activation energy by providing an alternative route for the reaction

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7
Q

What is concentration?

A

It is the amount of molecules of the reactant dissolved in a given volume of water

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8
Q

How does concentration change the rate of reaction?

A

If the particles are more crowded (higher concentration) they are much more likely to collide so the reaction is faster

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9
Q

How does pressure affect the rate of reaction?

A

If we squash more gas into a smaller area, the molecules will be closer together meaning they are more likely to collide

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10
Q

What is pressure?

A

How much gas has been squashed into a given area

They have more pressure making the particles closer together

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11
Q

How does temperature affect the rate of reaction?

A

If there is a higher temperature, the particles will vibrate more giving them more energy
More energy means they move faster and are more likely to collide

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12
Q

How does surface area affect the rate of reaction?

A

If the surface area is larger, more of the reactant is exposed meaning the particles of the other reactant are more likely to collide with it

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13
Q

Give 2 ways in which we can measure the rate of a reaction

A

How fast the reactants are used up

How fast the products of the reaction are formed

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14
Q

What is collision theory?

A

The theory that substances react when the particles of the reactants collide, break apart and then re-form to create new substances

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15
Q

What are successful collisions?

A

Collisions that result in a chemical reaction

16
Q

What is activation energy?

A

The amount of energy that needs to be put in to trigger the reaction

17
Q

What are the 3 ways of measuring the rate of reaction?

A

Change in mass

Volume of gas given off

Precipitation

18
Q

How do you measure rate of reaction with precipitation?

A

This is when the product of the reaction is a precipitate that clouds the solution

Observe a mark through the solution and measure how long it takes to disappear

The quicker the mark, the quicker the tst

19
Q

What are the 2 problems with the precipitation rate of reaction experiment?

A

Different people might not agree on the exact point that the mark disappears

Only works for reactions where the initial solution is clear

20
Q

How do you measure rate of reaction using change in mass?

A

If a reaction produces a gas, you can measure the rate of reaction by looking at the change in mass (gas is lost)

You measure the change in mass by using a balance and looking at how fast the mass goes down

21
Q

What is the advantage and disadvantage of the change in mass experiment?

A

Very accurate because the mass balance is accurate

But the gas is released straight into the room

22
Q

How do you measure the rate of reaction with the volume of gas given off?

A

You use a gas syringe to collect up the gas of the reaction

The more gas given off in a given time, the faster the reaction

23
Q

What is the advantage and disadvantage of the volume of gas given off experiment?

A

The volume of gas measured is very accurate

If the reaction is too violent, you can blow the plunger out of the end of the syringe

24
Q

Describe the experiment you use to see the effect of surface area on rate of reaction

A

You put marble chips and hydrochloric acid in conical flask and use the volume of gas given off method to calculate the rate of reaction

You then do the same but crunch up the chips more which gives a larger surface area

The second reaction should happen faster

25
Q

Describe the experiment you use to see the effect of concentration on rate of reaction

A

You use the change in mass method to calculate the rate of reaction of magnesium metal and dilute hydrochloric acid

You do the sane reaction with a higher concentration hydrochloric acid

The second reaction should have a higher rate

26
Q

Describe the experiment you use to see the effect of temperature on rate of reaction

A

Let the 2 clear solutions of sodium thiosulphate and hydrochloric acid react in a comical flask and use the precipitation method to calculate the rate of reaction

Then use a water bath to heat the solutions up before mixing them and calculate the rate of reaction

The second reaction should be faster

27
Q

Describe the experiment you use to see the effect of a catalyst on rate of reaction

A

You put hydrogen peroxide in a conical flask and put in a catalyst

Use the volume of gas given off (oxygen gas) to calculate the rate of reaction

Do this method for all the different catalysts to be tested

28
Q

What are the 2 advantages of using catalysts in industrial reactions?

A

Increases rate of reaction so the plant doesn’t need to operate for as long saving money

Allows the reaction to work at lower temperatures and pressures

29
Q

What are the 3 disadvantages of using catalysts in industrial reactions?

A

They often need to be removed from the product and cleaned

Different reactions use different catalysts so they can be quite expensive

Catalysts can stop working because of impurities so you need to keep your reaction mixture very clean