C1.4 Crude oils and fuels Flashcards
crude oil
mixture of hydrocarbons found in the earth
alkanes
Alkanes are saturated hydrocarbons. This means that their carbon atoms are joined to each other by single bonds. This makes them relatively unreactive, apart from burning or combustion, which is their reaction with oxygen in the air.
CnH2n+2
Distillation
Distillation is a process that can be used to separate a pure liquid from a mixture of liquids. It works when the liquids have different boiling points. Distillation is commonly used to separate ethanol (the alcohol in alcoholic drinks) from water.
heating → evaporating → cooling → condensing
Fractinal distillation
Some / most of the hydrocarbons (or petrol) evaporate / form vapours or gases
When some of / a fraction of the hydrocarbons (or petrol) cool to their boiling point they
condense
Hydrocarbons (or petrol) that have (relatively) low boiling points and are collected near
the top of the fractionating column or hydrocarbons with (relatively) high boiling points
are collected near the bottom of the fractionating column
The process is fractional distillation
Heat the crude oil / mixture of hydrocarbons or crude oil / mixture is heated to about
350°C
Some of the hydrocarbons remain as liquids
Liquids flow to the bottom of the fractionating column
Vapours / gases rise up the fractionating column
Vapours / gases cool as they rise up the fractionating column
The condensed fraction (or petrol) separates from the vapours / gases and flows out
through a pipe
Some of the hydrocarbons remain as vapours / gases
Some vapours / gases rise out of the top of the fractionating column
There is a temperature gradient in the fractionating column or the fractionating column is
cool at the top and hot at the bottom
Combustion
combustion of hydrocarbon fuels releases energy
it need oxygen (oxidation)
Ethane+oxygen= C02 +water
As you go up the fractionating column, the hydrocarbons have:
lower boiling points have : lower viscosity (they flow more easily) higher flammability (they ignite more easily).
Explain the process of cracking
It is when long chain hydrocarbons ae broken down into smaller more useful molecules.
1===long chain fraction is heated and vapourised
2==vapours pass over a catalyst
3===products are short chains
advantages of biodiesal
===renewable
===carbon neutral :plants absorb C02 as they grow
==biodegradable
disadvantages of biodiesal
==large areas of land needed to ggrow fuel crops
===deforestation to plant fuel crops
burning biofuels releases more nitrogen oxide
Incomplete combustion
If the oxygen supply is restricted - meaning that there’s not enough air - then the combustion of alkanes produces the poisonous gas carbon monoxide. For example, this equation shows the incomplete combustion of methane:
2CH4(g) + 3O2(g) → 2CO(g)+ 4H2O(g)
(Methane + Oxygen → Carbon monoxide + Water)