C1 Part A Flashcards

1
Q

Give the symbol equation for the thermal decomposition of limestone:

A

CaCO3→ CaO + CO2

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2
Q

Which other substances thermally decompose in the same way as limestone?

A

Magnesium, copper, zinc and sodium carbonate

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3
Q

Give the word and symbol equation for the reaction that causes limestone to be damaged by acid rain.

A

Calcium Carbonate + Sulfuric acid → Calcium sulfate + Carbon dioxide + Water

CaCO3 + SO4→ CaSO4 + CO2+ H2O

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4
Q

What product is formed when you react calcium carbonate with water?

A

Calcium Hydroxide

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5
Q

Calcium hydroxide is an alkali which means it can be used to neutralise……. and does this much faster than …………

It is also used to indicate the presence of ……….. when ……… . It becomes ……….. if there’s …….. and this is due to the formation of …………

A
  • Used to neutralise acidic soil in fields and does this much faster than powdered limestone
  • Indicates the presence of Carbon Dioxide when gas is bubbled through it. It becomes cloudy if there’s Carbon Dioxide in the gas - this is due to the formation of Calcium Carbonate.
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6
Q

How is powdered clay used to make cement and what happens when cement is mixed with sand and water?

A

It is heated in a kiln with clay. When cement is mixed with sand and water it becomes mortar.

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7
Q

What happens when clay is mixed with sand and aggregate?

A

Concrete is made

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8
Q

List the issues with quarrying limestone (5)

A
  • Huge holes change the landscape permanently (however restoration of the area is usually required after quarrying work has been finished)
  • Quarrying processes (eg. blasting rocks apart with explosives) make a huge amount of noise
  • Quarrying destroys habitata
  • Limestone must be transported elsewhere to be made into other products, creating more noise and pollution.
  • Waste materials produce unsightly tips
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9
Q

How do cement factories harm people and the environment? (2)

A
  • They create a lot of dust, which can cause breathing problems.
  • A huge amount of energy is needed, most of this will come from burning fossil fuels (which pollutes the atmosphere).
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10
Q

What are the informal names for Calcium Oxide and Calcium Hydroxide?

A

Calcium Oxide: Quicklime

Calcium Hydroxide: Slaked lime

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11
Q

What are some of the uses of Limestone products? (5)

A
  • Concrete and cement are building materials
  • Chemicals can be used in dyes, paints and medicine
  • Used to neutralise acidic soil, lakes and rivers
  • In power station chimneys to neutralise sulfur dioxide (a cause of acid rain)
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12
Q

Why is limestone so widely used? (4)

A
  • It is cheaper than granite or marble
  • Fairly easy to cut
  • More hardwearing than marble
  • Limestone, concrete and cement don’t rot like wood does when it gets wet and they’re fire-resistant.
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13
Q

List some advantages (3) and disadvantages (3) of concrete

A

Advantages

  • Can be poured into moulds
  • It’s cheap
  • Concrete doesn’t corrode and it’s fire resistant

Disadvantages

  • Emissions from the concrete and cement industry contribute to the greenhouse gas effect (and climate change)
  • Concrete has a low tensile strength and can crack, meaning often it must be reinforced with steel bars
  • It’s deemed to be ugly as a building material
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14
Q

What is a metal ore?

A

A rock that contains enough metal for it to be worthwhile extracting

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15
Q

What is the main aluminium ore, name and symbol?

A

Bauxite, aluminium oxide

Al2O3

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16
Q

Which two economic factors contribute to how worthwhile extracting a metal is?

A
  • The market price of the metal (if it drops, it might not be worth extracting)
  • Improvements in technology mean that extraction that might not have been worthwhile in the past, now is
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17
Q

By which two methods can metals be extracted from their ores?

A

Chemically (by reduction)

By Electrolysis

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18
Q

Some metals can be extracted from their ores by reduction with ……………. When an ore is reduced, this means ………… has been removed from it.

A

Some metals can be extracted from their ores by reduction with carbon. When an ore is reduced, this means oxygen has been removed from it.

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19
Q

Which metals can be extracted using reduction? (4)

A

Those lower in the reactivity series than carbon:

Zinc, Iron, Tin, Copper

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20
Q

Give the symbol and word equation for the reduction process used to extract iron.

Where does this occur in industry?

A

2Fe2O3 + 3C → 4Fe + 3CO2

Iron (III) Oxide + Carbon → Iron + Carbon Dioxide

In a blast furnace

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21
Q

Which metals are extracted by electrolysis? (5)

A

Those higher in the reactivity series than carbon:

Potassium, Sodium, Calcium, Magnesium, Aluminium

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22
Q

Why is electrolysis much more expensive than reduction?

A

It requires a lot of energy, both to melt the ores and charge the elctrodes.

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23
Q

How else is electrolysis used, other than for extraction? Give an example that includes a specific metal

A

Purification of metals

Copper produced by reduction is impure. Electrolysis is used to form a very pure copper, which is much better at conducting.

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24
Q

What is an electrolyte and how do they conduct electricity?

A

A liquid used to conduct in the process of electrolysis, often metal salt solutions made from the ore of the metal being extracted or molten metal oxides.

Electrolytes have free ions that enable electricity to be conducted.

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25
Q

Explain the process of electrolysis specific to copper, draw a diagram if it helps (3 main steps)

Anode - positive electrode

Cathode - negative electrode

A
  • Electrons are taken from copper atoms at the anode, causing them to enter the copper sulfate solution (electrolyte) as Cu2+ ions.
  • Cu2+ ions near the cathode gain electrons and become copper atoms
  • Impurities are left at the anode as a sludge, pure copper atoms bond to the cathode.
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26
Q

In copper electrolysis, what are the cathode and anode made of?

A

Cathode - Begins as a thin strip of pure copper that grows as electrolysis occurs

Anode - a lump of impure copper that will dissolve

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27
Q

Outline how displacement reactions can be used to extract metals

A
  • If a more reactive metal is placed in a metal compund, it will replace the less reactive metal in the compound
  • More reactive metals bond more strongly to the non-metal part of the compound, meaning the less reactive metal is pushed out
28
Q

Give the word equation for how iron is used in a displacement reaction to extract copper and explain why this is useful?

Why can silver not be used to extract copper?

A
  • Copper sulfate + Iron → Iron sulfate and copper
  • Useful because iron is cheap but copper is expensive.
  • Silver cannot be used because it is less reactive than copper.
29
Q

Why are scientists looking into new ways to extract copper from low grade ores?

A

Copper-rich ores are in short supply but demand is growing

30
Q

What is bioleaching? Describe the process

A

The use of bacteria to separate copper from copper sulfide.

Bacteria extracts energy from the bonds between the copper and sulfur. Leachate is produced, this contains copper that can be extracted (eg. by filtering).

31
Q

What is phytomining? Describe the process

A

Plants are grown in soil that contains copper. They can’t use or get rid of the metal so it gradually builds up in their leaves, the plants are harvested, dried and burnt. Copper can be collected from the ash left in the furnace.

32
Q

Why is recycling metals so important? (6)

A
  • Mining metal ores have the same negative impacts as quarrying, these are reduced when metal is recycled
  • Mining and extracting metals takes a lot of energy
    • Fossil fuels are running out, it is important to conserve them
    • The burning if fossil fuels contributes to climate change
  • Recycling metals uses a fraction of the energy it takes to mine/extract eg. recycling copper = 15%
  • Saves money
  • Recycling conserves the finite amount of metal on Earth
  • Cuts down on waste sent to landfill (if all the aluminium cans in the UK were recycled, 14 million fewer dustbins would need to be emptied each year)
33
Q

List the three basic properties of metals

A
  • Strong but malleable
  • Good at conducting heat
  • Good at conducting electricity
34
Q

What are the disadvantages in using metals in technology/as building materials? (2)

A
  • They can corrode when exposed to air/water and must be protected
  • Metals can become tired when stresses and strains are repeatedly put on them, this is known as metal fatigue and can cause them to break.
35
Q

What are the properties specific to Copper and what is it used for?

A

Copper is a good conductor of electricity, it’s strong but can be bent, doesn’t react with water and is therefore used in electrical wires and water pipes/tanks.

36
Q

What are the three, main properties of aluminium and titanium, what are they used for?

A

Aluminium : corrosion resistant, low density, not particularly strong. Used in aeroplane parts.

Titanium: corrosion resistant, low density, very strong. Used in replacement hips.

37
Q

What is an alloy?

A

A metal made by combining two or more metallic elements, especially to give greater strength or resistance to corrosion.

38
Q

Why is iron usually made into steel (an alloy)?

A
  • Impure iron is too brittle for most uses (other than ornamental railings)
  • Pure iron has a regular arrangement of identical atoms that slide over one another, making it soft and easily shaped. It is too bendy for most uses.
39
Q

Properties and uses of low carbon and high carbon steel?

A

Low carbon: 0.1% carbon, easily shaped. Used for car bodies.

High carbon: 1.5% carbon, very hard and inflexible. Blades for cutting tools and bridges.

40
Q

Which two metals are added to steel to make it stainless? Give the properties and uses of stainless steel

A

Chromium and sometimes nickel

Corrosion-resistant. Used for cutlery and in containers for corrosive substances.

41
Q

Why are alloys harder than pure metals?

A

Different elements consistent of different sized atoms. When they are added to one another, the element with the smaller atoms will upset the layers of the element with larger atoms, making them more difficult to slide over one another.

42
Q

What are bronze and cupronickel made of? Give their properties and uses

A

Bronze

  • Tin + Copper
  • Harder than copper
  • Good for making medals and statues

Cupronickel

  • Hard and corrosion resistant
  • Used to make ‘silver’ coins
43
Q

How is crude oil formed and what is it a mixture of?

A

From the buried remains of plants and animals. It’s a fossil fuel made of hydrocarbons

44
Q

What are hydrocarbons? Give two examples

A

Compounds of hydrogen and carbon, such as petrol and natural gas

45
Q

Which property of crude oil enables fractional distillation to separate the various components of it?

A

There are no chemical bonds so the various hydrocarbon molecules have all their original properties, including condensing points.

46
Q

How does a fractionating column work? Draw a diagram if it helps

A

Heated crude oil is piped in at the bottom. The vaporised oil rises up the column, where the various fractions are constantly tapped off at the different levels where they condense.

47
Q

How does the length of the molecule effect it’s condensing point?

A

The longer the molecule, the hotter it must be in order to condense

48
Q

What are alkanes and how does each one differ?

A

Hydrocarbons that are chains of carbon atoms surrounded by hydrogen atoms. Different alkanes have chains of different lengths.

49
Q

List the first four alkanes

A

Methane (a natural gas)

Ethane

Propane

Butane

50
Q

What is the general formula for alkanes?

A

CnH2n+2

51
Q

Carbon atoms form four bonds and hydrogen form one. In alkanes, the atoms have formed as many bonds as they can meaning that they are …………..

A

Saturated

52
Q

Describe the three basic trends of the different fractions that make-up crude oil

A
  1. The shorter the molecules, the more runny the hydrocarbon is
  2. The shorter the molecules, the more volatile they are (they become gas at a lower temperature
  3. The shorter the molecules, the more flammable the hydrocarbon is
53
Q

How does the volatility of the refinery gas fraction dictate what it is used for?

A

Refinery gas has the shortest molecules and therefore the lowest boiling point, meaning that it’s a gas at room temperature.

It’s used as bottled gas and stored under pressure in liquid form. When the tap on the bottle is opened, it vaporises and flows to a burner where a flame is ignitd.

54
Q

How are gloopy, viscous carbons used?

A

For lubricating engine parts and covering roads

55
Q

The petrol fraction of crude oil has longer molecules, how does this effect its boiling point and use?

A

Petrol has a higher boiling point and is liquid, meaning its ideal for storing in the fuel tank of a car. It can flow to the engine where it’s easily vaporised to mix with the air before it’s ignited.

56
Q

Why are crude oil fractions used as fuels? Can you give another example of where it is used in industry.

A

They burn “cleanly”

Crude oil can also provide the basis to make various chemicals, including plastics

57
Q

4Why is crude oil more commonly used than alternative energy sources? (3)

A
  • It is more reliable than wind or solar energy
  • Infrastructure is already set up for oil fractions (eg. petrol/diesel stations are common whereas electric or ethanol car stations are not)
  • There are less concerns about the safety of oil than about nuclear power
58
Q

Why do many people think we should stop using crude oil fractions as fuel and invest more in renewable energy sources?

A

Crude oil resources are finite, meaning they will run out one day and therefore we should conserve the oil that we do have.

59
Q

List the two main environmental impacts of using crude oil

A
  • Oil spills can poison animals and destroy their habitats
  • Crude oil’s energy can only be harnessed when it is burnt, this releases greenhouse gases into the atmosphere and contributes to climate change
60
Q

If there’s not enough oxygen supplied when a fossil fuel is burnt, what happens?

A

Some of the fuel doesn’t burn (partial combustion) and solid particles (particulates) of soot/unburnt fuel and Carbon Monoxide are released.

61
Q

What is the word equation for the combustion of a hydrocarbon?

A

hydrocarbon + oxygen → carbon dioxide + water vapour

62
Q

How does sulfur dioxide cause acid rain and how does acid rain harm the environment?

A

It mixes with clouds to form dilute sulfuric acid, which falls as acid rain.

Acid rain makes lakes acidic, causing plants and animals to die. It also kills trees and damages limestone buildings and stone statues.

63
Q

Scientists have found that 25% less sunlight reaches the surface of the Earth in some areas, compared to 50 years ago. How do they believe particulates have contributed to this ‘global dimming’?

A

Particles of soot and ash reflect sunlight back into space

64
Q

List three alternative fuels that have been developed

A
  • Ethanol
  • Biodiesel
  • Hydrogen gas
65
Q

How is ethanol made and what are it’s pros (2) and cons (3)?

A

Ethanol is produced from the fermentation of plants (it is a biofuel) .

Pros:

  • The CO2released when it’s burnt was taken in by the plant when it grew so its carbon neutral.
  • The only other waste product is water.

Cons:

  • It’s not widely available
  • Engines must be converted before they can use ethanol.
  • There are worries that if farmers begin producing crops for biofuel rather than food, it will increase food prices.
66
Q

How is biodiesel created and what are its pros (3) and cons (2)?

A

Biodiesel is produced from vegetable oils (eg. rapeseed/soybean).

Pros:

  • It’s carbon neutral
  • Engines don’t need to be converted.
  • It produces less sulfur dioxide and particulates than diesel/petrol

Cons:

  • Its expensive
  • We can’t make enough to replace diesel
67
Q

How is hydrogen gas created in order to power vehicles and what are its pros and cons?

A

Hydrogen gas is created by the electrolysis of water.

Pros:

  • It’s a very clean fuel

Cons:

  • A special engine is required.
  • It isn’t widely available.
  • Energy is necessary to create it.
  • Hydrogen gas is hard to store because it’s explosive.