C1- Atomic structure Flashcards

1
Q

define the (relevant) group names

A

1: alkali metals
2-3 (not including 2 or 3 ) transition metals
7: halogens
0: Noble Gases

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2
Q

define:
element:
compound:
mixture:

A

element: pure substance made up of only one type of element
compound: pure substance made up of 2 or more different elements chemically bonded
mixture: combination of two or more substances (elements or compounds) that aren’t chemically joined but physically mixed together

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3
Q

describe how filtration works as a method of separating mixtures

A

Insoluble Solid: The solid being separated must be insoluble in the liquid.
Filter Paper: A porous material that allows liquids to pass through but not solids.
Funnel: Holds the filter paper and directs the liquid into a container.
Filtrate: The liquid that passes through the filter paper.
Residue: The solid that is left behind on the filter paper

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4
Q

what is crystallisation

A

Crystallisation is the process of forming solid crystals from a solution by allowing the solvent to evaporate slowly ( heat up solution in an evaporating basin above a bunsen burner, then rest of solvent is left to evaporate in petri dish at room temp)

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5
Q

what is distillation and how does it work?

A

Distillation is used to seperate a soluble solid from a solvent and is often used in poorer countries to obtain pure water from sea water.
How it works:
- solution is heated and boiled to evaporate solvent
- vapour enters a condenser
-it cools and condenses back into a liquid and is collected in a receiving vessel
- solute remains in heated flask

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6
Q

fractional distillation, how it works and why:

A

used to separate miscible liquids ( combined completely) using their different boiling points though they can often be similar
how:
- ethanol has boiling point of 78 degrees
water has boiling point of 100 degrees

  • the mixture is heated above a bunsen burner and predominantly the ethanol evaporates but due to close boiling point, some water may also evaporate

-to prevent the water vapour entering the condenser, a fractionating column of glass beads is put in place

  • the temp is higher at the bottom and lower at the top of the column so as the vapour of the liquid with the higher boiling point rises, it will collect and condense on the glass beads whilst the liquid with the lower boiling point will pass over into the condenser
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7
Q

how do you test ( with a mixture of ethanol and water ) that there is no water remaining?

A

ethanol is flammable so if you apply a lighted splint, the distillate will burn with a blue flame unless there is an excess of water present

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8
Q

What is paper chromatography?

A

It is used to separate and identify substances from mixtures in a solution. It works because some compounds in a mixture will dissolve better than others in a solvent

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9
Q

How does paper chromatography work?

A
  • take a piece of filter paper and use a pencil to draw a line at the bottom of the sheet ( baseline)
  • dab a spot of the solution on the baseline
  • put filter paper upright in a beaker containing a solvent but making sure not to submerge pencil line
  • then wait for solvent to seep up the paper and the relative solubility of the components making up the mixture will determine how far they travel up the paper
  • if any components aren’t soluble, they’ll remain on baseline
  • leave to dry and pattern left is called a chromatogram
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10
Q

Why do the different components of the mixture move up the filter paper at different rates?

A

mobile phase: solvent that moves through the paper carrying different substances with it
stationary phase: the filter paper

the less soluble component is more attracted to the stationary phase and therefore, travels less distance

the more soluble component is more attracted to the mobile phase and travels more distance

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11
Q

how do you know if a substance is impure or pure?

A

pure: a pure substance produces one spot on the chromatogram

impure: an impure substance, or mixture, produces two or more spots

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12
Q

Interpreting a chromatogram:

A

you can compare unknown substances with know substances- they are likely to be the same if:
- they produce the same number of spots which match in colour
- they have the same Rf value ( distance travelled by substance/ distance travelled by solvent )

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13
Q

why is mass conserved in a chemical reaction

A

. The Law of The Conservation of Mass: states that the total mass of the products formed in a reaction is equal to the total mass of the reactants; mass is neither created nor destroyed in a chemical reaction

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14
Q

what is the definition for the state symbol (aq) ?

A

aqueous solution- substance dissolved in water

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15
Q

balance this symbol equation:

A

_C2H5OH + _O2 -> _CO2 + _H2O

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16
Q

Why may mass appear to change in a chemical reaction?

A

. a gas may be formed during a chemical reaction which, if not contained, can be released into the surroundings and the mass of the products will therefore be different to the mass of the reactants

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17
Q

why do the properties of a mixture not vary from the elements they’re composed of where compounds do?

A

The chemical properties of a mixture remain the same as the elements composing them because they haven’t been chemically bonded and therefore maintain their individual properties hence why a mixture can be separated physically whereas a compound cannot

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18
Q

How can you use experimental data to define a compound from a mixture

A

Compounds have a distinct melting and boiling point whereas mixtures melt and boil over a range of temperatures. For example, H2O, a compound, has a distinct melting point of 0 degrees and a distinct boiling point of 100 degrees

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19
Q

what did John Dalton discover and when?

A

Date: start of the 19th century

Discovered the name ‘atom’ and that every organism was made of
atoms. Found out that atoms are spherical and were indivisible, cannot
be destroyed or created. Many of atoms create molecules. Atoms of the
same element are identical

20
Q

what model did John Dalton compose?

A

the solid sphere

21
Q

What did JJ Thompson discover and when?

A

date: 1897

Discovered the electron. Positively charged ball/ sphere with negatively
charged electrons scattered around, the electrons were discovered by
passing electricity through a cathode ray tube with gas.

22
Q

What model did JJ Thompson compose?

A

the plum pudding model

23
Q

what did Earnest Rutherford do and when?

A

Date: 1909-1911

Shot a beam of positively charged alpha particles at a thin sheet of gold foil. Some
particles were scattered and a few were deflected back

24
Q

What did Earnest Rutherford prove with his experiment?

A

concluded that most of an atom’s mass is concentrated at the centre
called the nucleus. Those that went through but changed direction
were close to dense, positive nucleus, causing them to be repelled.
Those that rebounded showed there was a small dense nucleus. The
majority passing through showed there was a lot of empty space

25
What model did Earnest Rutherford compose?
the nuclear model
26
What discovery did Niels Bohr make and when?
Date: 1913 Niels bohr discovered protons and how atoms can have a different number of shells, where the electrons are. The electrons also have a fixed orbit around the nucleus and have set distances from the nucleus. All atoms must have the same number of protons and neutrons. Does not collapse inwards due to shells due to the attraction between the positive nucleus and negative electrons due to electrostatic force.
27
What model did Niels Bohr compose?
the planetary model
28
What did James Chadwick discover and when?
Date: 1940 James Chadwick discovered the neutron in the nucleus He bombarded beryllium atoms with alpha particles and an unknown radiation was produced He interpreted this radiation as being composed of particles with a neutral electrical charge and the approximate mass of a proton
29
What model was composed by James Chadwick?
The atomic model
30
What is the significance of group number and the properties of elements in that group?
the group number corresponds with the number of valence electrons elements have in a group hence why they exhibit similar chemical behaviour and activity
31
what is the significance of period on the properties of elements within that horizontal row
elements in the same period, row, have the same number of electron shells.
31
what is the trend in reactivity of group 1 elements?
. reactivity increases as you go down the group . increase in shell shielding and atomic radii causes a decrease in electrostatic attraction between the positive nucleus and the valence electrons . therefore, less energy is required to lose the outer electron
32
why is it necessary for group 1 metals to be stored under mineral oil to prevent oxidising with water vapour/ oxygen?
Group 1 metals react vigorously with water and oxygen and can cause potential hazards
33
What is the trend in reactivity for group 7 elements?
.reactivity decreases as you go down the group . shell shielding and atomic radii increases .weakens electrostatic forces between positive nucleus and valence electrons . makes it more difficult to gain an electron and fulfill octet rule
34
Why can we be confident that there are no elements missing in the first ten elements of the periodic table?
the periodic table is structured based on electronic configuration and within the first ten elements there are no gaps or irregularities within electronic configuration and therefore, there must be no missing elements
35
what is an ion?
a charged particle
36
what is an isotope?
an atom of the same element with the same number of neutrons but a different number of electrons
37
what is the diameter of an atom?
0.1 nm
38
what is the diameter of a nucleus
1 x 10^-14 metres
39
why do ions have a charge?
they have a charge because they have lost or gained electrons
40
why does chlorine not have a whole mass number?
chlorine has two isotopes ( chlorine 35 and chlorine 37 ) which occur in different abundances; chlorine 35 has a 75% abundance whereas chlorine 37 has a 25% abundance. The relative atomic mass listed on the periodic table is calculated by taking the weighted average of the masses of the isotopes, considering their natural abundances- (0.75 * 35) + (0.25 * 37) = 35.5
41
What are the maximum number of electrons in the first three energy levels?
2, 8, 8
42
what is the relative mass of a proton?
1
43
what is the relative mass of a neutron?
1
44
what is the relative mass of an electron?
1/2000