Brewers' spent grain Flashcards

1
Q

What is Brewers’ spent grain (BSG) ?

A

Brewers’ spent grain (BSG) is the major by-product of the brewing industry, representing around 85% of the total by-products generated. Brewers’ grains (BG) generated at a rate of up to 30% of the weight of the initial malt grist. Worldwide generationof BG has been estimated at 30 billion kilograms per annum.

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2
Q

What is the composition of BSG?

A

Brewer’s grains are a heterogeneous mixture of grain remnants from which the soluble and mash digestible components of malt have been extracted. BG’s at source are typically 70-85% moisture. BSG is a lignocellulosic material containing about 17% cellulose, 28% non-cellulosic polysaccharides, chiefly arabinoxylans, and 28% lignin.

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3
Q

What are BSG applications?

A

BSG is available in large quantities throughout the year, but its main application has been limited to animal feeding (90%?). Nevertheless, due to its high content of protein and fibre (around 20 and 70% dry basis, respectively), Brewers’ spent grains are of high nutritive value.

Whilst the protein content (circa 18% of dry matter) and amino acid profile of BG are of nutritional value, the high amount of lignocellulos- ic matter makes it indigestible to many animal species. The majority of BG used for animal feed is fed to
can cope with the high fibre con- tent.

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4
Q

What are the volume of BSG produced?

A

It was reported that about 3.4 million tonnes of BSG from
the brewing industry are produced in the EU every year
(Stojceska et al., 2008), out of which UK alone contributes over 0.5 million tonnes of this waste annually. However,Brazil, the world’s fourth largest beer producer (8.5 billion litres/year) in 2002, generated ~1.7 million tonnes of BSG (Mussatto et al., 2006).

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5
Q

What are the main BSG processing?

A

Many breweries have plants for BSG processing
using two-step drying technique, where the water content is first reduced to less than 60% by pressing, followed by drying to ensure the moisture content is below 10% (Santos et al., 2003).
However, the traditional process for drying BSG is
based on the use of direct rotary-drum driers. This procedure is considered to be energy-intensive.

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6
Q

BSG in animal feed constraints

A

However, high moisture content of BSG (80 to 85%)
together with polysaccharide and protein makes it particularly susceptible to microbial growth and subsequent spoilage in a short period of time (7 to 10 days) (Stojceska et al., 2008).

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7
Q

BSG animal feeding benefits

A

Their findings showed that BSG supplementation (45% w/w) increased actual milk yield, milk total solids content, and milk fat yield when compared to control containing maize silage (45% w/w). Also, both wet and dried BSG have been utilized asanimal feed (Dhiman et al., 2003). Feeding brewers’ grain dry or wet

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8
Q

BSG for human consumption

A

Since BSG is derived from materials utilized for
humans, it can be incorporated into so many human
diets, such as breads and snacks; especially where there
is need to boost the fibre contents.
BSG was incorporated into wheat flour for the production
of high-fiber enriched breads.

Comment JP Endres: Le sujet de l’utilisation des drêches pour l’alimentation humaine pose le problème de la teneur en fibre. On peut faire du pain, des cookies etc. mais à ce jour cette utilisation reste anecdotique et est réservé aux micro-brasseries des centres urbains (donc pas la taille industrielle de site qui nous intéresse et qui représente plus de 90% du marché mondial de la production de bière).

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9
Q

BSG - Metal adsorption and immobilization

A

BSG was studied by Lu and Gibb (2008) for the removal
of Cu(II) ions from aqueous solutions and they found its
maximum adsorption capacity to be 10.47 mg g-1
dry weight at pH 4.2. Based on this, BSG being a process byproduct, has a significant potential as a bioadsorbent for application in the remediation of metal contaminated
wastewater streams.

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10
Q

Challenges with BSG re-use

A

However, time, location and composition, environmental effectiveness, technological feasibility, social acceptability and economical affordability are among the key challenges associated with reliable and sustainable utilization of BSG.

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11
Q

More

A

http://www.academicjournals.org/article/article1380725235_Aliyu%20and%20%20Bala.pdf

BG_Nov_Dec_2011_Grains_Feature_937040182.pdf

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12
Q

Marketing identified Opportunities (JP Endres) #1

A

Brasseries HEINEKEN en SERBIE et en GRECE semblent avoir un souci pour sécuriser le débouché de leurs drêches tels que nous l’a rapporté leur responsable achat car faibles débouchés locaux (faible élevage ovin et bovin), pb de coûts de transports, passage de frontière etc).

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13
Q

Marketing identified Opportunities (JP Endres) #2

A

Le problème se pose aussi sur de grosses brasseries (plus de 4 million d’hL/an) (telles que celles que l’on trouve en Chine ou en Amérique latine) qui de par leur taille, vont rapidement inonder la région alentour de drêches et doivent transporter les drêches sur de longues distances, au dela de l’attractivité économique (valeur de la drêche vs coût de transport et biodégradabilité).

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14
Q

Current use (JP Endres) #2

A

Pour la question du coût, les drêches sont parfois vendues (cela peut aller au dela de 40 EUR la tonne selon le coût local des alternatives en alimentation animale), parfois données gratuitement aux éleveurs alentour. ce n’est pas un marché de commodités et dépend des conditions locales.

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15
Q

Market Challenge / opportunity discussion

A

The environmental implications of increased methane emissions from cows fed this hard to digest material can also be considered as having a negative environmental impact.

The European Feed Manufacturers Federation reported recently that 24 million tonnes of protein-rich material are required annually within the EU for animal feed usage and that approximately 70% of this is currently imported – the principal source is soya. Does it make economic or environmental sense to continue to import this material when there are protein rich co-products like BG which are generated locally in substantial quantities?

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16
Q

Heineken research in BG

A

Furthermore, researchers are developing technologies with which to process BG in order to enhance its digestibility and thus enable its incorporation into monogastric diets (i.e., feed for pigs, chickens, fish etc.). Researchers at Heineken have published details of a fractionation method for BG which broadly sepa- rates it into protein-rich and fibre-rich streams. The method involves form- ing a wet slurry from BG (5%) which is then screened. The finer non- retained fraction was shown to be protein-enriched, with added value as an animal feed ingredient due to the diminished fibre content.

17
Q

Case studies of energetic valorisation

A

Leading the way in the brewing industry has been the
Finnish company Wärtsilä, whose biomass boilers were installed in the United Kingdom in 2009 at Tadcaster and Manchester brewer- ies which at that time were oper- ated by Scottish & Newcastle and today Heineken.

There are now more than 100 ‘biogrates’ in operation worldwide. The process involves taking BG at source and passing it through a belt press or equivalent dewatering process to reduce the moisture content to approximately 58-60%. This material is then blended 50:50 with wood chips to generate a boiler feed with a moisture content in the region of 50%. The steam raised is used to generate heat and power for local reuse. By way of example, the Tadcaster and Manchester operations mentioned above have heat outputs of 7.4 MWth and electrical outputs of 3.1 MWe.

As a fuel BG are relatively high in nitrogen and there is a risk of high NOx emissions as a result of combustion. To counter this, urea can be sprayed into the boiler during com- bustion. The ash left behind from BG combustion is rich in phosphorus and is suitable for incorporation into fertilisers.

18
Q

Bioethanol production

A

Currently in the UK, TMO are leading the development of this tech-nology and have an operational dem- onstration facility that was built by Briggs of Burton. It is claimed that, using the TMO process it is theoreti- cally possible to produce 150 litres of fuel grade ethanol (29 MJ/kg) from BG resulting from one tonne of malted barley.

19
Q

Anaerobic digestion

A

In 2010 Magic Hat Brewing Company of Vermont in the United States claimed to become the first brewer worldwide to install an anaer- obic digestion system for treating BG. In fact, the feedstock for their anaerobic digester is formed from a blend of BG, brewery waste water and spent hops and yeast. The instal- lation uses an orbicular bioreactor manufactured by Purpose Energy of Waltham, Massachusetts.
The reactor has a capacity of 490,000 US gallons of sludge, gen- erating 200 cubic feet (or 78 m3) of biogas per minute. The biogas is used directly on site to meet process energy demands and Magic Hat estimate a net saving of $2 per barrel (US) beer produced. It is possible to derive further value from residues of anaerobic digestion pro- cesses by using them, for example, as soil conditioners.

20
Q

Brewery Markey Key Facts

A

5 companies represent 50% of the world production

Company
Production
(million hL)
% World Beer
Production
AB InBev*
352,9
18,1%
SAB Miller*
190,0
9,7%
Heineken
171,7
8,8%
Carlsberg
120,4
6,2%
China Resource
Brewery Ltd
106,2
5,4%
*October 2015, AB InBev acquired Sab Miller for $104 billion
21
Q

Marketing identified Opportunities #3

A

Most breweries uses Biogas to produce energy
BSG production surpasses acceptance capacity
Brewery wants to increase energetic autonomy
Legislation restrictions
Green image, etc.

22
Q

Project main learning - Combustion

A

Is Boiler Combustion a good way to valorize BSG?
Combustion is feasible for BSG, but:
Dewatering required. Mechanical dewatering not sufficient. Other alternatives are evaluated.
High risk of SO2 and NOx emission. Use of lime and selective catalytic reactor or co-combustion
Fouling and corrosion should not be problematic
High slagging risk expected for 50 % of the samples analyzed. Alternatives are proposed
Are all the BSG compatible with Combustion?
All BSG samples tested have globally the same characteristics (except for slagging)
What is the potential energy provided by Combustion of the BSG?
BSG have a Dry LHV (5340-5890 kWh.t-1 TS), similar to wood chips

23
Q

Project main learning - AD

A

Is Anaerobic Digestion a good way to valorize BSG?
Anaerobic Digestion is feasible for BSG, but:
Dilution required by 2 in wet processes (high TS and N content)
High retention time required (minimum 40 days) due to fiber degradation
Continuous follow-up of process recommended due to potential inhibition (lipids content)
Nutrients addition needed for K, Co and Ni, possible for Ca, Mg, Na, and Fe
Are all the BSG compatible with AD?
All BSG samples tested have globally the same characteristics
What is the potential energy provided by AD of the BSG?
Methane potential is 325 NL CH4.kg-1 DS (75–80 Nm3 CH4.kg-1raw)
Potential energy around 2900 kWh.T-1 of DS as biogas