Bravais lattices Flashcards

1
Q

What crystal families are there in 3D?

A
  1. Triclinic
  2. Monoclinic
  3. Orthorhombic
  4. Tetragonal
  5. Hexagonal
  6. Cubic
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2
Q

What crystal systems are there in 3D?

A
  1. Triclinic
  2. Monoclinic
  3. Orthorhombic
  4. Tetragonal
  5. Trigonal
  6. Hexagonal
  7. Cubic
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3
Q

What Bravais lattices exist for the triclinic crystal system?

A

aP

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4
Q

Why is the symbol for triclinic ‘a’?

A

From the word anorthic.

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5
Q

What Bravais lattices exist for the monoclinic crystal system?

A

mP, mS

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6
Q

What Bravais lattices exist for the orthorhombic crystal system?

A

oP, oF, oI, oA, oB, oC

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7
Q

What kind of centering exists for the orthorhombic crystal system?

A

Primitive, face-centering, body-centering, side-centering (A, B and C).

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8
Q

What restrictions are there on the lattice parameters in the triclinic crystal system?

A

None.

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9
Q

What restrictions are there on the lattice parameters in the monoclinic crystal system?

A

Two angles are 90°.
In b-unique setting: α = γ = 90°
In the c-unique setting: α = β = 90°.

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10
Q

What restrictions are there on the lattice parameters in the orthorhombic crystal system?

A

All angles are 90°.

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11
Q

What restrictions are there on the lattice parameters in the tetragonal crystal system?

A

All angles are 90° and a = b.

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12
Q

What restrictions are there on the lattice parameters in the cubic crystal system?

A

a = b = c, and all angles are 90°.

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13
Q

What restrictions are there on the lattice parameters in the trigonal crystal system (with rhombohedral axes)?

A

a = b = c, α = β = γ.

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14
Q

Why isn’t there a face-centered tetragonal Bravais lattice?

A

For a face-centered tetragonal lattice, a smaller body-centered lattice can always be chosen.

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15
Q

What is the standard setting for monoclinic cells?

A

Choosing b as the unique axis. The angle is usually taken to be acute (> 90°)

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16
Q

Which direction does the 3-fold axis run in the rhombohedral lattice cell?

A

Along the body diagonal.

17
Q

How are directions denoted in a crystal structure?

A

[uvw]

18
Q

How are sets of symmetrically equivalent lattice directions denoted in a crystal structure?

A

. E.g.:

[100], [010], [001], [-100], [0-10], [00-1] in a cubic lattice is denoted as <100>

19
Q

How are sets of parallel equidistant planes in a lattice denoted?

A

hkl

20
Q

How are single planes in a lattice denoted?

A

(hkl)

21
Q

Why can’t there be a B-centered monoclinic cell (with unique b-axis setting)?

A

In such a cell, you could always draw a smaller primitive cell (mP).

22
Q

Why can’t there be a F-centered monoclinic cell?

A

In such a cell, you could always draw a smaller C-centered cell.

23
Q

Why can’t there be an I-centered monoclinic cell?

A

In such a cell, you could always draw a smaller C-centered cell (via A-centered rotated around b-axis).

24
Q

Why can’t there be a C-centered tetragonal cell?

A

In such a cell, you could draw a smaller primitive cell.