bonding test (12/17/24) 🎀 Flashcards
What is electronegativity?
Measure of its attraction for electrons when bonded to another atom
Values can be used to predict the type of bond that will be formed between two atoms and can be found on Table S.
What type of process is the breaking of a chemical bond?
Endothermic process
Energy is added to overcome attractive forces and separate the atoms in a compound.
What type of process is the formation of a bond?
Exothermic process
Releases energy, and the greater the energy released, the greater the bond’s stability.
What characterizes metallic bonds?
Valence electrons move freely throughout the crystal, forming a ‘sea of mobile electrons’
Results in high melting points, hard solids, and good conductivity of heat and electricity.
What is the primary characteristic of covalent bonds?
Formed when two nuclei share electrons to achieve a full octet
Typically formed between two nonmetals.
What defines a nonpolar covalent bond?
Electrons are shared equally
Exists in atoms having equal or close electronegativity values, with a difference of 0-0.4.
What defines a polar covalent bond?
The sharing of electrons is unequal
The element with the higher electronegativity value attracts electrons more, resulting in partial charges.
What is the electronegativity difference for polar covalent bonds?
Greater than 0.4 but less than 1.7
The side of the molecule with higher electronegativity becomes slightly negative.
What characterizes ionic bonds?
Formed when ions bond together, involving one metal and one nonmetal
Involves the attraction of oppositely charged ions.
What happens to metals in ionic bonds?
Metals lose electrons and become positive
Nonmetals gain electrons and become negative.
What is the electronegativity difference for ionic bonds?
Greater than 1.7
Most ionic bonds exhibit the greatest electronegativity difference.
What are dipole-dipole forces?
Attractions between polar molecules
The positive side of one polar molecule is attracted to the negative side of another.
What is hydrogen bonding?
A bond between a hydrogen in one molecule and an oxygen, nitrogen, or fluorine in another
Hydrogen bonding forces are much stronger than dipole-dipole forces.
What are London dispersion forces?
Forces of attraction due to uneven distribution of electrons
Present in any molecule, but less apparent in asymmetrical molecules where dipole-dipole forces exist.
What is the octet rule?
Atoms generally react by gaining, losing, or sharing electrons to achieve a complete octet of eight valence electrons
The configuration of eight valence electrons is known as an octet.
What is a Lewis dot diagram?
A representation of valence electrons around a chemical symbol
Consists of a chemical symbol surrounded by 1-8 dots representing valence electrons.
What happens to metals in Lewis dot structures?
Metals lose their valence electrons, leaving no dots in the diagram
Nonmetals gain electrons, which are shown in the electron dot diagram.
How are covalent bonds represented in Lewis structures?
A single dash may be used to represent a pair of electrons
One dash represents two valence electrons.