Bonding Systems Flashcards
What type of bonding is enamel bonding?
Mechanical
What acid etch is usually used for enamel bonding
30-50% phosphoric acid
What is the composition of dentine?
20% organic (mostly collagen)
70% inorganic (mostly hydroxyapatite)
10% water
How is dentine an inconsistent material?
Aged dentine more mineralised
Dentine near pulp has more tubules and increased water content
What is the surface energy of dentine like?
LOW surface energy
4 requirements of a dentine bonding agent
Ability to FLOW
potentional for INTIMATE CONTACT with dentine surface
LOW VISCOSITY
ADHESION to substrate
3 ways adhesion to substrate is achieved
Mechanical
Chemical
Van der Waals
(Or combination)
How is mechanical adhesion achieved?
Achieved by DBA and dentine surface MESHING and interlocking together with MINIMUM GAPS
How is chemical adhesion achieved?
Bonding at a MOLECULAR LEVEL
What type of bond would the mineralised and organic constituents of dentine have?
Mineralised- IONIC bond
Organic- COVALENT bond
How is Van der Vaals adhesion achieved?
Based on ELECTROSTATIC or DIPOLE INTERACTION
What does the strength of van der Waals adhesion depend on?
Depends on CONTACT ANGLE, which is a good indication of WETTABILITY of a solid by a specific liquid
A contact angle of
Define critical surface angle
The surface tension of a liquid that will JUST spread of the surface of a solid
Define contact angle
The angle between the liquid surface and the solid surface, when a solid and liquid make contact
What surface energy must a liquid have to flow and stick
A liquid must have a lower surface energy than the surface it is being placed on
What material is placed on frying pans because it has such a low surface energy?
PTFE
What are surface wetting agents?
DBAs increase critical surface energy of dentine to allow composite to flow and stick to surface
How are DBAa bonded to dentine
Adhesion through molecular entanglement
Define smear layer
An adherent layer of ORGANIC DEBRIS that remains on the dentine surface after the preparation of the dentine during the restoration of the tooth
2 ways to deal with smear layer
Remove it and bond to ‘clean’ dentine beneath
Incorporate it by penetrating it, infiltrating it with bonding agent and stick it to the dentine below
4 problems with dentine bonding
Dentine is hydrophilic where as most adhesive are hydrophobic
Dentine is vital tissue
Dentine consists of both organic and inorganic material
Covered by smear layer
What are the 3 components of total etch DBA
- Dentine conditioner: an acid- usually 35% phosphoric
- Primer: adhesive part- with hydrophilic/hydrophobic molecule
- Adhesive: a resin which penetrates into the surface of the dentine attaching to the primers hydrophobic substance
What is the function of the dentine conditioner in total etch DBA.
Removes smear layer
Opens dentinal tubules (by removing smear layer)
Decalcifies uppermost layer of dentine
Function of primer in total etch DBA
Adhesive element in process
A coupling agent (usually HEMA)
Bifunctional- hydrophilic end to bond to hydrophilic dentine surface
Hydrophobic, methacrylate end to bond to the resin
Composition and function of adhesive in total etch DBA
A mixture of hydrophobic resins (usually Bis-GMA and HEMA)
May contain filler particles to make it stronger
Will contain CAMPHORQUINONE to allow it to LIGHT CURE
Penetrates primed dentine and forms micromechanical bond within tubules and exposed dentine collagen fibres
Forms HYBRID LAYER of collagen plus resin
Summary of actions of total etch DBA
Etching dentine:
- demineralisation of outer layer
- remaining collagen in HYDROPHILIC and has LOW SURFACE ENERGY (normal resin will not bond to it)
Primer:
- can penetrate dentine due to its BIFUNCTIONAL MOLECULES
- gives the surface HIGH ENERGY, and making it HYDROPHOBIC
Adhesive:
- can now penetrate
- MICROMECHANICAL RETENTION
2 problems with total etch
Overetching:
- collapse of collagen fibres– resin can’t penetrate
- too deep an etch, primer can’t penetrate full depth
Moisture dependant:
- too dry and dentine surface collapses
- too wet and primer is diluted- reduced strength
Name 6 ideal dental adhesive properties
Provide high BOND STRENGTH IMMEDIATE high bond strength DURABLE bond IMPERMEABLE bond EASY to use SAFE