Bonding Flashcards

1
Q

How ionic bonding occurs?

A

Ionic bonding occurs between metals and non-metals

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2
Q

Structure of an ionic bonding

A

-Giant lattice structure

Lattice is a regular, three-dimensional arrangement of ions.

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3
Q

Properties of ionic bonding

A
  • High melting point

- Giant lattice structure

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4
Q

How strong melting point are caused

A

Strong electrostatic attractions give ionic compounds high melting point.

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5
Q

Positive ions

Formation & charges

A
  • Generally formed by Metal atoms losing electrons.
  • Positive charge equal to the group number if formed from a group 1, 2 or 3 element.
  • Different charges if formed from transition metal
  • Knows as cations
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6
Q

Negative ions

Formation & charges

A
  • Generally formed by non-metal atoms losing electrons
  • Negative charge equal to 8 minus the group number of the element.
  • Sometimes exist as polyatomic ions such as OH-
  • Known as Anions
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7
Q

Strength of ionic bonding

A

To compare the relative strength of ionic bonds, the ionic charge and ionic radius have to be considered, sometimes called the charge/size ratio.
Example-
The ionic bonding in Mgf2 is much stronger than the bonding in NaF- this is because the magnesium ion is smaller than the sodium ion and also greater in charge. These factors increase electrostatic attraction between the ions.

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8
Q

what are covalent bonds ?

A

A covalent bond is an electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.

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9
Q

How covalent bonds forms?

A

A covalent bond forms when atoms share a pair of electrons. Generally, each atom in the bond contributes one electron to the pair.

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10
Q

What is a dative covalent bond?

A

A covalent bond consisting of an electron pair derived from one of the atoms.

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11
Q

How are covalent bonds shown?

A

In dot and cross diagrams

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12
Q

How are ionic bonds shown?

A

In an electron configuration diagrams

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13
Q

Strength of covalent bonds

A

Bond length and bond strength in covalent bonds are inversely related. This means that the shorter the covalent bond length, the greater the covalent bond strength.

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14
Q

What is a metallic bonds?

A

Is a bond between two metal elements

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15
Q

Structure of metallic bonds

A

A giant lattice of positive ions with delocalised electrons.

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16
Q

What are delocalised electrons?

A

The electrons from the outer shell of the metal atoms, but are not fixed to a particular atom so they can move freely throughout the structure.

17
Q

Properties of metals

A

-Electrical and thermal conductivity
> Due to the delocalised electrons, which are free to move
-High melting and boiling point
>Due to strong electrostatic attractions between positive ions and electrons
-Malleability
>Layers of positive ions slide over each other and the delocalised electrons move with the layers
-Ductility
> Positive ions roll over each other and the delocalised electrons move with the positive ions.

18
Q

Trends in melting points- Group 1 metals

A

Melting point decreases as the atoms get larger.

larger metals have more electrons and more electron shells, means they have more shielding between the nucleus and delocalised electrons. So the electrostatic forces are weakened, this produces weaker metallic bond, so less energy is required to break the bonds.

19
Q

Trends in melting points- Group 2 metals

A

Has a higher melting point than the group 1 metals in the same period.

Because the group 2 metal has two delocalised electrons per positive ion, rather than one.