Bonding 2 Flashcards

1
Q

Polar Molecule

A

A molecule with two centers of with a positive and negative charge

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2
Q

Why do polar molecules form

A

The electron change which is negative isnt’t distrubuted evenly amonge the atoms that make up the molecule

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3
Q

What does the greek symbole (delta) indicate

A

the partial charge

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4
Q

Why do ionic compounds have no partial charges

A

Theres is no sharing of electrons

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5
Q

Dipole

A

Seperation of positive and negative centers in an individual bond

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6
Q

are dipoles vectors of scalars

A

Vectors
- Magnitude and direction

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7
Q

Intra

A

Within

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8
Q

Inter

A

between

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9
Q

Intramolecular Forces

A

Covalent bonds holding the molecule together

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10
Q

Intermolecular forces

A

Attraction between bonds
– breaks when a substance is broken

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11
Q

What are the two major types of intermolecular forces?

A
  1. Van Der Waals force
  2. Hydrogen Bonding
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12
Q

What are the types of Van Der Waals forces?

A
  1. Dipole-dipole interactions
  2. London dispersion force
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13
Q

What are Van Der Waals forces?

A

An attraction force that exists between all molecules and is the weakest intermolecular force.

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14
Q

What factors affect the strength of Van Der Waals forces?

A

Depends on the size of the electron cloud and polarizability.

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15
Q

What is polarizability?

A

The extent to which an electron cloud can be deformed.

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16
Q

What are dipole-dipole forces?

A

Forces that exist between neutral polar molecules where positive and negative charges attract.

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17
Q

What is an ion-dipole interaction?

A

Occurs when water molecules orient themselves according to charges.

18
Q

What are London dispersion forces?

A

The weakest of all intermolecular forces that occur between adjacent neutral molecules.

19
Q

How do London dispersion forces arise?

A

Through instantaneous dipoles created by the distortion of electron clouds.

20
Q

What factors influence London dispersion forces?

A

Molecular weight, shape of the molecules, and surface area for contact.

21
Q

What is hydrogen bonding?

A

A special case of dipole-dipole forces that are abnormally strong.

22
Q

What is required for hydrogen bonding?

A

Hydrogen must be covalently bonded to a highly electronegative element (F, O, or N) and have at least one lone pair.

23
Q

Why can’t hydrogen bond in water without a lone pair?

A

No lone pair means no place for hydrogen to bond.

24
Q

What is the compressibility of gases?

A

Highly compressive

Gases take the shape and volume of their container.

25
What does the Kinetic-Molecular Theory state about liquids?
Molecules have some translational freedom but are held by intermolecular forces ## Footnote They can slide past each other and rotate.
26
What shape do liquids take?
The shape of their container ## Footnote Liquids have a constant volume regardless of their shape.
27
What happens to liquids when heated?
They tend to expand ## Footnote The volume occupied remains constant.
28
Define surface tension.
The amount of energy required to break the surface or overcome cohesive forces ## Footnote Surface molecules are attracted inward towards the interior molecules.
29
What are cohesive forces?
Forces that bind molecules to each other ## Footnote These forces contribute to surface tension.
30
What are adhesive forces?
Forces that bind molecules to a surface ## Footnote They influence the shape of the liquid meniscus.
31
What is a meniscus?
The shape of the liquid surface in a container ## Footnote It can be U-shaped or curved downwards depending on the balance of adhesive and cohesive forces.
32
What is viscosity?
Resistance to liquid flow ## Footnote It increases with stronger intermolecular forces and decreases with higher temperature.
33
What is the molecular behavior of solids according to molecular theory?
Molecules have no translational freedom and only vibrate ## Footnote They are held in place by strong attractive forces.
34
What are the characteristics of solids?
Definite shape and volume, virtually incompressible ## Footnote They expand only slightly when heated.
35
Define amorphous solids.
Solids that show no definite order in their molecular structure ## Footnote Examples include glass, plastic, and rubber.
36
What are crystalline solids?
Solids with an orderly, repeating three-dimensional pattern ## Footnote They melt at one specific temperature.
37
What characterizes metallic crystals?
Strong bonds between metal atoms and a sea of electrons ## Footnote This allows metals to be malleable and conduct electricity.
38
What causes metals to be malleable?
The ability of ions to slide past each other without shattering ## Footnote This is due to the unique structure of metallic crystals.
39
Cohesive forces
bind molecules together
40