BONDING Flashcards

1
Q

define ionic bonding?

A

strong electrostatic forces of attaction between oppositely charged ions. occurs in ionic compounds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

ionic compounds like sodium chloride form what structure?

A

giant ionic lattic structure. -regular strucure, - cubic shape, - giant repeating pattern.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

most ionic compounds dissolve in water because water is _____, and hence can do what to break up the structure.

A

can dissolve in water molescules as water molcules are polar, hence they can attract the + and - ions and hence break up the structure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

properties of ionic compounds?

A

soluble, can conduct electricity when molten or dissolved in solution, as the ions are free to move around,
have high mp as there are many strong electrostatic forces of attraction betweeen oppositely charged ions hence losts of energy is needed to overcome these forces.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

define covalent bonding

A

bonding formed involving the sharing of outer electrons in order for atoms to obtain a full shell, via an (electrostatic force of attraction between the shared pair of electrons and the positive nucleus)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

define dative/coordinate bonds, and show the eg of nitrogen with h+ in ammonium

A

these are where one atom donates 2 electrons to an atom or ion to form a bond. https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EaLW1_e-_tpAh0JJG2KPOCMBXQAwnXTaIGigNW-pWhuatA?e=8TeTHl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

eg of giant covalent structures,

A

graphite and diamond, sio2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

compare the properties of diamond and graphite

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EQ-oXevp7L1Dl1D9SlncNewBMDO3HTSmN-XOXpfzy3wkig?e=CdRqmN

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

why do molecules have a specific shape with specific angles.

A

because bonds repel each other equally. both contain electrons so they will want to be as far apart as possible.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

lonepair-bondpair relel more than bondpair-bondpair. 2 lone pairs together do what even more then

A

repel even further

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

what do lone pairs do

A

they shange the shape and bond angles by pishing bond pairs closer together. for every lone poair u reduce the bong angles by 2.5 degrees. (some molecules u dont reduce by 2.)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

give the name of shapes of molecules with 0 lone pairs, and the bond angles of em

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EeLDUbeCoCxIiCwp9wXksaUBmhe8vi1IaMBRK9ZNgP-tXw?e=6NMngu

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

give the name of shapes of molecules with lone pairs, and the bond angles of emj

A

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EbDNmMAm05FHgLg8jTMMDPABLOA2dqTaRI6-TGVOLLbaeg?e=oJ9rap

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

define electronegativity

A

the ability of an atom to attract a shared pair of electrons (towards itself) in a covalent bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

whats the trent of electrognegativity in the periodic table

A

the further up and right u go, the more electronegative the element is. (flurorine is the most EN)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

the bigger the difference in the EN, the most ____ the bond will be

A

polar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

are hydrocarbons classed as polar or non-polar

A

non-polar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

atoms bonded with the same or similar EN value are not ____

A

not polar. as the shared electrons sit in the middle

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

if polar bonds are arranged symmetrically, what effect does that have on the overall polarity.

A

then u have no overall polarity. (eg, c02

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

uneven distribution of charge leads to what

A

polar molecules eg (h2o)

21
Q

define van der waals and give a diagram

A

a temporary induce dipole-dipole that only exists when 2 moelcules or atoms are near by. when they move away the dipole interaction is destroyed. the delta+ on one atom or molecule will be attracted to the delta - on aother and a force of attraction is created. (its the weakest IMF)

https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/ERzRkXfudYtClZlxncYGq8oBRSnT81NKz2xuJv57YAE8QQ?e=2Ou8bE

22
Q

VDW forces can hold some molecules in what type of structure?

A

crystal structure. eg iodine.

23
Q

HOW DOES THE STRENGTH OF COVALENT BONDS AND VDW FORCES DIFFER IN FOR EG IODINE.

A

WEAK VDW FORCES HOLDS THE I2 MOLECULES TOGETHER (simple molecular (simple covalent))
sTRONG COVALENT BONDS HOLDS THE 2 IODINE ATOMS TOGETHER.

24
Q

the bigger the molecule or atom, the more ____

A

the bigger the molecule or atom, the more VDW forces as u have larger electron clouds

25
when we boil a liquid what are we breaking
the weak VDW forces not the covalent bonds
26
the longer, straight chain hydrocarbonds have more Vdw forces and so.... this means the bp ....
more energy is needed to overcome these forces. this means the bp increases
27
vdw forces are a lot weaker in what type of hydrocarbon leading to...
hydrocarbon with branches means they cant pack together as close. this weakens the VDW forces between the chains and lowers their boiling points
28
permanent dipole-dipole interactions exist in ...
molecules with a polarity
29
permanenet dipole-dipoles are----
weak electrostatic forces of attraction that exist between molecules with a polarity. (the delta + on one molecule is attracted to the delta- on another).
30
molecules that have dipole-dipole interactions also have...
vdw forces
31
how do u test for polar molecules eg h2o that exist.
Place a charged rod near a steady stream of the liquid. If the liquid contains polar molecules (like water), the stream will bend towards the rod. This happens because polar molecules align so their oppositely charged ends face the rod.
32
hydrogen bonding, and diagram showing its formation
strongest IMF and occurs when u have very electronegative elements. it occurs when hydrogen on one molecule forms a bond with the lone pair on Nitrogen, oxygen or fluorine. (3 most EN elements) https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/ET316Jaj7spEoeqf_nBKymQBRjJ3wba7VJbqP6sLk387Dg?e=wNCyhE
33
molecules that have H bonding also have...
vdws and dipole-dipole
34
Ice forms a regular strucutre held together by ____. why is ice less dense than water
ICE FORMS A REGULAR STRUCTURE HELD BY H BONDING. THE H BONDING CAUSES MOLECULES TO BE FURTHER APART, MAKING ICE LESS DENSE THAN WATER
35
BP OF HYDGROGEN HALIDES AND EXPLAIN
https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/ER_AXjX5aHZFuNJ8noaO83YB5tRyhWmEnzexOPRfBI7jFw?e=GKZikR
36
DEFINE METALLIC BONDING
ELECTROSTATIC FORCES OF ATTRACTION BETWEEN POSITIVE METALLIC IONS AND NEGATIVE SEA OF DELOCALISED ELECTRONS
37
STRUCTURE IN METALS
GIANT METALLIC LATTICE STRUCTURES
38
THE MORE ELECTRONS AN ATOM CAN DONATE TO THE DELOCALISE SYSTEM, THE ____ THE MP
HIGHER
39
Y DOES MAGNESIUM HAVE A HIGHER MP THAN SODIUM
CUZ MG CAN DONATE 2 ELECTRONS WHEREAS SODIUM CAN ONLY DONATE 1 PER ATOM
40
give the properties of metals with explanations
https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EQcDvPSbyYpInxqtv1wSj8kBWvFbLeueFXgY5r6J9l7jDQ?e=vQsHiN
41
why do solids have a high density
the particles are tightly packed and in a regular arrangement.
42
in solids particles vibrate on the spot and hence cant be..
compressed
43
why do liquids have a high density
particles are tightly packed and in a random arrangement
44
particles in a liquid have more energy than in a...
solid
45
why is it difficult for liquids to be compressed
cuz particles move freely
46
why do gases have a low density, and why can gases be compressed
particles are spaced out and in a random arrangement hence have a low density. particles in gases more freely hence its ez to compress
47
particles in a gas have more energy than in .....
liquids and solids
48
SUMMARY OF BONDING. MENTION THE USUAL STATE AT ROOM TEMP. CONDUCT ELECTRICITY AS A SOLID. CONDUCT ELECTRICITY AS A LIQUID. SOLUBLE IN WATER. MP AND BP.
https://merchanttaylorsschools-my.sharepoint.com/:w:/g/personal/tofoma_merchanttaylors_com/EaHY1_cmhAlLu8lVv7OnoB4BgBD47pyKMr9-jR1XYz-ENg?e=F4AVlZ
49
IONS CONDUCT ELECTRICITY WHEN? AND Y
HEATED OR MOLTEN AS FREE IONS CAN MOVE FREELY AND CARRY THE CHARGE.