Bonding Flashcards

1
Q

ionic bonding

A

the electrostatic force of attraction between opositely charged ionsbformed by electron transfer

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2
Q

do metal atoms lose or gain electrons

A

lose

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3
Q

covalent bond

A

a shared pair of electrons

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4
Q

dative covalent bond

A

the shared pair of electrons in a bond comes from one atom

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5
Q

metallic bonding

A

the electrostatic force of attraction between positive metal ions and delocalised electrons

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6
Q

factors that affect metallic bonding

A
  1. number of protons- more protons=stronger bond
  2. number of delocalised electrons per atom- more delocalised electrons=stronger bond
  3. size of ion- smaller ion=smaller bond
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7
Q

ionic bonding properties

A

•high boiling points- strong electrostatic forces
•good solubility in water
•poor conductivity when solid- ions can’t move
•good conductivity when molten

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8
Q

molecular (simple covalent) bonding properties

A

•low melting and boiling points -weak intermolecular forces
•poor solubility in water
•poor conductivity when solid- no ions to conduct and electrons are localised
•poor conductivity when molten

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9
Q

macromolecular (covalent) bonding properties

A

•high bpt and mpt- many strong covalent bonds
•insoluble in water
•poor conductivity apart from graphite

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10
Q

metallic bonding properties

A

•high mpt and bpt- strong electrostatic forces
•insoluble in water
•good conductivity- delocalised electrons

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11
Q

trigonal planar

A

3 bonding pairs
bond angle- 120
examples- BF3, NO3

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12
Q

linear

A

2 bonding pairs
bond angle-180
examples- CO2,HCN

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13
Q

tetrahedral

A

4 bonding pairs
bond angle-109.5
examples- SiCl4, SO4²‐

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14
Q

trigonal pyramidal

A

3 bonding pairs, 1 lone pair
bond angle-107
examples- NCl3, PF3

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15
Q

bent

A

2 bonding pairs, 2 lone pairs
bond angle- 104.5
examples-OCl2, H2S

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16
Q

trigonal bipyrimidal

A

5 bonding pairs
bond angle- 120, 90
example- PCl5

17
Q

octahedral

A

6 bonding pairs
bond angle-90
example- SF6

18
Q

do lone pairs or bonding pairs repel more

A

lone pairs

19
Q

electronegativity

A

the tendency of an atom in a covalent bond to attract electrons towards itself

20
Q

what’s the most electronegative element

A

flourine

21
Q

factors affecting electronegativity

A

•increases across a period as number of protons increases and atomic radius decreases
•decreases down a group as distance between nucleus and outer electrons increase and shielding increases

22
Q

what type of bonding do compounds with small or none electronegativity have

A

pure covalent

23
Q

what type of bonding do compounds with a large electronegativity have

A

ionic

24
Q

when does a permanent dipole form

A

when the elements in the bond have different electronegativities

25
Q

polar covalent bond

A

unequal distribution of electrons

26
Q

symmetrical molecule

A

all bonds identical and no lone pairs, will never be polar even if individual bonds are polar

27
Q

Van der Waals forces

A

occur between all molecular substances and noble gases. Do not occur in ionic substances

28
Q

induced dipole

A

van der waals forces, when electrons are constantly moving and electron density fluctuates

29
Q

factors affecting size of van der waals

A

the more electrons the higher the chance of temporary dipoles, increases size of van der waals

30
Q

permanent dipole-dipole forces

A

•occur between polar molecules
•stronger than Van der Waals

31
Q

Hydrogen bonding

A

•occurs when hydrogen is attached to a Nitrogen, Oxygen or Fluorine
•there’s a large electronegativity between the H and the N,O,F
•occurs in addition with Van der Waals