Bonding Flashcards

1
Q

what is an ionic bond ?

A

a bond between a metal and a non metal where an electrostatic force of attraction occurs between oppositely charged ions

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2
Q

state the charges on :
group 1
group2
group6
group7

A

+
2+
2-
-

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3
Q

what is a structure of an ionic bond ?

A

each ion attracts to opposiute charges - forms giant ionic lattice containing billions of ions (lattice structure)

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4
Q

what is formula for :
sulfate
hydroxide
nitrate
carbonate
ammonium

A

so42-
oh-
no3-
co32-
nh4+

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5
Q

ionic bonding properties :nacl
melting and boiling point

A

high MP &BP as a lot of energy is needed to overcome strong force of electrostatic force of attraction (the higher the charge of the ionic compound the higher the mp and bp - e.g mgo and nacl )

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6
Q

ionic bonding strength :nacl

A

when size of ions decrease , strength increases( . e.g fluoride ions are smaller than chloride ions so calcium fluoride has higher melting point then calcium chloride )
hard and brittle

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7
Q

ionic bonding solubility : nacl

A

they are soluble - but ionic lattice must be broken and water molecules attract and surround ions
as ionic charge increases - solubility decreases

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8
Q

ionic bonding electricity nacl

A

can conduct electricity when molten or in aqueous solution as ions are free to move and conduct electricity . in solid ions cannot move = not conduct electricity

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9
Q

when can ionic compounds split ?

A

if pressure / forces cause ions to one closer to each other , some charged ions may repel causing it to split .

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10
Q

what is a covalent bond ?

A

electrostatic force of attraction between a shared pair of electrons and nuclei of bonded atoms - when atoms are combined by covalent bionds they form molecules

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11
Q

what is the difference between multiple and single covalent bonds ?

A

single = shaired pair of electrons
multiple bonds = multiple pairs of electrons

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12
Q

what is a coordinate covalent bond

A

it is a covalent bond which includes a shaired pair of electrons from 1 atom

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13
Q

simple molecular properties iodine MP & BP

A

low as there are weak forces of attraction

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14
Q

simple molecular properties iodine electrical conductivity

A

doesn’t as no charged particles free to move

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15
Q

simple molecular properties iodine strength - brittle

A

weak intermolecular forces

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16
Q

simple molecular properties iodine solubility

A

depending on intermolecular forces (slightly )

17
Q

giant covalent (diamond ) properties (MP AND BP

A

high as lots of strong covalent bonds (electrostatic forces of attraction ) between atoms

18
Q

giant covalent (diamond ) properties electrical conductivity ?

A

cannot as no delocalised electrons around it

19
Q

giant covalent (diamond ) properties strength ?

A

very strong due top strong force of attraction between carbon atoms - rigid arrangement of atoms held y covalent bonds

20
Q

giant covalent (diamond ) properties solubility ?

A

insoluble

21
Q

what is metallic bonding ?

A

sea of delocalised electrons surrounding by poitive ions arranged in a lattice

22
Q

metallic bonding properties - melting point and boiling point

A

high MP AND BP as high metallic attraction as strong bonds =strong metallic bond between the -ve and +ve charge

23
Q

what is metallic bonding ? strength

A

strong as force of electrostatic attraction between opposite charges = high metallic bond as layers can slide while maintaining metallic bond

24
Q

what is metallic bonding ? electrical conductivity

A

high as surrounded by sea od delocalised electrons = conduct electricity

25
Q

what is metallic bonding ? solubility

A

insoluble

26
Q

graphite + graphene properties MP + BP

A

high MP AND BP as a lot of energy needed to break all strong covalent bonds

27
Q

graphite + graphene properties electrical conductivity

A

yes as 1 delocalised electron free per carbon atom = can conduct electricity

28
Q

graphite + graphene properties strength

A

brittle as weak forces between layers = easy for layers to slide

29
Q

graphite + graphene properties solubility

A

insoluble

30
Q

ICE properties : MP +BP

A

low mp amnd bp as there are weak froces of attraction between molecules

31
Q

ICE properties : electrical conductivity

A

doesn’t conduct as there are no mobile charged particles surrounding it

32
Q

density of ice versus water ?

A

ice is less dense then water as ice molecules are arranged in a lattice structure due to hydrogen bonds - liquid molecules are closer but not in a lattice

33
Q

electronegativity ?

A

relative ability of an atom to attract pairs of electrons in covalent bonds

34
Q

electronegativity down a group

A

electronehativity decreases

35
Q

electronegativity across a period ?

A

electronegativity increases

36
Q

factors effecting electronegativity

A

atomic radius - closer to nucleus = stronger attraction between nucleus and bonding pair of electrons
shielding - less shells of electrons between nuclei and the electrons = less shielding = less repulsion = stronger attraction between nucleus and outer bonding electrons
nuclear charge - more protons , stronger attraction between nucleus and bonding pairs of electrons

37
Q

a bond will be non polar when

A

bonded atoms are the same
bonded atoms have same or similar electronegativity

38
Q
A