bonding Flashcards

1
Q

what is a symbol for nitrate ion

A

NO3-

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2
Q

what is the symbol for a ammonium ion

A

NH4+

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3
Q

what is the symbol for a sulfate ion

A

SO4 2-

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4
Q

what is the symbol for a carbonate ion

A

CO3 2-

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5
Q

what are the steps to working out the formula of an ionic compound

A

1- write the 2 ions
2- swap the charges
3- drop the charges
4- simplify to the whole number ratio

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6
Q

workout the formula for this

Ca2- and O2+

A

Ca2+ and O2-
Ca2 and O2
Ca2O2

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7
Q

what is a giant ionic structure like

A

regular cubic shape
giant repeating pattern

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8
Q

why do ionic compounds have high melting points

A

strong electrostatic forces of attraction and requires lots of energy to overcome

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9
Q

where is the electrostatic attraction in a covalent bond

A

between the shared electrons and the nucleus

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10
Q

what is a Dative covalent bond

A

when one atom donates 2 electrons to form a bond

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11
Q

what usually represents a dative covalent bond

A

an arrow

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12
Q

describe the structure of graphite

A

each carbon bonded 3 times with 4th electron delocalised

layers which can slide over each other

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13
Q

why can graphite conduct electricity

A

delocalised electrons between the layers which can carry a charge

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14
Q

describe the properties of graphite

A

can conduct electricity

insoluble as covalent bonds too strong to break

layers are far apart so low density

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15
Q

why can diamond conduct heat well

A

its tightly packed and rigid

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16
Q

why cant diamond conduct electricity

A

no delocalised electrons

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17
Q

what do lone pairs do to bonding pairs

A

push them closer together

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18
Q

how many bond pairs and lone pairs does a linear shape have

whats the bond angle

A

2 bond pairs 0 lone

180

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19
Q

how many bond pairs and lone pairs does a trigonal planar have

whats the bond angle

A

3 bond pairs 0 lone

120

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20
Q

how many bond pairs and lone pairs does a tetrahedral have

whats the bond angle

A

4 bond pairs 0 lone

109.5

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21
Q

how many bond pairs and lone pairs does a
trigonal bipyramidal have

whats the bond angle

A

5 bond pairs 0 lone

90 and 120

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22
Q

how many bond pairs and lone pairs does a octahedral have

whats the bond angle

A

6 bond pairs 0 lone

90

23
Q

how many bond pairs and lone pairs does a pyramidal shape have

whats the bond angle

A

3 bonded 1 lone

107

24
Q

how many bond pairs and lone pairs does a bent molecule have

whats the bond angle

A

2 bonded 2 lone

104.5

25
how many bond pairs and lone pairs does a trigonal planar have whats the bond angle
3 bonded and 2 lone 120
26
how many bond pairs and lone pairs does a square planar have whats the bond angle
4 bonded and 2 lone 90
27
what is electronegativity
the ability for an atom to attract electrons toward itself in a covalent bond
28
how does electronegativity change as you go across the periods
it increases
29
how does electronegativity change down the groups
decreases
30
describe the trend of electronegativity on the periodic table as a whole what does this exclude
the further up and right you go the more electronegative the element is the noble gases
31
when do covalent bonds become polar
when atoms attached to it have a difference in electronegativity
32
the bigger the difference in electronegativity the more what
the more polar the bond will be
33
atoms with the same electronegativity are not what
polar
34
what are van der waals
weak forces that exist between atoms and molecules
35
van der waals are w----
weak
36
when do temporary dipoles form
when 2 molecules are near by and electrons are unevenly distributed
37
what determines how many van der waals the atom has
how big the molecule or atom is
38
why do long straight chain hydrocarbons have higher boiling points
they have more van der waals which need breaking
39
what is a dipole dipole
weak electrostatic force within polar molecules
40
why are dipole dipoles strong
they are permanent
41
why are dipole dipoles strong
they are permanent
42
when is hydrogen bonding strongest
when u have very electronegative elements
43
when does hydrogen bonding occur
when one molecule of hydrogen forms a bond with a lone pair of nitrogen, oxygen or fluorine
44
describe the structure of metals
giant metallic lattice structures
45
the more atoms a metal can donate the what
higher the melting point
46
what kind of crystal structure does iodine have
molecular
47
what kind of crystal structure does graphite have
giant covalent lattice
48
describe the structure and bonds of graphite
layers of carbon atoms van der waals between layers strong covalent bonds
49
why does something like iodine vaporize when heated
van der walls are weak van der walls between molecules
50
define electronegativity
the ability to attract shared electrons to an atom in a covalent bond
51
why does sulfur having a higher melting point then phosphorus
sulfur is larger so more energy is needed to break molecules
52
why are argons van der walls weak
argon exists as a single atom so cannot be easily broken
53
why is the bonding of nitrogen oxide covalent instead of ionic
small difference in electronegativity