Bonding Flashcards

1
Q

Ionic bonding

A

Involves electrostatic attraction between oppositely charged ions in a lattice

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2
Q

Ionic formulas

A

Positive cation-metal, no name change

Negative anion-non metal, name change

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3
Q

Metallic bonding

A

Involves attraction between delocalised electrons and positive ions arranged in a lattice

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4
Q

Metal properties

A

Good conductors-delocalised electrons

Strong, malleable, ductile, high melting points

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5
Q

What does strength of metsllic bond depend on

A

The size and charge of the ion

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6
Q

Covalent bonds

A

Metal and non metal react to share electrons and attain full outer shells
Nucleinof each atombattracted to shared electron pair

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7
Q

What covalent bonds are strongest

A

1pair-longest and weakest

3 pairs-shortest and strongest

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8
Q

Dative covalent bond

A

A covalent bond in which both ekectrons come from the same atom
- drawn with arrow in direction of electron movement not line

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9
Q

How to work out shape of molecules

A
Central atom
Group/ outer electron number
Charge
Bonds
Total
Divide by 2=number of electron pairs
Structure
Look at 6 and 4 to wirk out lone pairs
Shape
Bond angle
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10
Q

Pair repulsion theory

A

Outer shell electron pairs arrange as far apart as possible to minimise repulsion
Lone pair-lone pair=greatest repulsion
Bond pair-bond pair=least repulsion

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11
Q

Form of electron pairs

A

As charge clouds that repel each other

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12
Q

Molecular shapes

A
Linear-180•
Trigonal planar-120•
Tetrahedral-109.5
Trigonal bipyrimidal-120/90•
Octahedral-90•
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13
Q

Electronegativity

A

The power of an atom to attract the pair of electrons in a covalent bond

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14
Q

Electronegativity patterns

A

Increases accross period

Decreases down group

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15
Q

Factors affecting electronegativity

A

Nuclear charge-more protons=stonger bp nucleus attraction
Atomic radius-closer bonding electrons,stronger attraction
Shielding-less shells shielding bp, sttonger force

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16
Q

Polar covalent bonds

A

2 atoms in covalent bond have different electronegativity
2 electrons not shared equally
More e is d-, less e is d+

17
Q

Non polar covalent bond

A

2 atoms in covalent bond have same electronegativity

2 atoms shared equally

18
Q

Weakest to strongest IMF

A

Van der waals-weakest
Dipole dipole
Hydrogen-strongest

19
Q

VDW(induced dipole dipole)

A

More e at one end of atom by chance at 1 moment, w slight d-/+
This makes an instantaneous dipole and weak force of attraction between 2 neighbouring oppositely charged ends of temporary dipoles
Vdw always exist

20
Q

Dipole-dipole (permanent)

A

Bond between polar molecules, attractive force between dipoles on different molecules
Permanent so stronger than VDW

21
Q

Dipole moment

A

Some covalent bonds are polarso arramgenent can result in molecule iverall becoming polar

22
Q

Hydrogen bonding elements

A

Nitrogen
Oxygen
Fluorine

23
Q

Shape of covalent to H bond

A

Linear

24
Q

H bonds

A

H bonded to v electronegative atom
Strong intermolecular force not bond
Polar bond leaves H nucleus exposed as only one electron so strong attraction between exposed nucleus and lone pair on NOF

25
Q

Crystal structures

A

Ionic
Metallic
Giant covalent
Molecular

26
Q

Crystal structure examples

A
Diamond
Graphite
Ice
Iodine
Magnesium
Sodium chloride
27
Q

Clear ice explanation

A

Clear as light oasses through middle of hexagonal structure