Bonding 1-2 Flashcards

1
Q

When does ionic bonding occur

A

Metal + non metal
Electron transferred

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2
Q

When does covalent bonding occur

A

When does covalent bonding occur

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3
Q

When does metallic bonding occur

A

Metal and metal
Electron pooled

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4
Q

Why do chemical bonds occur

A

As they lower the potential energy between charged particles that constitute atoms
Potential energy : The stored desire between bonding atoms to repel each other as when two nuclei are pushed together protons are pushed together which repel

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5
Q

Compare electronegativity of ionic and covalent bonds increasing

A

Pure covalent (equally shared)-polar covalent (unequally shared )-Ionic transferred

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6
Q

What occurs during ionic bond

A

The metal loses an electron electron due to low ionisation energy :energy required to remove an electron )
The non metal gains an electron due to high electron affinity

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7
Q

What’s ionisation energy of cation -metal to lose electron

A

Ionisation energy is endothermic

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8
Q

What is the acceptance of an electron by non metal

A

Exothermic

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9
Q

Which is larger ionisation energy or acceptance of an electron

A

Ionisation energy is larger then acceptance of electron
However heat formation of ionic compound is generally an exothermic value

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10
Q

What’s the energy difference due to

A

Energy difference is due to formation of highly ordered structure known as crystal ionic structure

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11
Q

Where are valence electrons

A

Valence electrons are the outermost electrons in an atom

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12
Q

What does Lewis theory say

A

Electrons are transferred from one atom to another forming ions . One atom must lose a valence electron whilst other must gain

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13
Q

What are elements with low ionisation energy known as

A

Electropositive

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14
Q

What are elements which require electrons more readily known as

A

Electronegative

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15
Q

What are properties of ionic compounds

A

Larger ion, weaker attraction and hence
lower lattice energy.
• Larger charge, stronger attraction and
hence higher lattice energy.
• Ionic compounds have high melting points (and boiling points).
• All ionic compounds are solids at room temperature.
• Hard and brittle crystalline solids – many are soluble in water.

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16
Q

What’s the Lewis theory applied to covalent bonds

A

The Octet rule still applies, but now the
atoms achieve their octet by sharing
electrons.
* A bond consists of a shared pair of
electrons.

17
Q

How does chlorine create covalent bonds

A

Cl + Cl  Cl2
Chlorine has seven valence electrons (3s2 3p5)
Sharing of the unpaired 3p electrons  filled outer shells

18
Q

What are electrons which aren’t shared known as

A

Electrons that are not shared between
atoms are called lone pairs of electrons

19
Q

What’s the shape of molecule determined by (covalent bonding )

A

The shape of the molecule (covalent
bonding) using this theory is explained by
electrostatic repulsion between electron-
pair bonds and also lone pairs.

20
Q

What pattern do elements in first period tend to follow

A

C = 4 bonds and no lone pairs.
• N = 3 bonds and 1 lone pair.
• O=2 bonds and 2 lone pairs.
• H = 1 bond, no lone pairs.
• Halogens = 1 bond and 3 lone pairs

21
Q

What’s a polar covalent bond

A

Covalent bonding between two different
atoms, e.g. hydrogen and chlorine gives rise to
a covalent bond where the two electrons
(bond) are shared unequally.
• We have a polar covalent bond.
• The polar covalent bond has a polarity, i.e. one
end of the bond has a small positive charge
(hydrogen; relatively electron deficient),
whilst the other end has a small negative
charge (chlorine; relatively electron rich)

22
Q

What are some examples of polar covalent bonds

A

HCL H2O NH3

These molecules have a dipole

23
Q

What are examples of electronegative elements

A

Chlorine
Florine
Bromine
Oxygen
Nitrogen

24
Q

Calculation for size of dipole

A

Size of dipole indicated by dipole moment (µ)

µ = e x d
where e = magnitude of charge on an atom (δ+ or δ-)
and d = distance between the two charges
The unit of m is the debye (D)