BIOMOLECULES Flashcards
carbohydrates that do not fit the description of conventional formula
rhamnose(C6H1206) and deoxyribose(C6H10O4)
compounds that were not carbohydrates but still obeyed the formula?
formaldehyde and acetic acid
disaccharides?
sucrose, lactose, and galactose
trisaccharides
raffinose
tetrasaccharides
stachyose
non reducing sugar
sucrose
nonsugars?
polysaccharides
all naturally occurring monosaccharides belong to
D configuration
glucose is
dextro rotatory
laboratory method of preparation of glucose
hydrolysis of cane sugar(invertase enzyme)
commercial preparation method of glucose
from starch by hydrolysis
glucose is converted to hexane by
red P
bromine in water converts glucose to
gluconic acid
glucose on oxidation by HNO3 forms
saccharic acid
what are the limitations of open chain structure?
glucose doesn’t give 2,4 DNP test, NH3, NaHSO3, Schiff base, glucose penta acetate doesn’t react with hydroxyl amine
which form shows more stability
beta form
ring structure of glucose is also called as
pyranose structure or Haworth structure
fructose is a
levulose and ketose
the optical rotation of alpha D glucose
+112
the optical rotation of beta D glucose?
+19
the optical rotation of the equilibrium mixture of anomers of glucose?
+52.5
what is mutarotation
the change in the specific rotation of an optically active compound with time to an equilibrium value
ring structure of fructose is called
furanose structure
sucrose is the disaccharide of
alpha D + glucose and beta D - fructose