Biomolecules Flashcards

1
Q

There is a small set of elements found in living systems what are they

A

N,O,H,C

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2
Q

Living compounds are made from these primary biological molecules

A

H, N, O, P, S

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3
Q

Amino acids contain which two groups which ionize to be?

A

○ Amino group (NH2)
§ Ionizes to NH3+
○ Carboxylic acid group (COOH)
§ Ionizes to COO-

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4
Q

What is another name for carbohydrates

A

○ Monosaccharides
○ sugars

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5
Q

What is the formula for carbohydrates

A

○ (CH2O)n where n is greater than or = to 3

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6
Q

What is the molecular formula for glucose

A

○ C6H12O6

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7
Q
  • Does glucose take on a cyclic structure in solution
A

yes

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8
Q
  • What makes up a nucleotide
A

5 carbon sugar
○ Nitrogen
○ phosphate

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9
Q

What are characteristics of lipids

Bonus why are they hydrophobic

A

○ No real structure they can come in many shapes and sizes
○ Hydrophobic
Dont make polymers

bonus: Because they are long chains of C and H which are not polar

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10
Q

Define monomers in the context of polymers
namethemonomers

A

○ The individual building blocks
§ Amino acids
§ Carbohydrates
§ nucleotides

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11
Q
  • Define polymers
A

○ A string of monomers that can encode information

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12
Q

What does monomer residue mean

A

○ Monomers are considered monomer residue once they have become part of a polymer because they lose a little part of them self when they join together

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13
Q
  • What is the monomer of protiens and what is another name for protiens

bonus: how many amino acids are there

double bonus: why is this number important

A

○ Amino acids are the monomers for protiens
○ Polypeptides is another name for them
○ Bonus: 20
Double bonus: This is important because it allows for a variety of protiens to be formed making it so protiens can have many different jobs

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14
Q
  • What kind of bond links protien monomers together
A

○ Amide bonds called peptide bonds

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15
Q
  • Define conformation
A

○ It is the 3D shape of the polypeptide chain

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16
Q
  • Nucleic acids are best known as (two separate names) but also have a third less common name
A

○ DNA and RNA
○ polynucleotides

17
Q
  • Why do polysaccharides differ from nucleic acids and protiens
A

○ They differ from nucleic acids because they are homogeneous polymers so it limits their potential to carry genetic information
○ They also cannot adopt a very large variety of shapes which means they cant have lots of different jobs
○ They do however serve a fuel for the body by storing energy and also provide structural support

18
Q

Fill out this chart

A
19
Q
  • What is waters configuration
A

○ A tetrahedral with oxygen at center
- Hydrogen at two corners and free electrons at the others

20
Q
  • Which atom bears the + charge and which bears the - charge in
    water molecules
    ○ Oxygen +
    ○ Hydrogen -
    ○ Water is polar
A

○ Oxygen +
○ Hydrogen -
○ Water is polar

21
Q
  • Explain hydrogen bonds
    ○ Bonus: in a hydrogen bond what element is donating and what element is accepting
A

Hydrogen bonding is when a hydrogen atom experiences electrostatic attraction to strong biological electronegative atoms
-This means O and N only because they have to strongest electron
affinity and are biological atoms
-The hydrogen that is being bonded must already have a permanent
bond
□ C-H is not permanent because carbon does not have a strong
enough hold on the H

bonus:
§ H atoms donate
□ Water can donate two H
§ Unshared e- are acceptors
□ Water can accept two bonds
Water can make 4 Hbonds

22
Q
  • How many bonds does ice make vs water
A

○ Ice has a crystalline form so it forms 4 strong Hbonds
○ Water only forms about 3
- Usually for sure one acceptor and one donator
- These bonds are weaker and are continuously breaking and
reforming
-Short half life

23
Q
  • Why does ice float
A

○ Ice floats because Hbonds demand that the molecules be orientated a curtain way which makes a geometric constraint (leaving spaces between the atoms) which makes it less dense then water which is less orientated and more compact

24
Q
  • Define electronegativity
A

○ An atoms affinity for electrons
- How close they pull e- to themselves

25
Q
  • What are ionic interactions
A

○ Ionic interactions happen between too oppositely charged molecules that attract each other
○ Slightly stronger than Hbonds

26
Q
  • What bonds are considered van der Waals interactions and explain each one
A

○ Dipole-dipole interactions
- These are like Hbonds where the molecules are polar but form
weaker bonds
- H can form dipole-dipole bonds with atoms that are less
electronegative
-That is why they are weaker bonds
○ London dispersion forces
- These bonds occur in non-polar molecules when they experience a
small fluctuation in polarity which creates a wave effect and causes
molecules around it to be temporarily attracted to it
-This type of attraction has a short half life and is always
continually stopping and starting

27
Q
  • What is dielectric constant
A

○ It is a measure of a solvents ability to diminish the electrostatic attraction between dissolved ions
○ Water has a high dielectric constant
- This means that ions are not able to associate as much

28
Q
  • A dissolved partial is called what
A

○ A solute

29
Q
  • What is it called when an ion is surrounded by its solvent
A

○ The ion is solvated or hydrated if the solvent is water

30
Q
  • Define hydrophilic
A

○ Water loving
○ Polar

31
Q
  • Define hydrophobic
A

○ Have a lack of polar groups
○ Water fearing
○ Insoluble in water

32
Q
  • What happens during the hydrophobic effect and how is it defined
A

○ Because nonpolar substances take away some of waters energy by not allowing them to move wherever and whenever they want they water molecules force the hydrophobic molecules together so that they have less surface area and less water molecules are strained
- Although only the molecules around the hydrophobic mollecules are
strained and cant really move where they want all the water
molecules of water end up losing energy because they take turns
being strained
○ The exclusion of nonpolar substances from an aqueous solution is known as the hydrophobic effect

33
Q
  • Is hydrophobic bonds correct
A

○ There is no such thing as hydrophobic bonds
On a test anything that says this is wrong

34
Q
  • Define amphiphilic molecules and how do they compare to amphipathic molecules
A

○ Amphiphilic molecules have a part of them that is hydrophilic and a part of them that is hydrophobic
○ The difference between amphiphilic and amphipathic is amphiphilic molecules usually like water more and amphipathic molecules usually hate water more

35
Q
  • When an amphiphilic molecule is shaped like a cone how does it act in water
A

○ It forms a sphere micelle with the hydrophilic heads on the outside and the hydrophobic tails on the inside
○ It is shaped like a cone because it only has one hydrophobic tail

36
Q
  • What happens when the amphiphilic molecule has two hydrophobic tails
A

○ It forms a bilayer with hydrophilic heads facing out on either side and the hydrophobic tails facing inwards

37
Q
  • What does a bilayer help with
A

○ This bilayer is used as cell walls and prevents polar substances from pouring out
○ Polar substances have a hard time getting through the bilayer because they hydrophobic core refuses to let them in
○ Substances of high concentration usually want to move to lower concentration so it can equalize its concentration and energy level
§ The bilayer tends to stop this so that whatever is needed in the cell stays in the cell and anything that isnt needed stays out