Biomaterials Exam - Biomechanics and Biomaterials Flashcards
What does a contact angle measure?
how a liquid interacts with a solid
Explain what a low contact angle (approaching 0) would mean.
good wetting because the liquid would rather interact with the surface than itself
Explain what a high contact angle (approaching 180) would mean.
poor wetting because the liquid would rather associate with itself than the surface
What is the difference between hydrophobic and hydrophilic?
- hydrophobic is “water-fearing” which means that the surface will not interact well with water
- hydrophilic is “water-loving” which means that the surface will interact readily with water
True or false: Molecules can have both hydrophilic and hydrophobic components.
true
What is a hydrophilic primer/adhesive used for?
Tooth structure is hydrophilic, but composite is hydrophobic so they wouldn’t be able to attach to one another. A hydrophilic primer/adhesive is used which has a hydrophilic portion that adheres to the tooth structure and a hydrophobic portion that adheres to the composite.
This is called surface wetting.
When is surface wetting important?
- anytime two different materials come into contact
- impression materials
- adhesives
- bacterial adhesion
What affects primary bonding?
chemical and electro-chemical reactions
What affects secondary bonding?
processes such as adsorption (onto) and absorption (into)
Define corrosion.
the spontaneous destructive oxidation of metals
Which are the only metals not to corrode spontaneously in Earth’s normal atmosphere?
gold, platinum, and palladium (noble metals)
Differentiate between active and passive corrosion.
- active corrosion - leads to destruction ((gamma)2)
- passive corrosion - produce corrosion film that prevents further corrosion (titanium implants)
What are the 4 types of corrosion? Explain each.
- galvanic corrosion - one metal acts as cathode and one metal acts as anode
- structure selective corrosion - each phase in a two-phase mix acts as either a cathode or an anode
- crevice corrosion - surface of the restoration acts as a cathode and crack tip of prep acts as anode
- stress corrosion - stressed restoration acts as anode and unstressed region acts as cathode
What does an anode do during corrosion? What does a cathode do during corrosion?
- anode - corroding metal
- cathode - different metal (passive-supplied electrons to solution)
How are ceramics affected through chemical dissolution? Give examples.
normally occurs through dissolution of oxides created by the hydrogen bonding effects of water in local areas of high acidity
- examples:
- acids dissolve hydroxyapatite (caries, acid etch for enamel bonding)
- acidulated fluoride treatments dissolve ceramic crowns and may roughen surface or remove surface stain