Biological Chemistry/Macromolecules Flashcards

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1
Q

draw fructose in its ring form

A
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2
Q

draw fructose in its linear form

A
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3
Q

draw glucose in its ring form

A
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4
Q

draw glucose in its linear form

A
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5
Q

what is the nomenclature for carbohydrates?

A
  • Number of carbons
  • Aldose or ketose sugars
  • Alpha or beta
  • D and L isomers
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6
Q

how do the aldose and ketose carbs vary?

A
  • In an aldose group, the C with the carbonyl group is C1 (glucose)
  • In a ketose sugar, it is on C2 (fructose)
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7
Q

how do the alpha and the beta version vary for carbs?

A
  • Alpha - below the plane: the hydroxyl is opposite the CH2OH
  • Beta - above the plane: the hydrozyl is near the CH2OH
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8
Q

What are the D and L versions - position of OH on penultimate carbon?

A
  • Left is an L sugar (above the plane)
  • Right is a D sugar (below the plane)- this is the type found in biological systems
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9
Q

How does a disaccharide form?

A
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10
Q

what are the common disaccharides?

A
  1. glucose + glucose = maltose
  2. glucose + fructose = sucrose
  3. glucose + galactose = lactose
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11
Q

what is a lipid?

A

they are hydrophobic and are used for energy store

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12
Q

what is a fatty acid?

A
  • monomer of lipids
  • Amphipathic molecule
    • Hydrophilic carboxylic acid head is ionized and polar
    • All the carbons are single bonded - saturated
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13
Q

what is a triaglycerol?

A
  • Glycerol with 3 fatty acids that is used to store energy
  • The double bonded unsaturated fatty acids adds kinks in tails
  • The single bonded saturated fatty acids allows them to pack together efficiently
  • Hydrophobic interactions between the tails
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14
Q

what is a major component of biological membranes?

A

phospholipid bilayer

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15
Q

what is a phospholipid?

A
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16
Q

what is cholesterol?

A

found in the hydrophobic region of the membrane (near the tails) where they help maintain membrane fluidity

17
Q

what are diasterioisomers?

A

they have the same molecular formulas but are structurally mirror images of each other. hence, they are different and unique molecules