Biochemistry intro 1 - atoms, biomolecules and reactions Flashcards
Describe the basic structure of an atom
An atom has protons and neutrons in the nucleus and electrons orbiting around the nucleus in electron shells. A proton has a mass of 1 and a charge of +1, a neutron has a mass of 1 and no charge and an electron has a negligible mass and a charge of -1
What is ionisation energy?
The energy input needed to discharge an electron
What is a covalent bond and an ionic bond?
Covalent bond is shared pair of electrons whereas an ionic bond is the attraction of opposite charges
Does ionic radius increase or decrease as you move down a group?
As you move down a group, ionic radius increases due to more electron shells
What is bond energy?
The amount of energy required to break a bond (measured in kcal/mol)
What is van der waals interactions?
Interaction of electrons of non-polar substances
What is meant by electronegativity?
Electronegativity is the force than an atomic nucleus exerts on an electron (so how much they want an electron)
What is phosphorylation and de-phosphorylation?
Phosphorylation is the addition of a phosphate whereas de-phosphorylation is the removal of a phosphate
What is acylation and carboxylation?
Acylation is the addition of an acyl group (R-C=O) and carboxylation is the addition of a carboxyl group (COOH)
What is esterification?
When alcohol and acid react to form an ester
What is condensation and hydrolysis?
Condensation is the removal of water and hydrolysis is the addition of water
What is oxidation, reduction and a redox reaction?
Oxidation is the loss of electrons, reduction is the gain of electrons and a redox reaction is when one thing is being oxidised and the other thing is being reduced
What is meant by the terms reducing agent and oxidising agent?
A reducing agent is being oxidised so is an electron donor and an oxidising agent is being reduced so is an electron acceptor
Starting at an alkane, keep oxidising and name what you get until you reach carbon dioxide
Alkane → Alcohol → Aldehyde → Carboxylic acid → Carbon dioxide